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Chemistry B (21st Century) · OCR J258 · Paper 2 · June 2018

OCR GCSE Chemistry B (21st Century) Paper 2 June 2018 question paper

OCR J258 · Paper 2

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Question 1

Table 1.1 shows some information about diamond, graphite and carbon dioxide.

Figure for question 1
Answer
Mark scheme for question 1
(a)

Complete Table 1.1 by filling in the state for graphite and carbon dioxide.

[2]

Answer
Mark scheme for question 1(a)
(b)

Explain why diamond and graphite are elements, but carbon dioxide is a compound.

[2]

Answer
Mark scheme for question 1(b)
(c)

Diamond and graphite have giant covalent structures. Carbon dioxide has a simple covalent structure.

Explain how the diagrams of their structures show that these statements are true.

[2]

Answer
Mark scheme for question 1(c)

Question 2

Nitrogen oxides are pollutant gases that are produced when coal burns in a power station.

Answer
Mark scheme for question 2
(a)
(a)(i)

Nitrogen monoxide is one type of nitrogen oxide that is formed in a power station.

The reaction that forms nitrogen oxide can be shown in an equation.

Complete the word and balanced symbol equation by filling in the boxes.

Question 2, shown as an image
Question 2, shown as an image

[2]

Answer
Mark scheme for question 2(a)(i)
(a)(ii)

Which statements about nitrogen oxides are true and which are false ?

Put a tick (✓) in one box in each row.

Figure for question 2

[2]

Answer
Mark scheme for question 2(a)(ii)
(b)

The graph shows information about the concentration in parts per billion (ppb) of nitrogen oxides in the air between 1980 and 2012.

Figure for question 2 Figure for question 2

Describe how the highest daily concentration of nitrogen oxides changed between 1980 and 2012.

[2]

Answer
Mark scheme for question 2(b)
(c)

The World Health Organisation recommends a safe limit for people to be exposed to nitrogen oxides. They recommend that this limit is 100 ppb.

(c)(i)

Why is it necessary to set a safe limit for exposure to nitrogen oxides?

[1]

Answer
Mark scheme for question 2(c)(i)
(c)(ii)

Layla and Mia talk about the graph. Layla says that the nitrogen oxides have been below the safe limit since 1990. Mia says that nitrogen oxides have only been below the safe limit since 2004.

Explain how the graph could be used to support both of these ideas.

Layla’s idea........

Mia’s idea........

[2]

Answer
Mark scheme for question 2(c)(ii)

Question 3

Mauritius is a country of small islands surrounded by sea. There is almost no fresh water in Mauritius.

Answer
Mark scheme for question 3
(a)

A distillation process is used to produce fresh water.

Statements A–G describe some correct and some incorrect stages in the distillation process.

ACold water is used to cool the steam.
BWater evaporates.
CWater condenses.
DWater is heated.
ESeawater is taken from the sea.
FWater is sent through pipes to homes.
GSalt is filtered out from the seawater.

Put the correct statements in the correct order.

The first and last have been done for you.

Figure for question 3

[2]

Answer
Mark scheme for question 3(a)
(b)
(b)(i)

Chlorine is used to treat drinking water before it is sent to homes. The waste water from homes is treated with oxygen.

The table shows some information about oxygen and chlorine.

Figure for question 3

Complete Table 3.1 by filling in the missing information.

[2]

Answer
Mark scheme for question 3(b)(i)
(b)(ii)

Complete Table 3.2 below to show the tests and results used to identify oxygen and chlorine gas.

Figure for question 3

[3]

Answer
Mark scheme for question 3(b)(ii)

Question 4

The alkanes and the alkenes are both examples of homologous series.

Answer
Mark scheme for question 4
(a)

Table 4.1 shows the names and chemical formulae of some alkanes.

Alkanes
methaneCH4
ethaneC2H6
propaneC3H8
butaneC4H10

Table 4.1

(a)(i)

Down the series, the number of carbon atoms and hydrogen atoms increases by the same amount each time.

Use examples from Table 4.1 to show that this statement is true.

[2]

Answer
Mark scheme for question 4(a)(i)
(a)(ii)

Pentane is an alkane with five carbon atoms.

Predict the formula of pentane.

[1]

Answer
Mark scheme for question 4(a)(ii)
(b)

Table 4.2 shows the names and formulae of some alkenes.

Figure for question 4
(b)(i)

Complete Table 4.2 by drawing the displayed formula for propene.

[2]

Answer
Mark scheme for question 4(b)(i)
(b)(ii)

There is no alkene called ‘methene’.

Which statement explains why ‘methene’ cannot exist?

Tick (✓) one box.

