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Chemistry A (Gateway) · OCR J248 · Paper 2 · Foundation · November 2021

OCR GCSE Chemistry A (Gateway) Paper 2 Foundation November 2021 question paper J248/02

1h 45m 90 marks

OCR J248 · Paper 2

22 questions
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Question 1

The burning of fossil fuels can produce gases that cause acid rain.

Which gas causes acid rain?

A Carbon monoxide

B Nitrogen

C Oxygen

D Sulfur dioxide

Question 1, shown as an image

[1]

Answer
Mark scheme for question 1

Question 2

The diagram shows the copper wires in a plug.

Figure for question 2

A Copper conducts electricity.

B Copper conducts heat.

C Copper is hard.

D Copper reacts only slowly with water.

Question 2, shown as an image

[1]

Answer
Mark scheme for question 2

Question 3

Which metal ion gives a lilac colour in a flame test?

A Copper

B Lithium

C Potassium

D Sodium

Question 3, shown as an image

[1]

Answer
Mark scheme for question 3

Question 4

Look at the diagram of a titration experiment.

Figure for question 4

What is the name of apparatus X ?

A Burette

B Conical flask

C Gas syringe

D Pipette

Question 4, shown as an image

[1]

Answer
Mark scheme for question 4

Question 5

Figure for question 5

[1]

Answer
Mark scheme for question 5

Question 6

The Earth’s early atmosphere was mostly carbon dioxide gas.

The Earth’s atmosphere now contains only about 0.04% carbon dioxide gas.

Which process decreased the amount of carbon dioxide in the Earth’s early atmosphere?

A Burning hydrogen

B Carbon dioxide absorbing the Sun’s energy

C Carbon dioxide dissolving in oceans

D Volcanic emissions

Question 6, shown as an image

[1]

Answer
Mark scheme for question 6

Question 7

Crude oil is separated into fractions by fractional distillation.

Look at the diagram of the fractions made in fractional distillation.

Figure for question 7

Which of these fractions has the smallest molecules?

A Bitumen

B Diesel oil

C Gases

D Petrol

Question 7, shown as an image

[1]

Answer
Mark scheme for question 7

Question 8

Transition metals have properties that are different from other metals in the Periodic Table.

Copper is a transition metal.

Which of the following describes copper?

A A metal which forms blue compounds.

B A metal which reacts violently with water.

C A metal with a low density that floats on water.

D A metal with a low melting point.

Question 8, shown as an image

[1]

Answer
Mark scheme for question 8

Question 9

A chemical cell has a voltage of 1.50 V.

What will the voltage be once the reactants are used up?

A 0.00 V

B 0.75 V

C 1.50 V

D 3.00 V

Question 9, shown as an image

[1]

Answer
Mark scheme for question 9

Question 10

Copper carbonate, CuCO3, decomposes when heated. Copper oxide, CuO, and carbon dioxide gas are made.

Question 10, shown as an image

12.4 g of copper carbonate decomposes to make 8.0 g of copper oxide.

How much carbon dioxide gas is made?

A 1.55 g

B 4.4 g

C 8.0 g

D 20.4 g

Question 10, shown as an image

[1]

Answer
Mark scheme for question 10

Question 11

Propene gas is bubbled into bromine water.

What happens to the colour of the bromine water?

A Changes from colourless to orange

B Changes from orange to colourless

C Stays colourless

D Stays orange

Question 11, shown as an image

[1]

Answer
Mark scheme for question 11

Question 12

Sodium reacts with fluorine to form sodium fluoride.

What is the correctly balanced symbol equation for this reaction?

Question 12, shown as an image
Question 12, shown as an image
Question 12, shown as an image
Question 12, shown as an image
Question 12, shown as an image

[1]

Answer
Mark scheme for question 12

Question 13

Look at the results of a titration experiment.

Titration 1 (rough)Titration 2Titration 3Titration 4
Volume of acid used (cm3)26.0025.2025.5025.60

What is the accurate average volume of acid used in the titration?

25.35 cm3 A

25.43 cm3 B

25.55 cm3 C

25.58 cm3 D

Question 13, shown as an image

[1]

Answer
Mark scheme for question 13

Question 14

Butene, pentene and hexene are alkenes. They are all members of the same homologous series.

Why are they members of the same homologous series?

A Their molecules differ by –CH3.

B They have the same general formula.

C They have the same molecular formula.

D They have the same physical properties.

Question 14, shown as an image

[1]

Answer
Mark scheme for question 14

Question 15

Butane is a hydrocarbon molecule with a low boiling point.

Which statement about butane is correct?

A Butane is a large molecule and has strong intermolecular forces.

B Butane is a large molecule and has weak intermolecular forces.

C Butane is a small molecule and has strong intermolecular forces.

D Butane is a small molecule and has weak intermolecular forces.

Question 15, shown as an image

[1]

Answer
Mark scheme for question 15

Question 16

This question is about the elements in Group 1 of the Periodic Table.

(a)

Group 1 elements all react in a similar way.

Explain why.

[1]

Answer
Mark scheme for question 16(a)
(b)

Lithium, sodium and potassium are Group 1 elements.

