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Chemistry A (Gateway) · OCR J248 · Paper 2 · Foundation · June 2023

OCR GCSE Chemistry A (Gateway) Paper 2 Foundation June 2023 question paper J248/02

1h 45m 90 marks

OCR J248 · Paper 2

23 questions
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Question 1

A student does a flame test with a sample of potassium chloride.

Which colour is the flame?

A Lilac

B Green‑blue

C Red

D Yellow

Question 1, shown as an image

[1]

Answer
Mark scheme for question 1

Question 2

What is the test for chlorine gas?

A Damp universal indicator paper turns red then white

B Decolourises bromine water

C Limewater turns milky

D Relights a glowing splint

Question 2, shown as an image

[1]

Answer
Mark scheme for question 2

Question 3

Why do marble chips react faster with warm hydrochloric acid than with cold hydrochloric acid?

A The warm hydrochloric acid acts as a catalyst.

B The warm hydrochloric acid has more crowded particles.

C The warm hydrochloric acid has particles with more energy.

D The warm hydrochloric acid has particles that move slower.

Question 3, shown as an image

[1]

Answer
Mark scheme for question 3

Question 4

Which conditions are needed for the rusting of iron to happen?

A Air and no water

B Air and oil

C Air and salt

D Air and water

Question 4, shown as an image

[1]

Answer
Mark scheme for question 4

Question 5

What is the displayed formula of ethanol ?

Figure for question 5
Question 5, shown as an image

[1]

Answer
Mark scheme for question 5

Question 6

Tap water is treated to make it safe to drink.

Which substance is added to the tap water to kill bacteria and microbes?

A Aluminium sulfate

B Carbon dioxide

C Chlorine

D Iodine

Question 6, shown as an image

[1]

Answer
Mark scheme for question 6

Question 7

Methane is a hydrocarbon.

Which substance cannot be produced when methane burns in air?

A Carbon

B Carbon dioxide

C Hydrogen

D Water

Question 7, shown as an image

[1]

Answer
Mark scheme for question 7

Question 8

Brass is an alloy used to make musical instruments.

What are the main metals in brass?

A Aluminium and copper

B Copper and tin

C Copper and zinc

D Lead and tin

Question 8, shown as an image

[1]

Answer
Mark scheme for question 8

Question 9

What was the main gas in the Earth’s early atmosphere?

A Ammonia

B Carbon dioxide

C Nitrogen

D Oxygen

Question 9, shown as an image

[1]

Answer
Mark scheme for question 9

Question 10

Bromine reacts with sodium iodide.

What is the balanced symbol equation for the reaction?

Question 10, shown as an image
Question 10, shown as an image
Question 10, shown as an image
Question 10, shown as an image
Question 10, shown as an image

[1]

Answer
Mark scheme for question 10

Question 11

Ammonia is made in the Haber process.

Question 11, shown as an image

What happens when this reaction reaches equilibrium?

A The backward reaction happens at a faster rate than the forward reaction.

B The forward and backward reactions happen at the same rate.

C The forward and backward reactions stop happening.

D The forward reaction happens at a faster rate than the backwards reaction.

Question 11, shown as an image

[1]

Answer
Mark scheme for question 11

Question 12

Iron objects can be protected from rusting by coating them with a layer of zinc.

What is this process called?

A Galvanising

B Insulating

C Oxidation

D Reduction

Question 12, shown as an image

[1]

Answer
Mark scheme for question 12

Question 13

Calcium carbonate, CaCO3, thermally decomposes to make calcium oxide, CaO, and carbon dioxide.

Question 13, shown as an image

5.0 g of calcium carbonate makes 2.8 g of calcium oxide.

How much carbon dioxide is made?

A 2.2 g

B 2.8 g

C 4.4 g

D 7.8 g

Question 13, shown as an image

[1]

Answer
Mark scheme for question 13

Question 14

Crude oil is a resource that is being made extremely slowly.

Which word describes a resource that is being made extremely slowly?

A Finite

B Hydrocarbon

C Non‑renewable

D Petrochemical

Question 14, shown as an image

[1]

Answer
Mark scheme for question 14

Question 15

The Group 7 element fluorine is a gas at room temperature and pressure.

The Group 7 elements show a trend in boiling points going down the group.

Which row shows the boiling points of the Group 7 elements?

Boiling Point (C)
FluorineChlorineBromineIodine
A–18859184–15
B–188–3459184
C18818459–15
D–1518418859
Question 15, shown as an image

[1]

Answer
Mark scheme for question 15

Question 16

Figure for question 16
(a)

The teacher says that the reaction is faster with magnesium powder than with magnesium ribbon.

