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Chemistry A (Gateway) · OCR J248 · Paper 2 · Foundation · June 2019

OCR GCSE Chemistry A (Gateway) Paper 2 Foundation June 2019 question paper J248/02

1h 45m 90 marks

OCR J248 · Paper 2

23 questions
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Question 1

Which type of water is potable water?

A Groundwater

B Seawater

C Tap water

D Waste water

Question 1, shown as an image

[1]

Answer
Mark scheme for question 1

Question 2

Which of these elements is a transition metal ?

A Calcium

B Caesium

C Carbon

D Cobalt

Question 2, shown as an image

[1]

Answer
Mark scheme for question 2

Question 3

Lithium, sodium and potassium all react with water.

In all three reactions the same gas is produced.

What is the name of the gas?

A Carbon dioxide

B Chlorine

C Hydrogen

D Oxygen

Question 3, shown as an image

[1]

Answer
Mark scheme for question 3

Question 4

The rate of a reaction can be changed by adding a catalyst to the reaction mixture.

Which line of the table shows how the rate of reaction and the mass of the catalyst change as

Figure for question 4
Question 4, shown as an image

[1]

Answer
Mark scheme for question 4

Question 5

How was the Earth’s early atmosphere formed?

A Animals breathing

B Global warming

C Plants growing

D Volcanic activity

Question 5, shown as an image

[1]

Answer
Mark scheme for question 5

Question 6

Crude oil is a mixture of hydrocarbons.

Crude oil is separated into useful fractions.

Which of these mixtures of substances could be in a fraction from crude oil?

A C2H4, C4H10, C4H10O

B C2H4, C2H3Br, C4H10

C C2H6, C3H8, C4H10

D C2H6, C2H3Br, C4H10O

Question 6, shown as an image

[1]

Answer
Mark scheme for question 6

Question 7

Crude oil is separated into useful fractions by fractional distillation.

The diagram shows the useful fractions made in fractional distillation.

Figure for question 7

Which of these fractions has the weakest intermolecular forces?

A Bitumen

B Diesel oil

C Gases

D Petrol

Question 7, shown as an image

[1]

Answer
Mark scheme for question 7

Question 8

What type of reaction takes place between an alkene and hydrogen?

A Addition

B Dehydration

C Neutralisation

D Thermal decomposition

Question 8, shown as an image

[1]

Answer
Mark scheme for question 8

Question 9

The table shows the main stages in the life-cycle assessment of a manufactured product.

StageProcess
1Manufacturing the product
2Obtaining raw materials
3Disposing of the product
4Using the product

What is the correct order for the stages?

A 1, 2, 3, 4

B 1, 2, 4, 3

C 2, 1, 4, 3

D 2, 4, 1, 3

Question 9, shown as an image

[1]

Answer
Mark scheme for question 9

Question 10

The Haber process is used to make ammonia, NH3.

Question 10, shown as an image

What is the raw material for the nitrogen?

A Air

B Hydrochloric acid

C Natural gas

D Seawater

Question 10, shown as an image

[1]

Answer
Mark scheme for question 10

Question 11

Which statement describes the test for chlorine gas ?

A A lighted splint makes a squeaky pop.

B Limewater turns milky.

C A glowing splint re-lights.

D Damp litmus paper is bleached.

Question 11, shown as an image

[1]

Answer
Mark scheme for question 11

Question 12

Which statement describes the atom economy of a reaction?

A A measure of how many atoms in the reactants form the waste products.

B A measure of how many atoms in the reactants form the desired product.

C A measure of the actual yield of product compared to the predicted yield of product.

D A measure of how many atoms form waste products compared to desired products.

Question 12, shown as an image

[1]

Answer
Mark scheme for question 12

Question 13

Which statement describes the properties of transition metals ?

A High melting point, shiny when freshly cut and brittle.

B Good conductors of electricity, low density and low melting point.

C Good conductors of electricity, strong and malleable.

D Strong, malleable and low density.

Question 13, shown as an image

[1]

Answer
Mark scheme for question 13

Question 14

Which statement describes the advantages of instrumental methods of analysis?

A Instruments can analyse very small amounts and carry out the analyses slowly.

B Instruments are very accurate and use large amounts of substances.

C Instruments are very accurate and carry out the analyses slowly.

D Instruments are very accurate and can run all the time.

Question 14, shown as an image

[1]

Answer
Mark scheme for question 14

Question 15

The table shows the composition of the Earth’s early atmosphere compared with the atmosphere today.

NitrogenOxygenArgonCarbon dioxide
Percentage of gas in the early atmosphere40.50.595
Percentage of gas in the atmosphere today78210.90.04

Which gas has changed by the largest percentage from the early atmosphere to the atmosphere today?