They react with water.

Figure for question 16

Look at the table.

Group 1 elementTime for element to react completely (s)Observations
Lithium24fizzes moves slowly on the surface of the water makes an alkaline solution
Potassium6fizzes vigorously and gas catches fire melts moves very quickly on the surface of the water makes an alkaline solution
Sodium14fizzes vigorously melts moves quickly on the surface of the water makes an alkaline solution

All three elements make the same gas when they react with water.

(b)(i)

What is the name of this gas?

[1]

Answer
Mark scheme for question 16(b)(i)
(b)(ii)

How would you test for this gas?

[2]

Answer
Mark scheme for question 16(b)(ii)
(b)(iii)

* Rubidium is another Group 1 element. It is below potassium in Group 1 of the Periodic Table.

Predict what you will see and the reaction time when rubidium reacts with water.

Include an equation for the reaction.

[6]

Answer
Mark scheme for question 16(b)(iii)

Question 17

This question is about some of the hydrocarbons found in crude oil.

Table 17.1 shows information about four hydrocarbons found in crude oil.

Figure for question 17
(a)

Ethane is a hydrocarbon.

What is meant by a hydrocarbon?

[2]

Answer
Mark scheme for question 17(a)
(b)

Look at the displayed formula for ethane.

Figure for question 17

Ethane is a saturated compound.

What is meant by a saturated compound?

[1]

Answer
Mark scheme for question 17(b)
(c)

Use the information in Table 17.1 to predict the boiling point of nonane.

[1]

Answer
Mark scheme for question 17(c)
(d)

Explain why a mixture of hexane, nonane and pentadecane can be separated by fractional distillation.

In your answer use information from Table 17.1 and ideas about intermolecular forces.

[3]

Answer
Mark scheme for question 17(d)
(e)

Nonane is one of the hydrocarbons found in aircraft fuel.

Nonane burns completely in a plentiful supply of oxygen.

Complete the balanced symbol equation by putting numbers on the dotted lines.

Question 17, shown as an image

[2]

Answer
Mark scheme for question 17(e)
(f)

Incomplete combustion of nonane makes carbon monoxide instead of carbon dioxide.

Describe and explain one problem caused by carbon monoxide.

[2]

Answer
Mark scheme for question 17(f)

Question 18

Ammonia, NH3, is made by the Haber process.

Look at the equation for the reaction.

Question 18, shown as an image
(a)
Question 18, shown as an image

[1]

Answer
Mark scheme for question 18(a)
(b)

Fig. 18.1 shows the percentage of ammonia made at different temperatures and pressures.

Figure for question 18
(b)(i)

What is the percentage of ammonia made at 350 °C and 200 atmospheres ?

[1]

Answer
Mark scheme for question 18(b)(i)
(b)(ii)

What temperature and pressure, shown on Fig. 18.1, make the highest percentage of ammonia?

Pressure =........ atmospheres

[1]

Answer
Mark scheme for question 18(b)(ii)
(c)

Ammonia reacts with nitric acid, HNO3, to form the fertiliser ammonium nitrate, NH4NO3.

Write the balanced symbol equation for this reaction.

[1]

Answer
Mark scheme for question 18(c)
(d)

Ammonium sulfate is another fertiliser that is made using ammonia.

State the name of the acid that reacts with ammonia to form ammonium sulfate.

[1]

Answer
Mark scheme for question 18(d)
(e)

State one reason why farmers add fertilisers to soil.

[1]

Answer
Mark scheme for question 18(e)
(f)

Some fertilisers must be dissolved in water before farmers can add them to the soil.

Fig. 18.2 shows information about the solubility of three fertilisers at different water temperatures.

Figure for question 18

Which fertiliser is most soluble in water at 20 °C?

Tick (✓) one box.

Question 18, shown as an image
Question 18, shown as an image

[1]

Answer
Mark scheme for question 18(f)
(g)

A student makes some ammonium sulfate in the laboratory.

This is the method she uses:

• Pour 25 cm3 of dilute ammonia solution into a conical flask.

• Add 2–3 drops of methyl orange indicator.

• Add dilute acid from a burette until the reaction is complete.

(g)(i)

Explain how the student can make sure that the reaction is complete.

[1]

Answer
Mark scheme for question 18(g)(i)
(g)(ii)

Ammonia solution releases small amounts of ammonia gas.

Ammonia is a colourless gas with a sharp, irritating smell.

Describe how to control one hazard when making ammonium sulfate.

[1]

Answer
Mark scheme for question 18(g)(ii)
(h)

Potassium nitrate, KNO3, is another fertiliser.

Potassium nitrate is made by reacting potassium hydroxide, KOH, with nitric acid, HNO3.

Question 18, shown as an image

Calculate the mass of potassium nitrate that can be made from 315 tonnes of nitric acid.

Give your answer to 3 significant figures.

(The relative atomic mass, Ar, of H is 1.0, of K is 39.1, of N is 14.0 and of O is 16.0).

Mass of potassium nitrate =........ tonnes

[4]

Answer
Mark scheme for question 18(h)

Question 19

A student investigates the rate of reaction between marble chips and dilute hydrochloric acid.