Figure for question 4

[1]

Answer
Mark scheme for question 4(b)(ii)
(c)

The general formula for all of the alkenes is CnH2n. The empirical formula for all of the alkenes is CH2.

(c)(i)

Use examples from Table 4.2 to explain why all of the alkenes have the same general formula, CnH2n.

[2]

Answer
Mark scheme for question 4(c)(i)
(c)(ii)

Explain why the empirical formula of all of the alkenes is CH2.

[1]

Answer
Mark scheme for question 4(c)(ii)

Question 5

The diagram shows the arrangement of electrons in an atom of fluorine.

Figure for question 5
Answer
Mark scheme for question 5
(a)

Use the diagram and the Periodic Table provided to complete the missing information in the

Figure for question 5

[3]

Answer
Mark scheme for question 5(a)
(b)

This diagram shows the arrangement of electrons in a fluoride ion.

Figure for question 5
(b)(i)

Describe one way that an atom of fluorine and a fluoride ion are the same and one way that they are different.

Same........

Different........

[2]

Answer
Mark scheme for question 5(b)(i)
(b)(ii)

What is the formula of a fluoride ion?

Question 5, shown as an image

[1]

Answer
Mark scheme for question 5(b)(ii)

Question 6

Amir makes some copper chloride. He reacts copper oxide with dilute hydrochloric acid.

This is an equation for the reaction.

Question 6, shown as an image
Question 6, shown as an image
Answer
Mark scheme for question 6
(a)

Amir does a calculation to work out how much copper chloride he can make from some copper oxide (the theoretical yield).

(a)(i)

He starts by working out the relative formula masses of the compounds in the equation.

Complete Table 6.1 by working out the missing relative formula masses.

Use the Periodic Table to help you.

Figure for question 6

[2]

Answer
Mark scheme for question 6(a)(i)
(a)(ii)

Amir uses 8 g of copper oxide in his experiment.

What is the theoretical yield of copper chloride from 7.95 g of copper oxide? Use Table 6.1 and the equation to help you.

Question 6, shown as an image

0.1345 g 1.345 g 13.45 g 134.5 g

[1]

Answer
Mark scheme for question 6(a)(ii)
(b)

Amir adds 8 g of solid copper oxide to a small amount of dilute hydrochloric acid in a beaker. Some of the copper oxide does not react.

He now has a mixture which contains a solution of copper chloride and some solid copper

Figure for question 6
(b)(i)

Amir uses different techniques to separate solid copper oxide and to obtain crystals of copper chloride from the mixture.

Draw lines from each substance to the correct technique.

Figure for question 6

[2]

Answer
Mark scheme for question 6(b)(i)
(b)(ii)

Amir’s percentage yield for this experiment is very low.

Suggest a reason why.

[1]

Answer
Mark scheme for question 6(b)(ii)

Question 7

Eve measures the volume of gas given off when solid calcium carbonate reacts with a dilute acid.

Fig. 7.1 shows a graph of her results.

Figure for question 7
Answer
Mark scheme for question 7
(a)
(a)(i)

What volume of gas is given off during the first minute of the reaction?

[1]

Answer
Mark scheme for question 7(a)(i)
(a)(ii)

What volume of gas is given off during the second minute of the reaction?

[2]

Answer
Mark scheme for question 7(a)(ii)
(b)

Look at the graph in Fig. 7.1.

Describe what happens to the rate of the reaction during the experiment.

[2]

Answer
Mark scheme for question 7(b)
(c)

Eve does some more experiments.

She measures the rate of reaction when she uses different concentrations of acid.

Table 7.1 shows her results.

Concentration of acid (mol / dm3)Rate of reaction (cm3 / s)
0.21.4
0.42.8
0.64.2
0.85.6
1.07.0

Table 7.1

(c)(i)

Predict the rate of reaction when acid of concentration 0.5 mol / dm3 is used. (i)

Rate of reaction =........ cm3 / s

[2]

Answer
Mark scheme for question 7(c)(i)
(c)(ii)

Eve says that the data shows that rate of reaction is proportional to the concentration.

How does the data show that Eve is right?

[2]

Answer
Mark scheme for question 7(c)(ii)
(c)(iii)

Eve writes an expression to show that rate of reaction is proportional to concentration.

Which expression shows that rate of reaction is proportional to concentration?

Tick (✓) one box.

Question 7, shown as an image
Question 7, shown as an image
Question 7, shown as an image

[1]

Answer
Mark scheme for question 7(c)(iii)

Question 8

Salt that is used for food contains compounds of Group 1 elements. One type of food salt is called ‘Healthy salt’.

Ben wants to find out what the difference is between table salt and ‘Healthy salt’.

