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Chemistry A (Gateway) · OCR J248 · Paper 2 · Foundation · June 2018

OCR GCSE Chemistry A (Gateway) Paper 2 Foundation June 2018 question paper J248/02

1h 45m 90 marks

OCR J248 · Paper 2

25 questions
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Question 1

Lithium, sodium and potassium are Group 1 elements.

What happens when these elements are added to water?

A Some float and carbon dioxide gas and an alkaline solution are made.

B Some float and hydrogen gas and an alkaline solution are made.

C They all float and hydrogen gas and an acidic solution are made.

D They all float and hydrogen gas and an alkaline solution are made.

Question 1, shown as an image

[1]

Answer
Mark scheme for question 1

Question 2

Damp litmus paper is used to test for chlorine gas.

Which statement describes the correct result of the test for chlorine gas?

A Damp blue litmus paper turns red then white.

B Damp blue litmus paper turns white then red.

C Damp red litmus paper turns blue then white.

D Damp red litmus paper turns white then blue.

Question 2, shown as an image

[1]

Answer
Mark scheme for question 2

Question 3

What is the name of the process that converts large alkane molecules into smaller alkane molecules?

A Cracking

B Fractional distillation

C Hydrogenation

D Polymerisation

Question 3, shown as an image

[1]

Answer
Mark scheme for question 3

Question 4

Which displayed formula shows an alkene?

Figure for question 4
Question 4, shown as an image

[1]

Answer
Mark scheme for question 4

Question 5

Figure for question 5

[1]

Answer
Mark scheme for question 5

Question 6

Figure for question 6

[1]

Answer
Mark scheme for question 6

Question 7

Which statement about catalysts is correct?

A A catalyst decreases the activation energy of a reaction.

B A catalyst increases the activation energy of a reaction.

C A catalyst increases the time for a reaction to go to completion.

D A catalyst slows down a reaction.

Question 7, shown as an image

[1]

Answer
Mark scheme for question 7

Question 8

Hydrogen gas can be made by reacting methane and steam (H2O).

Question 8, shown as an image

6 g of hydrogen gas can be made from 18 g of steam, H2O.

How much hydrogen gas can be made from 3.6 g of steam, H2O?

A 0.4 g

B 0.6 g

C 1.2 g

D 6.8 g

Question 8, shown as an image

[1]

Answer
Mark scheme for question 8

Question 9

Which statement is true for a reversible reaction when it is at dynamic equilibrium?

A The concentration of the products is increasing.

B The rate of the backward reaction is greater than the rate of the forward reaction.

C The rate of the forward reaction is equal to the rate of the backward reaction.

D The rate of the forward reaction is greater than the rate of the backward reaction.

Question 9, shown as an image

[1]

Answer
Mark scheme for question 9

Question 10

Figure for question 10

[1]

Answer
Mark scheme for question 10

Question 11

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Question 12

DNA molecules are polymers.

What are the monomers that make up DNA called?

A Carbohydrates

B Nucleotides

C Phosphates

D Proteins

Question 12, shown as an image

[1]

Answer
Mark scheme for question 12

Question 13

What is the major source of carbon monoxide in the Earth’s atmosphere?

A Incomplete combustion of fossil fuels and wood.

B Production in a nuclear power station.

C The combustion of impurities in coal.

D The combustion of impurities in natural gas.

Question 13, shown as an image

[1]

Answer
Mark scheme for question 13

Question 14

Look at the following sentences.

They describe one possible theory for how the Earth’s atmosphere evolved.

The sentences are not in the correct order.

Figure for question 14

What is the correct order for the sentences?

A 2, 4, 3, 5, 1

B 2, 5, 4, 3, 1

C 5, 2, 3, 4, 1

D 5, 2, 4, 3, 1

Question 14, shown as an image

[1]

Answer
Mark scheme for question 14

Question 15

Look at the information about four different polymers.

PolymerCost (£ per kg)Tensile strength (MPa)Melting point (°C)Maximum useable temperature (°C)
A0.741512085
B1.207825470
C0.9235176160
D1.4242156160

Which polymer would be best for making a plastic cup to hold hot drinks?

Question 15, shown as an image

[1]

Answer
Mark scheme for question 15

Question 16

The Group 7 elements are called the halogens.

The table shows information about some of the halogens.

NameAtomic numberBoiling point (°C)State at room temperatureMolecular formula
Fluorine9−188GasF2
Chlorine17−34GasCl2
Bromine3559LiquidBr2
Iodine53184SolidI2
(a)

Which is the most reactive halogen in the table?

[1]

Answer
Mark scheme for question 16(a)
(b)

Astatine is also a halogen. It has the atomic symbol At and an atomic number of 85.