Use the results to explain why the teacher is correct.

[2]

Answer
Mark scheme for question 16(a)
(b)(i)

Describe how the rate of reaction changes when the concentration of the hydrochloric acid increases.

[1]

Answer
Mark scheme for question 16(b)(i)
(b)(ii)

Explain your answer to (i) using ideas about particles.

[2]

Answer
Mark scheme for question 16(b)(ii)
(c)

The teacher used 0.1 g of magnesium.

0.1 g of magnesium reacts with hydrochloric acid to make 0.008 g of hydrogen gas.

A student suggests that the rate of reaction could be investigated by measuring the loss in mass during the reaction.

Suggest why this method would not work well.

[1]

Answer
Mark scheme for question 16(c)
(d)

Describe the test for hydrogen gas.

[2]

Answer
Mark scheme for question 16(d)
(e)

In another experiment, the teacher reacts 0.1 g of zinc with excess hydrochloric acid.

Question 16, shown as an image

Calculate the mass of hydrogen gas made.

Relative atomic mass (Ar): H = 1.0 Zn = 65.4

[3]

Answer
Mark scheme for question 16(e)

Question 17

The table shows information about the physical properties of four elements, W, X, Y and Z.

WXYZ
Density (g / cm3)0.977.870.0031.74
Melting point (C)981538–102650
Conducts electricity?✓✓✗✓
(a)

Which element is a non‑metal?

Give a reason for your answer.

Element........

Reason........

[2]

Answer
Mark scheme for question 17(a)
(b)

One of the elements is sodium in Group 1.

Which element is sodium?

Give a reason for your answer.

Element........

Reason........

[2]

Answer
Mark scheme for question 17(b)
(c)

One of the elements is a transition metal.

(c)(i)

Compare the physical and chemical properties of Group 1 metals and transition metals. Use the information in the table, and your own knowledge.

[3]

Answer
Mark scheme for question 17(c)(i)
(c)(ii)

Transition metals can be used as catalysts.

What is meant by a catalyst?

[2]

Answer
Mark scheme for question 17(c)(ii)
(d)
Figure for question 17

[2]

Answer
Mark scheme for question 17(d)
(e)

Iron reacts with dilute sulfuric acid, H2SO4.

Iron sulfate, FeSO4, and hydrogen gas, H2, are made.

(e)(i)

Write the balanced symbol equation for this reaction.

[1]

Answer
Mark scheme for question 17(e)(i)
(e)(ii)

A student reacts 2.8 g of iron with dilute sulfuric acid.

The student makes 5.4 g of iron sulfate.

They predicted that they should have made 7.6 g of iron sulfate.

Calculate their percentage yield.

Give your answer to 1 decimal place.

[3]

Answer
Mark scheme for question 17(e)(ii)

Question 18

Propane, C3H8, is an alkane.

Propane undergoes complete combustion in oxygen. Carbon dioxide and water are made.

(a)

Write the balanced symbol equation for the complete combustion of propane.

[2]

Answer
Mark scheme for question 18(a)
(b)

The table shows the energy given out when 1 g of different alkanes burn.

AlkaneNumber of carbon atomsEnergy given out (kJ)
methane155.6
ethane252.6
propane350.4
butane4
pentane548.7
hexane648.4
(b)(i)

Plot a graph of the data from the table.

[2]

Answer
Mark scheme for question 18(b)(i)
(b)(ii)

Draw a curve of best fit on your graph.

Figure for question 18

[1]

Answer
Mark scheme for question 18(b)(ii)
(b)(iii)

The energy given out when 1 g of butane burns is missing from the table.

Use the graph to estimate the energy given out by butane.

[1]

Answer
Mark scheme for question 18(b)(iii)
(b)(iv)

What name is given to the type of reaction that gives out energy ?

[1]

Answer
Mark scheme for question 18(b)(iv)
(c)

Complete the displayed formula of propane, C3H8.

Figure for question 18

[1]

Answer
Mark scheme for question 18(c)
(d)

Combustion of alkanes makes carbon dioxide gas.

(d)(i)

State an environmental problem caused by increased levels of carbon dioxide gas.

[1]

Answer
Mark scheme for question 18(d)(i)
(d)(ii)

Explain how this environmental problem can be reduced.

[1]

Answer
Mark scheme for question 18(d)(ii)

Question 19

A student plans a titration experiment.

