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Chemistry A (Gateway) · OCR J248 · Paper 3 · Higher · June 2019

OCR GCSE Chemistry A (Gateway) Paper 3 Higher June 2019 question paper J248/03

1h 45m 90 marks

OCR J248 · Paper 3

22 questions
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Question 1

Sodium is an element that can be found in the Periodic Table.

A sodium atom contains 11 electrons.

Which statement about sodium is true ?

A Sodium is in Group 2 of the Periodic Table.

B Sodium is in Period 2 of the Periodic Table.

C Sodium is in Period 3 of the Periodic Table.

D Sodium is in Group 3 of the Periodic Table.

Question 1, shown as an image

[1]

Answer
Mark scheme for question 1

Question 2

Carbon dioxide exists as a simple molecule.

Why do simple molecules have low boiling points?

A Simple molecules have weak covalent bonds between atoms.

B Simple molecules have weak intermolecular forces between atoms.

C Simple molecules have weak ionic bonds between the molecules.

D Simple molecules have weak intermolecular forces between the molecules.

Question 2, shown as an image

[1]

Answer
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Question 3

Mendeleev’s arrangement of elements led to our modern Periodic Table.

How did Mendeleev arrange the elements in his Periodic Table?

A In order of decreasing atomic mass and similar physical properties.

B In order of increasing atomic number and similar physical properties.

C In order of decreasing atomic number and similar chemical properties.

D In order of increasing atomic mass and similar chemical properties.

Question 3, shown as an image

[1]

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Question 4

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[1]

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Question 5

Carbon can form different allotropes.

Which of these are allotropes of carbon?

A Diamond, graphite, graphene.

B Diamond, granite, graphite.

C Fullerene, graphene, ethene.

D Granite, graphite, graphene.

Question 5, shown as an image

[1]

Answer
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Question 6

Magnesium reacts with copper oxide.

Magnesium oxide and copper are made.

Question 6, shown as an image

Which substance is the reducing agent ?

A Copper

B Copper oxide

C Magnesium

D Magnesium oxide

Question 6, shown as an image

[1]

Answer
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Question 7

The atomic radius of a helium atom is 0.031 nm.

What is the atomic radius of a helium atom in standard form?

3.1 × 10−1 A

3.1 × 10−2 B

3.1 × 10−3 C

3.1 × 10−4 D

Question 7, shown as an image

[1]

Answer
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Question 8

What is the electronic structure of sulfur?

A 2

B 2, 6

C 2, 8, 6

D 2, 8, 8, 6

Question 8, shown as an image

[1]

Answer
Mark scheme for question 8

Question 9

The melting point of bromine is −7 °C.

The boiling point of bromine is 59 °C.

What state would bromine be at room temperature?

A Aqueous

B Gas

C Liquid

D Solid

Question 9, shown as an image

[1]

Answer
Mark scheme for question 9

Question 10

Avogadro’s constant has a value of 6.02 × 1023. 10

How many oxygen atoms are in 0.25 moles of oxygen molecules?

1.204 × 1024 A

1.505 × 1023 B

3.010 × 1023 C

6.020 × 1023 D

Question 10, shown as an image

[1]

Answer
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Question 11

Methane burns in oxygen to form carbon dioxide and water.

Question 11, shown as an image

Calculate the amount of carbon dioxide made when 6.4 g of methane is burnt.

A 2.8 g

B 4.4 g

C 14.4 g

D 17.6 g

Question 11, shown as an image

[1]

Answer
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Question 12

Paper chromatography can be used to separate the colours in ink.

Water is the solvent used to separate the colours in water soluble ink.

What name is given to the water used in paper chromatography?

A Absorption phase

B Liquid phase

C Mobile phase

D Stationary phase

Question 12, shown as an image

[1]

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Question 13

Figure for question 13

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Question 14

During the electrolysis of molten lead bromide, bromine is made at the anode.

Which half equation shows that bromine is made at the anode?

Question 14, shown as an image
Question 14, shown as an image
Question 14, shown as an image
Question 14, shown as an image
Question 14, shown as an image

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Question 15

Which of these substances has a giant covalent structure ?

A Carbon dioxide

B Magnesium oxide

C Sulfur dioxide

D Silicon dioxide

Question 15, shown as an image

[1]

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Question 16

Lithium is a metal found in Group 1 of the Periodic Table.

(a)(i)

Describe the structure and bonding in a metal.

You may include a diagram in your answer.

[2]

Answer
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(a)(ii)

Lithium is malleable even though metallic bonds are strong.