The student measures the volume of carbon dioxide gas given off every 30 seconds.

Look at the apparatus they use.

Figure for question 19
(a)

Suggest a piece of apparatus that the student could use to measure the volume of carbon dioxide more accurately.

[1]

Answer
Mark scheme for question 19(a)
(b)

Describe the test for carbon dioxide gas.

[2]

Answer
Mark scheme for question 19(b)
(c)

The graph shows the student’s results.

Figure for question 19
(c)(i)

What is the time taken to make 23 cm3 of carbon dioxide? (i)

[1]

Answer
Mark scheme for question 19(c)(i)
(c)(ii)

The student repeats the experiment. The only difference is they use larger marble chips.

Draw a line on the graph to show the results of this experiment.

[2]

Answer
Mark scheme for question 19(c)(ii)
(d)

The student made 0.073 g of carbon dioxide in their experiment.

They predicted that they should have made 0.088 g.

Calculate the percentage yield.

Give your answer to 2 significant figures.

[3]

Answer
Mark scheme for question 19(d)
(e)

Another student investigates the effect of changing the temperature of the dilute hydrochloric acid on the rate of the reaction.

The table shows the student’s results.

ExperimentTemperature (°C)Time for reaction to finish (s)
120107
23061
34035
45017

Describe and explain the effect of changing the temperature on the rate of the reaction.

Use the student’s results and the reacting particle model in your answer.

[3]

Answer
Mark scheme for question 19(e)

Question 20

Figure for question 20
(a)

Which metal in the table would you use to make the aircraft wing?

Explain your answer. Use information from the table to help you.

Metal........

Explanation........

[4]

Answer
Mark scheme for question 20(a)
(b)

Aluminium can be made into an alloy called duralumin.

Which metal is mixed with aluminium to make duralumin?

[1]

Answer
Mark scheme for question 20(b)
(c)

Iron corrodes. This is called rusting.

A student does an experiment to find out what conditions are needed to cause an iron nail to rust.

Look at the diagram of their experiment.

Figure for question 20

They leave the tubes for one week.

Predict in which tube the iron nail will rust.

Explain your answer.

Tube........

Explanation........

[4]

Answer
Mark scheme for question 20(c)
(d)

Describe and explain one way to prevent an iron bridge from rusting.

[2]

Answer
Mark scheme for question 20(d)

Question 21

Figure for question 21 Figure for question 21
(a)

Explain how the mass spectrum and the infrared spectrum show that the sample is ethanol, C2H5OH.

[3]

Answer
Mark scheme for question 21(a)
(b)

Mass spectrometry and infrared spectrometry are both examples of instrumental methods of analysis.

Describe two advantages of instrumental methods of analysis.

[2]

Answer
Mark scheme for question 21(b)
(c)

Ethanol, C2H5OH, burns in a plentiful supply of oxygen to form carbon dioxide and water.

This is an example of complete combustion.

(c)(i)

Write the balanced symbol equation for this reaction.

[2]

Answer
Mark scheme for question 21(c)(i)
(c)(ii)

If there is a limited supply of oxygen, incomplete combustion will happen.

Describe a disadvantage of incomplete combustion.

[1]

Answer
Mark scheme for question 21(c)(ii)
(d)

Ethanol, C2H5OH, can be dehydrated to make ethene, C2H4.

Question 21, shown as an image

Calculate the atom economy for the production of ethene from ethanol.

(The relative formula mass, Mr, of C2H5OH is 46.0 and of C2H4 is 28.0).

[2]

Answer
Mark scheme for question 21(d)

Question 22

A car manufacturer is designing a new car. They need to decide if the car will have a petrol engine or a diesel engine.

(a)

The car manufacturer carries out a life-cycle assessment for both types of car.

(a)(i)

Describe the purpose of a life-cycle assessment.

[1]

Answer
Mark scheme for question 22(a)(i)
(a)(ii)

Describe two examples of data, other than waste products and pollution, that could be included in a life-cycle assessment.

[2]

Answer
Mark scheme for question 22(a)(ii)
(b)

The graphs show the air emission results of a life-cycle assessment for a petrol car and a diesel car.

Figure for question 22
(b)(i)

At which stage are the most oxides of nitrogen produced by the diesel car ?

Tick (✓) one box.

Question 22, shown as an image

[1]

Answer
Mark scheme for question 22(b)(i)
(b)(ii)

The car manufacturer estimates that a petrol car produces 29.8 tonnes of carbon dioxide over its lifetime.

A diesel car produces only 20.5 tonnes of carbon dioxide over its lifetime.

Use the graphs to calculate the mass, in tonnes, of carbon dioxide produced by the petrol car and the diesel car during vehicle operation.

Use your answers to calculate the difference, in tonnes, in the mass of carbon dioxide produced by the petrol car and the diesel car during vehicle operation.

Give your final answer to 2 significant figures.

Mass of carbon dioxide produced by the petrol car =........ tonnes

Mass of carbon dioxide produced by the diesel car =........ tonnes

Difference in mass of carbon dioxide =........ tonnes

[4]

Answer
Mark scheme for question 22(b)(ii)

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