The diagram shows some of the apparatus they use.

Figure for question 19
(a)
Figure for question 19

[4]

Answer
Mark scheme for question 19(a)
(b)

This is the equation for the reaction in the experiment.

Question 19, shown as an image
(b)(i)

What type of reaction is this?

Tick (✓) one box.

Question 19, shown as an image

[1]

Answer
Mark scheme for question 19(b)(i)
(b)(ii)

Water is a waste product in this reaction.

Calculate the atom economy for the reaction.

Relative atomic mass (Ar): H = 1.0 O = 16.0 Na = 23.0 Cl = 35.5

[3]

Answer
Mark scheme for question 19(b)(ii)

Question 20

Crude oil is separated into different fractions by fractional distillation.

Table 20.1 shows information about three of the molecules that are found in three different fractions.

Table 20.1

MoleculeFormulaBoiling point (C)
nonaneC9H20151
heptadecaneC17H36302
octacosaneC28H58436
(a)

Which of these three molecules would be separated highest up the fractionating column?

Explain your answer using ideas about molecular size and boiling point.

Molecule........

Reason........

[3]

Answer
Mark scheme for question 20(a)
(b)

Cracking breaks down large molecules produced in fractional distillation into more useful molecules.

The equation shows the cracking of octacosane.

Question 20, shown as an image

octacosane dodecane molecule X

(b)(i)

State the name of molecule X, C2H4.

[1]

Answer
Mark scheme for question 20(b)(i)
(b)(ii)

Molecule X has the general formula CnH2n.

Octacosane and dodecane are both alkanes and have a different general formula.

State the general formula of the alkanes.

[1]

Answer
Mark scheme for question 20(b)(ii)
(c)

Table 20.2 shows the percentage supply and percentage demand for some of the different fractions obtained from crude oil.

Table 20.2

FractionPercentage supply (%)Percentage demand (%)
LPG24
petrol523
naphtha8
kerosene127
diesel oil1723
fuel oil5638
(c)(i)

Calculate the percentage demand for naphtha.

[1]

Answer
Mark scheme for question 20(c)(i)
(c)(ii)

Suggest why fuel oil, rather than diesel oil, is cracked to obtain petrol.

[1]

Answer
Mark scheme for question 20(c)(ii)

Question 21

Figure for question 21 Figure for question 21

[6]

Answer
Mark scheme for question 21

Question 22

A student investigates two solutions, A and B.

They know that

• one solution contains a halide ion

• the other solution contains a different anion.

They test 2 cm3 of each solution for the halide ion using this method:

• Add a few drops of dilute hydrochloric acid and shake.

• Add a few drops of silver nitrate solution.

• Record the colour of the precipitate.

(a)

The teacher says that the student should have used a different acid instead of dilute hydrochloric acid.

(a)(i)

State the name of the acid the student should have used.

[1]

Answer
Mark scheme for question 22(a)(i)
(a)(ii)

Explain why using dilute hydrochloric acid would affect the results of this test.

[2]

Answer
Mark scheme for question 22(a)(ii)
(b)
Figure for question 22

[2]

Answer
Mark scheme for question 22(b)
(c)
Figure for question 22

[3]

Answer
Mark scheme for question 22(c)
(d)

Barium chloride solid is toxic if swallowed and harmful if inhaled.

Barium chloride solutions with concentrations of 21 g / dm3 are suitable for experiments in school.

Calculate the mass of barium chloride that should be dissolved in 25 cm3 of water to make a solution with a concentration of 21 g / dm3.

Use the equation:

Question 22, shown as an image

Give your answer to 2 significant figures.

[3]

Answer
Mark scheme for question 22(d)

Question 23

The table shows information about three different polymers, A, B and C.

Tensile strength is the amount of load a material can take before it breaks.

Melting point (C)Softening temperature (C)Stiffness (MPa)Tensile strength (MPa)
A1307298015
B24095320065
C25075240050
(a)

A company wants to use a polymer to make a disposable cup for hot drinks.

Suggest and explain which polymer, A, B or C, the company should use.

Polymer........

Reason........

[3]

Answer
Mark scheme for question 23(a)
(b)

This is the repeating unit in polymer B.

Figure for question 23

Draw the structure of the monomer from which polymer B is made.

[2]

Answer
Mark scheme for question 23(b)
(c)

Some substances are naturally occurring polymers.

Draw lines to connect each monomer with its naturally occurring polymer.

Figure for question 23

[2]

Answer
Mark scheme for question 23(c)

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