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Chemistry A (Gateway) · OCR J248 · Paper 1 · Foundation · June 2023

OCR GCSE Chemistry A (Gateway) Paper 1 Foundation June 2023 question paper J248/01

1h 45m 90 marks

OCR J248 · Paper 1

22 questions
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Question 1

Where is most of the mass found in an atom?

A Electrons

B Neutrons

C Nucleus

D Protons

Question 1, shown as an image

[1]

Answer
Mark scheme for question 1

Question 2

Sodium fluoride has the formula NaF. The formula of the sodium ion is Na +. 2

What is the formula of the fluoride ion?

F + A

F – B

F2+ C

F2– D

Question 2, shown as an image

[1]

Answer
Mark scheme for question 2

Question 3

Which row of results shows that the pH of a solution is acidic ?

pHUniversal indicator colour
A3orange
B10blue
C3blue
D10orange
Question 3, shown as an image

[1]

Answer
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Question 4

Thomson discovered the first sub-atomic particle.

Which sub-atomic particle did Thomson discover?

A Atom

B Electron

C Neutron

D Proton

Question 4, shown as an image

[1]

Answer
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Question 5

What is the relative formula mass of iron chloride, FeCl3?

Relative atomic mass (Ar): Cl = 35.5 Fe = 55.8.

A 91.3

B 126.8

C 162.3

D 202.9

Question 5, shown as an image

[1]

Answer
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Question 6

An element gains electrons to form a full outer shell.

Which part of the Periodic Table will the element be from?

Figure for question 6
Question 6, shown as an image

[1]

Answer
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Question 7

Why can the mass of a reaction in an open conical flask decrease?

A One of the products is a gas.

B One of the products is a solid.

C One of the reactants is a liquid.

D One of the reactants is a solid.

Question 7, shown as an image

[1]

Answer
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Question 8

When the model of the atom was developed, scientists reviewed the work of other scientists.

Why is it important for scientists to review each other’s work?

A They will copy the experiments to complete the research first.

B They will evaluate the data and suggest improvements.

C They will make sure that personal protective equipment is worn.

D They will start an argument about who is correct.

Question 8, shown as an image

[1]

Answer
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Question 9

Which reaction profile has an arrow showing the activation energy ?

Figure for question 9
Question 9, shown as an image
Figure for question 9
Question 9, shown as an image
Question 9, shown as an image

[1]

Answer
Mark scheme for question 9

Question 10

63.5 g of copper reacts to make 134.5 g of copper chloride, CuCl2.

Question 10, shown as an image

How much copper chloride will be made from 0.635 g of copper?

A 0.01345 g

B 0.1345 g

C 1.345 g

D 13.45 g

Question 10, shown as an image

[1]

Answer
Mark scheme for question 10

Question 11

Why are nanoparticles useful as catalysts in chemical reactions?

A Nanoparticles are a new technology.

B Nanoparticles have a high surface area to volume ratio.

C Nanoparticles have a large particle size.

D Nanoparticles have a low surface area to volume ratio.

Question 11, shown as an image

[1]

Answer
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Question 12

The melting point of magnesium chloride is 714 °C.

Which state symbols are used for magnesium chloride at these temperatures?

State symbol at 25 °CState symbol at 110 °C
Agg
Bss
Csg
Dgs
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[1]

Answer
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Question 13

What changes did Mendeleev make to improve his Periodic Table?

A He arranged elements by mass number.

B He arranged elements by the number of neutrons.

C He put elements with low melting points on the left and high melting points on the right.

D He realised some elements had not yet been discovered so left spaces for them.

Question 13, shown as an image

[1]

Answer
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Question 14

Nitrogen monoxide, NO, can be oxidised to form nitrogen dioxide, NO2.

Question 14, shown as an image

What is the oxidising agent in this reaction?

A Nitrogen

B Nitrogen dioxide

C Nitrogen monoxide

D Oxygen

Question 14, shown as an image

[1]

Answer
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Question 15

Hydrochloric acid, HC l, reacts with magnesium, Mg.

Magnesium chloride and hydrogen are made.

What is the balanced symbol equation for this reaction?

Question 15, shown as an image
Question 15, shown as an image
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Question 15, shown as an image

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Question 16

(a)

Oxygen is a gas at room temperature.

(a)(i)

The diagrams show three different particle models.

Figure for question 16

Which particle model represents a gas ?

Tick (✓) one box.

Question 16, shown as an image

[1]

Answer
Mark scheme for question 16(a)(i)
(a)(ii)

Oxygen has a melting point of –219 °C and a boiling point of –183 °C.

State a temperature at which oxygen will be a liquid.

[1]

Answer
Mark scheme for question 16(a)(ii)
(a)(iii)

Complete the sentences about the particle models.