Explain why metals are malleable.

[1]

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(a)(iii)

Lithium can conduct electricity in the solid and liquid state.

Explain why metals can conduct electricity.

[2]

Answer
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(b)
Figure for question 16

[2]

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(c)

The scientist uses the particle model to show the elements present in alloy B.

Look at her diagram.

Figure for question 16
(c)(i)

Calculate the percentage of lithium atoms in the diagram of alloy B.

[1]

Answer
Mark scheme for question 16(c)(i)
(c)(ii)

Use your answer to part (c)(i) to explain if the diagram accurately shows the structure of alloy B.

[1]

Answer
Mark scheme for question 16(c)(ii)

Question 17

A new sun cream has been developed using zinc oxide nanoparticles.

The small particles provide better protection from the sun and they do not leave white marks on the skin.

(a)

Explain one possible risk of using nanoparticles in sun cream.

[1]

Answer
Mark scheme for question 17(a)
(b)

A cube-shaped nanoparticle has sides of length 50 nm.

Figure for question 17

Calculate the surface area to volume ratio for this nanoparticle.

Use the equation: ratio = surface area ÷ volume

[4]

Answer
Mark scheme for question 17(b)
(c)(i)

Scientists compare the size of nanoparticles to the sizes of other small objects.

Question 17, shown as an image
ObjectDiameter (nm)
Gold atom0.14
Water molecule0.27
DNA strand2.5
Zinc oxide nanoparticle32
Red blood cell7000
Human hair100 000

The diameter of a DNA strand is 2.5 nm.

Explain why DNA is a nanoparticle but a water molecule is not a nanoparticle.

[2]

Answer
Mark scheme for question 17(c)(i)
(c)(ii)

Calculate how many zinc oxide nanoparticles would fit across a human hair.

Give your answer to 2 significant figures.

[2]

Answer
Mark scheme for question 17(c)(ii)

Question 18

Simple distillation can be used to separate mixtures of liquids.

A scientist is using simple distillation to separate a mixture of alcohols.

Look at the table. It shows the boiling points of three alcohols.

AlcoholBoiling point (°C)
Methanol65
Ethanol78
Propanol97
(a)(i)
Figure for question 18

[2]

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(a)(ii)

Simple distillation uses evaporation and condensation to separate mixtures.

Question 18, shown as an image

Describe the change in the arrangement of particles as substances evaporate.

[1]

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(a)(iii)

Describe the change in the movement of particles as substances evaporate.

[1]

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(a)(iv)

The scientist wants to improve the separation of the mixture of alcohols.

Suggest a piece of equipment he could use.

Explain how this will improve the separation of the mixture of alcohols.

[2]

Answer
Mark scheme for question 18(a)(iv)
(b)

Ethanol can be used as a biofuel. The combustion of ethanol is an exothermic reaction.

Explain why combustion is an exothermic reaction.

Use ideas about bond breaking and bond making in your answer.

[1]

Answer
Mark scheme for question 18(b)
(c)(i)

Methanol is another biofuel that can be used in combustion reactions.

Question 18, shown as an image

Look at the table. It shows some bond energies.

BondBond energy (kJ / mol)
C−H413
O=O498
C−O358
C=O805
O−H464

Calculate the energy transferred to break all the bonds in the reactants.

Energy transferred =........ kJ / mol

[2]

Answer
Mark scheme for question 18(c)(i)
(c)(ii)

Calculate the energy transferred when all the bonds form in the products.

Energy transferred =........ kJ / mol

[2]

Answer
Mark scheme for question 18(c)(ii)
(c)(iii)

Use your answers to parts (i) and (ii) to calculate the energy change for this reaction.

Energy change =........ kJ / mol

[1]

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Mark scheme for question 18(c)(iii)

Question 19

Figure for question 19
(a)(i)
Figure for question 19

[2]

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Mark scheme for question 19(a)(i)
(a)(ii)

What is meant by physical property?

[1]

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(b)

Element C burns in oxygen to make white clouds of its oxide.

Describe how you could test the oxide to find out if the element is a metal.

[3]

Answer
Mark scheme for question 19(b)
(c)(i)

Chlorine is a non-metal.

Chlorine has two common isotopes.

Look at the information about the common isotopes of chlorine.

Figure for question 19

Complete the table to show the atomic structure for each isotope of chlorine.

IsotopeNumber of protonsNumber of neutronsNumber of electrons
Chlorine-35.................................................................................
Chlorine-37.................................................................................