Look at the table.

(b)(i)

Predict the state of astatine at room temperature.

[1]

Answer
Mark scheme for question 16(b)(i)
(b)(ii)

Predict the boiling point of astatine.

[1]

Answer
Mark scheme for question 16(b)(ii)
(c)

Sodium, Na, reacts with chlorine. A white solid is made.

(c)(i)

What is the name of this white solid?

[1]

Answer
Mark scheme for question 16(c)(i)
(c)(ii)

Write down the balanced symbol equation for this reaction.

[2]

Answer
Mark scheme for question 16(c)(ii)

Question 17

A student added 2.4 g of magnesium to hydrochloric acid. She observed that no magnesium was left when the reaction was complete.

The student transferred the solution to an evaporating basin. She heated the solution using a Bunsen burner and evaporated all the water.

(a)

Explain how you can tell from the student’s observation that the hydrochloric acid was in excess.

[1]

Answer
Mark scheme for question 17(a)
(b)

Look at the equation for the reaction.

Question 17, shown as an image

The student knows the reaction is complete when there is no magnesium left.

Use the equation to explain one other way the student could tell that the reaction was complete.

[1]

Answer
Mark scheme for question 17(b)
(c)

The student predicts she should make 9.5 g of magnesium chloride, MgCl2.

She actually makes 7.9 g.

Calculate the percentage yield.

Give your answer to 3 significant figures.

[3]

Answer
Mark scheme for question 17(c)
(d)

Write down one reason, other than a mistake, why the student may have obtained a percentage yield of less than 100%.

[1]

Answer
Mark scheme for question 17(d)

Question 18

Antacid tablets are used to treat indigestion.

A student investigates two different antacid tablets, X and Y. Both tablets, X and Y, contain calcium carbonate, CaCO3.

Calcium carbonate reacts with hydrochloric acid. Calcium chloride, CaCl2, water and carbon dioxide are made.

(a)

Write a balanced symbol equation for this reaction.

[2]

Answer
Mark scheme for question 18(a)
(b)

The diagram shows the apparatus the student uses.

Figure for question 18

The student reacts tablet X with 100 cm3 of hydrochloric acid. The hydrochloric acid is in excess.

He measures the volume of gas made every minute during the first five minutes.

He does a second experiment using tablet Y and a fresh 100 cm3 sample of the same hydrochloric acid.

The table shows his results.

TimeVolume of gas (cm3)
(minutes)Tablet XTablet Y
000
13832
24854
34867
44872
54872
(b)(i)

The graph shows the results for tablet X.

What is the volume of gas made by the end of the experiment?

Figure for question 18

[1]

Answer
Mark scheme for question 18(b)(i)
(b)(ii)

Plot the results for tablet Y on the grid. Draw a line of best fit.

[2]

Answer
Mark scheme for question 18(b)(ii)
(b)(iii)

Tablet X contains less calcium carbonate than tablet Y.

How do the results show this?

[1]

Answer
Mark scheme for question 18(b)(iii)
(c)

The rate of reaction between calcium carbonate and hydrochloric acid can be increased by:

• Using a more concentrated solution of hydrochloric acid

• Increasing the temperature of the acid.

Explain how each of these methods increase the rate of the reaction.

Use ideas about collisions between particles.

[4]

Answer
Mark scheme for question 18(c)

Question 19

Ammonia is made from nitrogen and hydrogen.

(a)

The reaction between nitrogen and hydrogen is reversible.

Explain what this means.

[1]

Answer
Mark scheme for question 19(a)
(b)

The graph shows the percentage of ammonia made at different temperatures and pressures.

Figure for question 19
(b)(i)

Describe how the percentage of ammonia changes as the pressure increases at 450 °C.

[1]

Answer
Mark scheme for question 19(b)(i)
(b)(ii)

Write down a temperature and pressure which make 20% of ammonia.

Temperature =........ °C Pressure =........ atmospheres

[1]

Answer
Mark scheme for question 19(b)(ii)

Question 20

Figure for question 20
(a)

Describe how the student does the flame test in Test 1.

You may draw a labelled diagram to help your answer.

[3]

Answer
Mark scheme for question 20(a)
(b)
Figure for question 20

[6]

Answer
Mark scheme for question 20(b)

Question 21

Figure for question 21
(a)
Figure for question 21

[4]

Answer
Mark scheme for question 21(a)
(b)

Another student does a titration. She also uses dilute sulfuric acid, sodium hydroxide solution and an indicator solution.

The table shows her results.

Titration number1234
Volume of acid (cm3)26.425.225.625.4

The student decides that the best value for the mean (average) volume of acid is 25.4 cm3

Show how she calculated this value.