He does some experiments to find the emission spectra of some Group 1 elements. He also does experiments to find the emission spectra of table salt and ‘Healthy salt’.

He puts small samples of each element and salt in a spectroscopy machine and looks at the print-out of results.

Here are Ben’s results.

Element
Emission spectrum

Figure for question 8

Food salt
Emission spectrum

Figure for question 8
(a)

* What conclusions can you make about the elements that table salt and ‘Healthy salt’ do and do not contain? Explain how the lines in both emission spectra support your conclusions.

[6]

Answer
Mark scheme for question 8(a)
(b)

Elements in salts can also be identified using chemical tests.

Each test involves adding chemicals to the salts and looking for colour changes or reactions.

Ben thinks that spectroscopy is a better method to use to identify the elements.

What are the advantages and disadvantages of using spectroscopy rather than chemical tests to identify elements?

[3]

Answer
Mark scheme for question 8(b)
(c)

Ben says that spectroscopy is a qualitative technique. He says that he wants to try a quantitative technique to find out more about the salts.

Draw lines to connect each technique with its use.

Figure for question 8

[2]

Answer
Mark scheme for question 8(c)

Question 9

Soft drinks are sold in containers made from PET (a polymer), aluminium and glass.

Figure for question 9

PET bottle
Aluminium can
Glass bottle

All three containers are non-biodegradable.

Many people want to choose containers that cause less harm to the environment.

Table 9.1 shows some information about the life cycle of the containers.

Figure for question 9
(a)

* Use the data from Table 9.1 to explain why all of the containers cause some harm to the environment and decide which container causes the least harm.

[6]

Answer
Mark scheme for question 9(a)
(b)

Table 9.1 does not include all of the factors needed to do a full life cycle assessment for the drinks containers.

Which two factors will have the biggest effect on the life cycle assessment of the drinks containers?

Tick (✓) two boxes.

Figure for question 9

[2]

Answer
Mark scheme for question 9(b)

Question 10

Kai works in a research laboratory for a company that produces organic carbon compounds.

Answer
Mark scheme for question 10
(a)

Kai has three unlabelled samples of different compounds. All are colourless liquids.

Kai thinks that one of the compounds might be an alkene. He thinks that another of the compounds might be a carboxylic acid. He thinks the third compound is neither an alkene nor a carboxylic acid.

Describe some simple experiments that Kai could use to find out which compound is which.

Include two tests and the expected results in your answer.

[3]

Answer
Mark scheme for question 10(a)
(b)
Figure for question 10
(b)(i)

At what concentrations is ethanoic acid harmful, but not corrosive?

[2]

Answer
Mark scheme for question 10(b)(i)
(b)(ii)

Suggest a concentration at which ethanoic acid is flammable.

[1]

Answer
Mark scheme for question 10(b)(ii)
(b)(iii)

Kai adds very concentrated ethanoic acid to ethanol and heats the mixture.

Suggest some safety procedures for Kai to use to make sure that he is safe during this experiment.

[3]

Answer
Mark scheme for question 10(b)(iii)

Question 11

Figure for question 11
Answer
Mark scheme for question 11
(a)

Some of Mendeleev’s groups contain similar elements to groups in the modern Periodic Table.

Which group in Mendeleev’s table contains the elements now found in Group 14 of the modern Periodic Table?

[1]

Answer
Mark scheme for question 11(a)
(b)

None of the elements from Group 18 of the modern Periodic Table are shown on Mendeleev’s table.

Suggest a reason why.

[1]

Answer
Mark scheme for question 11(b)
(c)

Mendeleev put some of the transition metals into his Group 8.

He put some other transition metals into the other groups.

Give the symbols for three transition metals in Mendeleev’s table that he did not put in Group 8.

[2]

Answer
Mark scheme for question 11(c)
(d)

The transition metals are in the same block of the modern Periodic Table because their properties are similar to each other.

Which property do all the transition metals have?

Tick (✓) one box.

Figure for question 11

[1]

Answer
Mark scheme for question 11(d)
(e)

Transition metal salts are acidic.

Sundip does an experiment to test the acidity of some solutions of transition metal salts. She uses Universal Indicator and a colour chart to find the pH of each salt.

These are Sundip’s results.

Name of saltpH
copper sulfate3
iron sulfate3
zinc sulfate4
nickel sulfate4
(e)(i)

Describe how Sundip uses Universal Indicator to test the pH of the solutions of the salts.

[2]

Answer
Mark scheme for question 11(e)(i)
(e)(ii)

Sundip thinks her results do not show the difference in pH between the salts. She thinks she needs to improve the precision of her pH results.

Explain why she needs to improve her precision and suggest how she can change her experiment to do this.

[2]

Answer
Mark scheme for question 11(e)(ii)

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