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AQA GCSE Combined Science: Synergy

Topic questions Quantitative chemistry Amounts of substance in equations

Amounts of substance in equations

5 questions · 56 marks · about 1 hour

Amounts of substance in equations questions

AQA 8465 Amounts of substance in equations 5 questions

Paper 4: Physical sciences June 2022 Higher tier, Question 6 11 marks

This question is about ammonia.

Nitrogen gas reacts with hydrogen gas to produce ammonia gas in a reversible reaction.

The equation for the reaction is:

N2(g) + 3 H2(g) maths symbol 2 NH3(g)

6.1

What is the effect of increasing the pressure on the equilibrium position in this reaction?

Tick (✓) one box.

The equilibrium position shifts towards the side with the smaller number of molecules.

The equilibrium position is unchanged.

The equilibrium position shifts towards the side with the larger number of molecules.

[1]
Reveal mark scheme Mark scheme for question 6.1
6.2

The reaction to produce ammonia gas is exothermic.

What is the effect of increasing the temperature on the relative amount of ammonia at equilibrium?

Tick (✓) one box.

The relative amount of ammonia decreases.

The relative amount of ammonia stays the same.

The relative amount of ammonia increases.

[1]
Reveal mark scheme Mark scheme for question 6.2
6.3

How must the apparatus for the reaction be designed so that dynamic equilibrium can be reached?

[1]
Reveal mark scheme Mark scheme for question 6.3
6.4

Explain what happens to the relative amounts of nitrogen, hydrogen and ammonia after dynamic equilibrium has been reached.

[2]
Reveal mark scheme Mark scheme for question 6.4
6.5

Ammonia reacts with hydrogen chloride to produce ammonium chloride (NH4Cl).

The equation for the reaction is:

Question 6, shown as an image

6.8 g of ammonia reacts with excess hydrogen chloride.

Explain why ammonia is described as the limiting reactant in this reaction.

[2]
Reveal mark scheme Mark scheme for question 6.5
6.6

Calculate the maximum mass of ammonium chloride that could be produced from 6.8 g of ammonia.

Relative atomic masses (Ar): N = 14 H = 1 Cl = 35.5

[4]
Reveal mark scheme Mark scheme for question 6.6

Paper 3: Physical sciences November 2021 Higher tier, Question 4 8 marks

Magnesium and hydrochloric acid react to produce magnesium chloride and hydrogen.

4.1

Give the test for hydrogen gas.

Give the result of the test if hydrogen gas is present.

[2]
Reveal mark scheme Mark scheme for question 4.1
4.2

During the reaction between magnesium and hydrochloric acid, hydrogen ions form hydrogen molecules.

The half equation for this process is:

Question 4, shown as an image

What type of reaction does this half equation show?

Give the reason for your answer.

[2]
Reveal mark scheme Mark scheme for question 4.2
4.3

0.72 g of magnesium reacted completely with dilute hydrochloric acid.

The equation for the reaction is:

Question 4, shown as an image

Calculate the mass of magnesium chloride produced.

Relative atomic masses (Ar): Mg = 24 Cl = 35.5

[4]
Reveal mark scheme Mark scheme for question 4.3

Paper 3: Physical sciences November 2020 Higher tier, Question 9 17 marks

This question is about the industrial process used to produce ammonia.

Ammonia is produced from nitrogen and hydrogen.

9.1

Complete the dot and cross diagram for the ammonia molecule shown in Figure 11.

Show only the electrons in the outer shell of each atom.

Figure for question 9
[2]
Reveal mark scheme Mark scheme for question 9.1
9.2

Hydrogen is obtained from natural gas.

One stage in the process is to react carbon monoxide with steam.

The equation for the reaction is:

Figure for question 9

The forward reaction is exothermic.

In the industrial process, the reaction occurs at approximately 400 °C

The reaction between carbon monoxide and steam reaches dynamic equilibrium.

Which statement describes dynamic equilibrium?

Tick (✓) one box.