Use words from the list.

condensing freezing less melting more

A liquid becoming a solid is called........ In a solid, the particles

move........ than in a liquid. In a solid, the arrangement of particles is

........ random than in a liquid.

[3]

Answer
Mark scheme for question 16(a)(iii)
(b)

Draw lines to connect each particle with its correct description.

Figure for question 16

[2]

Answer
Mark scheme for question 16(b)
(c)

The element oxygen has three different isotopes.

Figure for question 16

Isotope 1 Isotope 2 Isotope 3

(c)(i)

Which isotope has the highest mass?

[1]

Answer
Mark scheme for question 16(c)(i)
(c)(ii)

Which isotope has the same number of protons and neutrons?

[1]

Answer
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(c)(iii)

Atoms of each isotope have the same number of electrons.

How many electrons do these atoms have?

[1]

Answer
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(d)

A sample of air contains all three isotopes of oxygen. It contains 99.759% of isotope 1 and 0.037% of isotope 2.

Calculate the percentage of isotope 3 in the sample of air.

[2]

Answer
Mark scheme for question 16(d)

Question 17

A scientist measures the melting points of three painkillers.

PainkillerMelting point (°C)
A136
B169
C76
(a)

All of the painkillers are pure substances.

(a)(i)

Explain what is meant by a pure substance.

[1]

Answer
Mark scheme for question 17(a)(i)
(a)(ii)

How can you tell that the three painkillers are pure from their melting points?

[1]

Answer
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(b)

The scientist uses gas chromatography to investigate a mixture of painkiller A and painkiller B.

How many peaks will the scientist see in the gas chromatogram?

[1]

Answer
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(c)

The scientist then analyses painkiller D using thin layer chromatography.

The chromatogram is shown in the diagram.

Figure for question 17
(c)(i)

Calculate the Rf value of painkiller D.

Question 17, shown as an image

Give your answer to 2 decimal places.

[3]

Answer
Mark scheme for question 17(c)(i)
(c)(ii)

Which components are needed for thin layer chromatography?

Question 17, shown as an image

balance
Bunsen burner
mobile phase

paper
stationary phase
thermometer

[2]

Answer
Mark scheme for question 17(c)(ii)
(d)

The scientist thinks that an impure painkiller will only have two spots on the thin layer chromatogram.

Give two reasons why the scientist is incorrect.

[2]

Answer
Mark scheme for question 17(d)

Question 18

Molecules can be shown by different models.

(a)

Draw three lines to connect each name to its correct model.

Figure for question 18

[3]

Answer
Mark scheme for question 18(a)
(b)

A student wants to use a model to show the location of the electrons in a water molecule as shown in Fig. 18.1.

Fig. 18.1

Figure for question 18

Model 1 Model 2

Explain why the student uses model 1 instead of model 2.

[2]

Answer
Mark scheme for question 18(b)
(c)

Fig. 18.2 shows a model of octane.

Fig. 18.2

Key

Question 18, shown as an image
Figure for question 18
(c)(i)

What is the empirical formula of octane?

[1]

Answer
Mark scheme for question 18(c)(i)
(c)(ii)

Calculate the relative formula mass of octane.

Relative atomic mass (Ar): C = 12.0 H = 1.0.

[3]

Answer
Mark scheme for question 18(c)(ii)
(d)

Fig. 18.3 shows a model of a carbon nanotube.

Fig. 18.3

Figure for question 18
(d)(i)

What is the diameter of the carbon nanotube in nanometres ?

[1]

Answer
Mark scheme for question 18(d)(i)
(d)(ii)

Fig. 18.4 shows a model of the structure and bonding in graphite.

Fig. 18.4

Figure for question 18

Explain why the carbon nanotube is stronger than graphite.

Use Fig. 18.3 and Fig. 18.4.

[2]

Answer
Mark scheme for question 18(d)(ii)
(d)(iii)

A hydrogen atom has a diameter of 2.4 10–10 m. (iii) maths symbol

Calculate how many times larger the carbon nanotube is than the hydrogen atom.

[2]

Answer
Mark scheme for question 18(d)(iii)

Question 19

The table shows the type of bonding in three substances.

SubstanceType of bonding
Bromine, Br2simple molecular (covalent)
Sodium chloride, NaClionic
Diamond, Cgiant covalent
(a)

* Describe and compare the types of bonding in these three substances.

Predict which substance will have the lowest melting point.

[6]

Answer
Mark scheme for question 19(a)
(b)

Titanium is a metal element. Metal elements can be mixed with other elements to form metal alloys.

Figure for question 19

Metal element
Metal alloy

(b)(i)

Explain why a metal alloy is harder than a metal element.

[2]

Answer
Mark scheme for question 19(b)(i)
(b)(ii)

In medicine, titanium alloys are used in hip replacements.

The table shows some properties of alloys. Tensile strength is the amount of load a material can take before it breaks.