A Nitrogen

B Oxygen

C Argon

D Carbon dioxide

Question 15, shown as an image

[1]

Answer
Mark scheme for question 15

Question 16

This question is about the corrosion of metals.

(a)

A student investigates the rusting of iron.

Fig. 16.1 shows the experiments she sets up.

Figure for question 16

Write about what the student would observe in each tube after one week.

Explain the observations.

Tube A........

Tube B........

Tube C........

[3]

Answer
Mark scheme for question 16(a)
(b)

Another student buys a new bicycle. The bicycle chain is made of iron.

The student decides to oil the chain to prevent it from rusting, as shown in Fig. 16.2.

Figure for question 16

Explain why oiling the chain will prevent the iron from rusting.

[2]

Answer
Mark scheme for question 16(b)
(c)

A galvanised iron bucket is made of iron coated with a layer of zinc.

After years of use, the zinc coating has become scratched.

The iron below the zinc has been exposed but the iron has not rusted.

Explain why the iron has not rusted.

[2]

Answer
Mark scheme for question 16(c)

Question 17

This question is about hydrocarbons.

The table shows some information about alkanes.

Figure for question 17
(a)

Complete the table.

[3]

Answer
Mark scheme for question 17(a)
(b)

Ethane is a saturated hydrocarbon.

Explain why ethane is called both a hydrocarbon and saturated.

[2]

Answer
Mark scheme for question 17(b)
(c)

A student has two test tubes. One contains ethane and one contains ethene.

Figure for question 17

The student added bromine water to each test tube.

Describe what she observes.

Ethane........

Ethene........

[2]

Answer
Mark scheme for question 17(c)
(d)

Ethane belongs to the homologous series called the alkanes.

What is the name of the homologous series that ethene belongs to?

[1]

Answer
Mark scheme for question 17(d)
(e)

Pentane, C5H12, is an alkane found in petrol.

Pentane undergoes complete combustion in excess oxygen, O2.

Carbon dioxide and water are made.

Write the balanced symbol equation for the complete combustion of pentane.

[2]

Answer
Mark scheme for question 17(e)

Question 18

This question is about the extraction of metals.

(a)

When iron oxide is heated with carbon, iron is made.

(a)(i)

Complete the word equation for this reaction.

Question 18, shown as an image

[1]

Answer
Mark scheme for question 18(a)(i)
(a)(ii)

Iron oxide is reduced during this reaction.

Explain how you can tell that iron oxide is reduced.

[1]

Answer
Mark scheme for question 18(a)(ii)
(b)
Figure for question 18
(b)(i)

Zinc is usually extracted from zinc oxide by heating zinc oxide with carbon.

Explain why. Use the reactivity series to help you.

[1]

Answer
Mark scheme for question 18(b)(i)
(b)(ii)

Aluminium is extracted from aluminium oxide by electrolysis.

Explain why. Use the reactivity series to help you.

[1]

Answer
Mark scheme for question 18(b)(ii)
(c)

The table shows some information about aluminium and zinc.

MetalCost of 1 kg (£)Amount in Earth’s crust (%)
Aluminium1.318.1
Zinc2.510.0078

Suggest two reasons why it could be more important to recycle zinc than aluminium.

Use information from the table to help you.

[2]

Answer
Mark scheme for question 18(c)
(d)

Aluminium alloys are often used to build aircraft.

A sample of an aluminium alloy contains 1.28 g of magnesium and 43.70 g of aluminium only.

Calculate the percentage of magnesium in this alloy.

Give your answer to 3 significant figures.

[4]

Answer
Mark scheme for question 18(d)

Question 19

The Haber process is used to make ammonia, NH3.

Question 19, shown as an image
(a)

The reaction reaches a dynamic equilibrium.

(a)(i)

What happens to the rate of the forward and backward reactions at dynamic equilibrium?

[1]

Answer
Mark scheme for question 19(a)(i)
(a)(ii)

What happens to the concentrations of the reacting substances at equilibrium?

[1]

Answer
Mark scheme for question 19(a)(ii)
(b)

Ammonia is used to make fertilisers.

Fertilisers usually contain nitrogen.

Name the two other elements that fertilisers usually contain.

[2]

Answer
Mark scheme for question 19(b)
(c)

Ammonium sulfate is a salt used as a fertiliser.

Ammonium sulfate can be made in a laboratory in a batch process.

Ammonia solution is titrated with dilute sulfuric acid to make a solution of ammonium sulfate, as shown in the diagram.

Figure for question 19

Describe how you would make dry crystals of ammonium sulfate from ammonium sulfate solution.

[2]

Answer
Mark scheme for question 19(c)
(d)

Calcium sulfate is another salt.

A student made some calcium sulfate.