[2]

Answer
Mark scheme for question 19(c)(i)
(c)(ii)

Chlorine gas, Cl2, reacts with barium, Ba.

Barium chloride, BaCl2, is made.

Write a balanced half equation for chlorine in this reaction.

[1]

Answer
Mark scheme for question 19(c)(ii)
(c)(iii)

Barium chloride solution reacts with sodium sulfate solution, Na2SO4.

A white precipitate of barium sulfate, BaSO4, is made.

Write a balanced ionic equation to show the formation of barium sulfate.

Include state symbols.

[2]

Answer
Mark scheme for question 19(c)(iii)

Question 20

Figure for question 20
(a)(i)

Plot a graph of the pH value against the amount of hydrochloric acid added and draw a line of best fit.

[3]

Answer
Mark scheme for question 20(a)(i)
(a)(ii)

Use your graph to estimate the volume of hydrochloric acid when the pH is 10.

[1]

Answer
Mark scheme for question 20(a)(ii)
(a)(iii)
Figure for question 20

[1]

Answer
Mark scheme for question 20(a)(iii)
(a)(iv)

Acidic solutions contain hydrogen ions, H +. Alkaline solutions contain hydroxide ions, (iv) OH −.

Write the balanced ionic equation for neutralisation.

[1]

Answer
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(b)

Hydrochloric acid, HCl (aq), is a strong acid. Ethanoic acid, CH3COOH (aq), is a weak acid.

Explain the difference between a strong and a weak acid.

[2]

Answer
Mark scheme for question 20(b)
(c)(i)

Nitric acid, HNO3, is another strong acid.

Nitric acid has a pH of 2.

The teacher adds enough water to reduce the concentration of the nitric acid by a factor of 100.

Calculate the new pH of the nitric acid.

[2]

Answer
Mark scheme for question 20(c)(i)
(c)(ii)

Nitric acid, HNO3, can also neutralise sodium hydroxide, NaOH.

Sodium nitrate, NaNO3, and water are made.

Write a balanced symbol equation for this reaction.

[1]

Answer
Mark scheme for question 20(c)(ii)
(c)(iii)

Describe how dry sodium nitrate crystals can be made using this reaction.

[2]

Answer
Mark scheme for question 20(c)(iii)

Question 21

Sodium chloride, NaC l, is an ionic compound.

Sodium chloride forms a giant ionic lattice that can be represented using different models.

Look at the diagrams. They show two models of sodium chloride.

Figure for question 21

Space-filling model
Ball-and-stick model

(a)(i)

A scientist thinks the ball-and-stick model should be used to model ionic compounds.

Describe two limitations of using the ball-and-stick model for ionic compounds.

[2]

Answer
Mark scheme for question 21(a)(i)
(a)(ii)

Ionic compounds can also be modelled using a dot-and-cross diagram.

Draw a dot and cross diagram to show the ions in sodium chloride.

[2]

Answer
Mark scheme for question 21(a)(ii)
(b)

* A student investigates the electrolysis of potassium bromide solution.

Figure for question 21

He notices that different products are formed at each electrode.

Explain the formation of the products during the electrolysis of potassium bromide solution.

[6]

Answer
Mark scheme for question 21(b)

Question 22

Lead is most commonly extracted from an ore called galena, PbS.

(a)

Extracting lead from the galena ore involves two steps.

Step 1: The galena ore is roasted in air to produce lead oxide, PbO.

Step 2: The lead oxide is heated in a blast furnace with carbon.

(a)(i)

The reaction in step 1 is an exothermic reaction.

Draw a labelled reaction profile diagram for an exothermic reaction.

Label the activation energy and the energy change on your diagram.

Figure for question 22

[4]

Answer
Mark scheme for question 22(a)(i)
(a)(ii)

In step 2 the lead oxide is reduced by carbon.

Question 22, shown as an image

Explain, in terms of electron transfer, why carbon is called a reducing agent in this reaction.

[1]

Answer
Mark scheme for question 22(a)(ii)
(b)(i)

Solid lead reacts with nitric acid, HNO3.

Lead nitrate, Pb(NO3)2, nitrogen oxide, NO, and water are made.

Write a balanced symbol equation for this reaction.

[2]

Answer
Mark scheme for question 22(b)(i)
(b)(ii)

How many moles of lead nitrate would be produced if 20.7 g of lead reacts with nitric acid?

Give your answer to 2 significant figures.

[4]

Answer
Mark scheme for question 22(b)(ii)

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