Figure for question 9
[1]
Reveal mark scheme Mark scheme for question 9.2
9.3

The reaction between carbon monoxide and steam is faster at 600 °C than at 400 °C

Explain why a temperature of 600 °C is not used in the industrial process.

[2]
Reveal mark scheme Mark scheme for question 9.3
9.4

Predict the effect of increasing the pressure on the yield of hydrogen.

Give one reason for your answer.

[2]
Reveal mark scheme Mark scheme for question 9.4
9.5

Give two reasons why a catalyst is used in the reaction between carbon monoxide and steam.

[2]
Reveal mark scheme Mark scheme for question 9.5
9.6

The carbon dioxide produced in this reaction can be used in fizzy drinks.

In fizzy drinks carbon dioxide gas dissolves in water to form an aqueous solution of carbonic acid.

Carbonic acid is a weak acid.

Explain the difference between a weak acid and a strong acid.

[2]
Reveal mark scheme Mark scheme for question 9.6
9.7

The equation for the production of ammonia from nitrogen and hydrogen is:

Figure for question 9

1.275 × 1011 kg of ammonia is used each year to manufacture fertilisers.

This is 85% of the ammonia produced each year.

Calculate the mass of nitrogen needed to manufacture the total mass of ammonia produced each year.

Relative atomic masses (Ar): H = 1 N = 14

[6]
Reveal mark scheme Mark scheme for question 9.7

Paper 3: Physical sciences June 2019 Higher tier, Question 8 10 marks

A student planned to make copper sulfate crystals from excess copper oxide and dilute sulfuric acid.

The equation for the reaction is:

Question 8, shown as an image
8.1

Why is it necessary to add excess copper oxide?

[1]
Reveal mark scheme Mark scheme for question 8.1
8.2

This is the method used.

1. Add 25 cm3 of dilute sulfuric acid to a conical flask.

2. Gently warm the dilute sulfuric acid.

3. Add excess copper oxide to the dilute sulfuric acid.

4. Stir the mixture.

5. Heat to evaporate all the water from the mixture.

Suggest two improvements to the method.

Explain why each improvement is needed.

[4]
Reveal mark scheme Mark scheme for question 8.2
8.3

The student used:

• 2 g of copper oxide (in excess)

• 25 cm3 of a solution of dilute sulfuric acid with a concentration of 49 g/dm3

Determine by how many moles the copper oxide (CuO) was in excess.

Relative atomic masses (Ar): Cu = 63.5 O = 16

Relative formula mass (Mr) of sulfuric acid = 98

Question 8, shown as an image
[5]
Reveal mark scheme Mark scheme for question 8.3

Paper 3: Physical sciences June 2018 Higher tier, Question 5 10 marks

A teacher demonstrated the extraction of copper from copper oxide.

This is the method used.

1. Mix 1.30 g of zinc and 1.59 g of copper oxide.

2. Heat the mixture strongly.

3. When the mixture starts to glow, stop heating.

4. Let the glow spread through the mixture.

5. Leave the mixture to cool.

6. Add hydrochloric acid to the cooled mixture.

7. Filter the mixture obtained in step 6.

5.1

A student concluded that an exothermic reaction had taken place.

Explain how an observation made during the demonstration shows this.

[2]
Reveal mark scheme Mark scheme for question 5.1
5.2

The equation for the reaction between zinc and copper oxide is:

Figure for question 5

1.59 g of copper oxide reacted.

Calculate the mass of copper produced.

Relative atomic masses (Ar): Cu = 63.5 O = 16 Zn = 65

Question 5, shown as an image
[3]
Reveal mark scheme Mark scheme for question 5.2
5.3

Explain why steps 6 and 7 result in only copper being obtained as the residue.

[4]
Reveal mark scheme Mark scheme for question 5.3
5.4

The ionic equation for the reaction is:

Figure for question 5

Which statement about the reaction between zinc and copper ions is correct?

Tick one box.

Figure for question 5
[1]
Reveal mark scheme Mark scheme for question 5.4

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