Alloy(g / cmDensity
3)
Tensile strength (MPa)Does it contain any toxic elements?
14.43950yes
24.52950no
35.70546no

Which alloy would be best to use in a hip replacement? Explain your answer.

Alloy........

Reason........

[3]

Answer
Mark scheme for question 19(b)(ii)

Question 20

A teacher wants to make hydrogen and chlorine using electrolysis.

(a)

Some possible steps they can use in the electrolysis experiment are listed.

1. Put test tubes over the electrodes to collect gases.

2. Weigh each electrode.

3. Put the electrodes into a solution of sodium chloride.

4. Put on safety goggles.

5. Connect the battery.

6. Put the electrodes into solid sodium chloride.

Put the four steps that the teacher should use in the correct order.

Figure for question 20

[3]

Answer
Mark scheme for question 20(a)
(b)

Chlorine is in Period 3 and Group 7 of the Periodic Table.

Which statements about chlorine are correct ?

Tick (✓) two boxes.

Question 20, shown as an image

[2]

Answer
Mark scheme for question 20(b)
(c)

The teacher sets up another electrolysis experiment using copper sulfate solution, CuSO

The table shows their results.

ExperimentMass of copper made (mg)Volume of oxygen made (cm3)
17.92.8
221.17.5
328.210.0
435.3
542.414.9
(c)(i)

Estimate how much oxygen will be made in experiment 4.

[1]

Answer
Mark scheme for question 20(c)(i)
(c)(ii)

Describe the relationship between the amount of copper made and the amount of oxygen made.

[1]

Answer
Mark scheme for question 20(c)(ii)
(d)

Copper sulfate solution is an electrolyte.

What type of compound is an electrolyte?

Tick (✓) one box.

Question 20, shown as an image

[1]

Answer
Mark scheme for question 20(d)
(e)

Another teacher repeats the electrolysis experiment.

They record the mass of the electrode at the start of the experiment.

At the end of the experiment, they remove the electrode from the solution and record the mass immediately as shown in the diagram.

Figure for question 20

They notice that the mass is higher than they expect.

Suggest two changes the teacher could make to get a more accurate mass.

[2]

Answer
Mark scheme for question 20(e)

Question 21

A scientist is studying acids and alkalis.

(a)

Which statement about acids and alkalis is correct ?

Tick (✓) one box.

Question 21, shown as an image

[1]

Answer
Mark scheme for question 21(a)
(b)

The scientist reacts sulfuric acid with insoluble magnesium carbonate, MgCO3.

They repeat the experiment two more times.

The table shows their results.

Experiment 1Experiment 2Experiment 3
Mass of magnesium sulfate, MgSO4, produced (g)4.374.314.38
Mass of magnesium carbonate, MgCO3, remaining (g)1.331.381.32
(b)(i)

Calculate the mean mass of magnesium sulfate, MgSO4, made.

Give your answer to 3 significant figures.

[3]

Answer
Mark scheme for question 21(b)(i)
(b)(ii)

Complete the balanced symbol equation for the reaction.

Include state symbols.

Question 21, shown as an image

[2]

Answer
Mark scheme for question 21(b)(ii)
(b)(iii)

How does the scientist remove the unreacted solid magnesium carbonate, MgCO3(s)?

[1]

Answer
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(b)(iv)

How does the scientist obtain pure dry magnesium sulfate crystals from magnesium sulfate solution?

[1]

Answer
Mark scheme for question 21(b)(iv)

Question 22

(a)

A student does an experiment to find out the temperature change of the reaction between an acid and an alkali.

The diagram shows the student’s experiment.

(a)(i)

Label the equipment in the diagram.

Figure for question 22

[3]

Answer
Mark scheme for question 22(a)(i)
(a)(ii)

Suggest one change the student can make so that the temperature change is measured more accurately. Use the diagram.

[1]

Answer
Mark scheme for question 22(a)(ii)
(b)

The student adds the acid, 5 cm3 at a time, to the alkali in the beaker. (b)

The student records the temperature of the solution after each addition of acid.

The table shows their results.

Volume of acid (cm3)Temperature (°C)
018
520
1023
1526
2027
2526
3024
(b)(i)

Plot the results from the table on the grid.

Figure for question 22

[2]

Answer
Mark scheme for question 22(b)(i)
(b)(ii)

Describe what happens to the temperature measured as the acid is added.

[2]

Answer
Mark scheme for question 22(b)(ii)
(b)(iii)

The reaction is exothermic.

Explain how you can tell this from the student’s results.

[1]

Answer
Mark scheme for question 22(b)(iii)
(c)

The activation energy for the student’s reaction is 132 kJ / mol.

Complete the sentence to state the meaning of activation energy.

Activation energy is the minimum........

[1]

Answer
Mark scheme for question 22(c)

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