[2]

Answer
Mark scheme for question 21(b)
(c)

The equation for this reaction is

Question 21, shown as an image
Relative formula mass, Mr
H2SO498
NaOH40
Na2SO4142
H2O18

Water is a waste product in this reaction.

Calculate the atom economy for the reaction.

Give your answer to 1 decimal place.

[3]

Answer
Mark scheme for question 21(c)

Question 22

Scientists are worried about the greenhouse effect.

(a)

Complete the following paragraph about the greenhouse effect.

Use words from the list.

CFCs cool Earth’s

hydrogen infrared methane

microwave Sun’s ultraviolet warm

Greenhouse gases such as carbon dioxide and........ absorb........

radiation radiated by the........ surface, then emit it in all directions. This

greenhouse effect keeps the Earth and its atmosphere........ enough for living

things to exist.

[2]

Answer
Mark scheme for question 22(a)
(b)

Write about two possible ways that greenhouse gas emissions can be reduced.

[2]

Answer
Mark scheme for question 22(b)

Question 23

This question is about metals and alloys.

(a)

The table gives information about some alloys.

AlloyMain metal or metalsUse
Brass.............................................................Musical instruments and coins
Bronze.............................................................Statues
Duralumin.............................................................Aircraft parts
SolderLead and tinJoining metals
SteelIronBridges, cars

Complete the table.

Choose your answers from the list.

Aluminium and copper

Aluminium and iron

Copper and tin

Copper and zinc

Copper and lead

Lead and zinc

[3]

Answer
Mark scheme for question 23(a)
(b)
Figure for question 23 Figure for question 23

[2]

Answer
Mark scheme for question 23(b)
(c)

Steel is an alloy containing iron.

Complete the word equation for the corrosion of iron.

Question 23, shown as an image

[2]

Answer
Mark scheme for question 23(c)
(d)(i)

Iron can be plated with a layer of zinc to prevent it corroding.

This is called galvanising.

Explain how galvanising prevents iron from corroding.

[2]

Answer
Mark scheme for question 23(d)(i)
(d)(ii)

Iron can also be plated with a layer of tin to prevent it corroding.

Describe a disadvantage of tin plating for preventing corrosion.

[1]

Answer
Mark scheme for question 23(d)(ii)

Question 24

This question is about life-cycle assessment.

(a)

A car company is developing three new cars:

• A petrol car

• A diesel car

• An electric car.

They do a life-cycle assessment of each car.

Look at the information about the life-cycle assessment of each car.

Figure for question 24

The company decides to manufacture and sell the electric car.

Explain why they make this choice.

Use the information from the life-cycle assessment to help you.

[3]

Answer
Mark scheme for question 24(a)
(b)

The fuels for the petrol and diesel cars are made from crude oil.

Crude oil is separated into different parts by fractional distillation.

The diagram shows a fractionating column.

Figure for question 24

Explain why crude oil vapour can be separated by fractional distillation.

[3]

Answer
Mark scheme for question 24(b)
(c)

The table shows the boiling points of molecules present in different crude oil fractions.

MoleculeBoiling point (°C)
A−2
B125
C216
D502

Which molecule, A, B, C or D, is in the LPG fraction ?

Explain your decision.

[2]

Answer
Mark scheme for question 24(c)
(d)

Car manufacturers are developing cars that are powered by hydrogen/oxygen fuel cells.

The table shows some information about a 200 km journey using an electric car and a car using a fuel cell.

Figure for question 24

Evaluate the advantages and disadvantages of using a car powered by a fuel cell, rather than an electric car for the 200 km journey.

[3]

Answer
Mark scheme for question 24(d)

Question 25

A student is using the internet to find out about alcohols. The student finds the following information.

NameNumber of carbon atomsBoiling point (°C)
Methanol165
Ethanol279
Propanol397
Pentanol5138
Hexanol6156
(a)

Plot a graph of the boiling points of the alcohols on the grid. Draw a line of best fit.

Figure for question 25

[3]

Answer
Mark scheme for question 25(a)
(b)(i)

The student could not find a value for the boiling point of butanol, C4H9OH.

Use the graph to estimate the boiling point of butanol.

[1]

Answer
Mark scheme for question 25(b)(i)
(b)(ii)

Draw the displayed formula of butanol, C4H9OH.

[1]

Answer
Mark scheme for question 25(b)(ii)
(c)

The alcohols all react in a similar way because they all contain the same functional group

What is the functional group in an alcohol molecule?

[1]

Answer
Mark scheme for question 25(c)
(d)

Ethanol, C2H5OH, can be oxidised to ethanoic acid using potassium manganate(VII).

What is the formula of ethanoic acid?

[1]

Answer
Mark scheme for question 25(d)

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