Look at the method he used:

• pour 100 cm3 of calcium nitrate solution into a beaker

• add drops of sodium sulfate solution until a precipitate appears

• allow the precipitate to settle to the bottom of the beaker

• pour off the liquid

• use a spatula to transfer the solid calcium sulfate onto a piece of filter paper.

Describe and explain two ways that the student could improve his method to increase amount of pure, dry calcium sulfate made.

[4]

Answer
Mark scheme for question 19(d)

Question 20

Crude oil is separated into useful fractions using fractional distillation.

The table shows the percentages of crude oil fractions from different oil wells.

FractionPercentage of fraction in crude oil
Oil well XOil well YOil well Z
LPG2710
Petrol31025
Paraffin61520
Diesel71115
Fuel oil262928
Bitumen56282
(a)

Which oil well contains the highest percentage of low boiling point fractions?

Tick (✓) one box.

Figure for question 20

[1]

Answer
Mark scheme for question 20(a)
(b)

A barrel of crude oil from oil well Y has a mass of 139 kg.

Calculate the mass of fuel oil in this barrel.

[2]

Answer
Mark scheme for question 20(b)
(c)

Fractions from crude oil contain alkanes.

Alkanes have the general formula CnH2n+2.

Write the formula of hexadecane, the alkane with 16 carbon atoms.

[1]

Answer
Mark scheme for question 20(c)
(d)

A sample of decane was cracked.

Look at the diagram of the apparatus used.

Figure for question 20
(d)(i)

Describe how this apparatus is used to produce ethene from decane.

[2]

Answer
Mark scheme for question 20(d)(i)
(d)(ii)

One molecule of decane, C10H22, produced two molecules of ethene, C2H4, and one molecule of product Z.

Question 20, shown as an image

Write the formula for product Z.

[1]

Answer
Mark scheme for question 20(d)(ii)

Question 21

A student investigates the reaction between magnesium and dilute hydrochloric acid, HC l.

The student adds magnesium ribbon to hydrochloric acid in a beaker, as shown in the diagram.

Figure for question 21

Magnesium chloride, MgCl2, and hydrogen gas are made.

(a)

Write the balanced symbol equation for this reaction.

[2]

Answer
Mark scheme for question 21(a)
(b)
Figure for question 21 Figure for question 21

[6]

Answer
Mark scheme for question 21(b)
(c)

The student repeats experiment 1. This time he uses acid at a lower temperature.

Explain, using the reacting particle model, what happens to the rate of reaction and predict the reaction time for this reaction.

[3]

Answer
Mark scheme for question 21(c)
(d)

During chemical reactions, reactants are used up and the rate of reaction decreases.

Explain, in terms of particles, why the rate of reaction decreases.

[2]

Answer
Mark scheme for question 21(d)

Question 22

This question is about properties of materials.

Police bullet-resistant vests could be made from steel or Kevlar ®.

Figure for question 22

The table shows some information about steel and Kevlar®.

SteelKevlar®
Density (g / cm3)7.851.44
Relative strength15
Flexibilitylowhigh
Resistance to corrosionlowhigh
(a)

Describe and explain two reasons why bullet-resistant vests are made from Kevlar® instead of steel.

[4]

Answer
Mark scheme for question 22(a)
(b)
Figure for question 22

What type of molecule is Kevlar ® ?

[1]

Answer
Mark scheme for question 22(b)
(c)

Nanoparticles are being used to make a material that is better than Kevlar® at resisting bullets.

Nanoparticles are often made of silicon dioxide.

A silicon dioxide nanoparticle has a diameter of 18 nm.

The diameter of a silicon atom is 0.22 nm.

(c)(i)

Estimate how many times larger the silicon dioxide nanoparticle is, compared to a silicon atom.

Give your answer to 1 significant figure.

[3]

Answer
Mark scheme for question 22(c)(i)
(c)(ii)

Silicon dioxide is used as a catalyst.

Suggest why 1 g of silicon dioxide is more effective as a catalyst when used as nanoparticles rather than as a powder.

[3]

Answer
Mark scheme for question 22(c)(ii)

Question 23

Figure for question 23
(a)

Evaluate the information shown in the graph.

To what extent does the graph support a link between human activity and global warming?

[3]

Answer
Mark scheme for question 23(a)
(b)

There are problems with using information about CO2 emissions by fossil fuels to draw conclusions about the effect of carbon dioxide emissions on global sea levels.

Suggest what these problems are.

[2]

Answer
Mark scheme for question 23(b)
(c)(i)

Describe one effect on the Earth’s climate of increased carbon dioxide levels, other than rising sea levels.

[1]

Answer
Mark scheme for question 23(c)(i)
(c)(ii)

Suggest how we can lower carbon dioxide levels.

[1]

Answer
Mark scheme for question 23(c)(ii)

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