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Chemistry B (21st Century) · OCR J258 · Paper 1 · June 2019

OCR GCSE Chemistry B (21st Century) Paper 1 June 2019 question paper

OCR J258 · Paper 1

12 questions
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Question 1

Chemists add chlorine to water. This makes the water suitable to drink.

(a)

Choose the test for chlorine.

Tick (✓) one box.

Question 1, shown as an image

[1]

Answer
Mark scheme for question 1(a)
(b)

Choose words from the list below to complete the sentences.

You may use each word once, more than once, or not at all.

animals diseases microorganisms smelly toxic

Chlorine is used to kill........ in water.

This stops the untreated water from causing........

Chlorine can be hazardous because it is........

[3]

Answer
Mark scheme for question 1(b)
(c)

A chlorine atom has seven electrons in its outer shell.

Complete the ‘dot and cross’ diagram for an HC l molecule.

You only need to show outer-shell electrons.

Figure for question 1

[2]

Answer
Mark scheme for question 1(c)

Question 2

2 ‘Camping gas’ contains butane.

Figure for question 2

Fig. 2.1 shows a model of butane. The model helps us to imagine what butane looks like.

Figure for question 2
(a)

Fig. 2.1 is called a ‘ball and stick’ model.

(a)(i)

What do the ‘sticks’ show?

Question 2, shown as an image

covalent bonds

intermolecular forces

ionic bonds

shared electrons

[2]

Answer
Mark scheme for question 2(a)(i)
(a)(ii)

Which statement is correct about the model of butane shown in Fig. 2.1 ?

Tick (✓) one box.

Question 2, shown as an image

[1]

Answer
Mark scheme for question 2(a)(ii)
(b)
Figure for question 2

[2]

Answer
Mark scheme for question 2(b)
(c)

58 g of butane contain 48 g of carbon.

What is the percentage of carbon in butane?

Give your answer to 2 significant figures.

[3]

Answer
Mark scheme for question 2(c)

Question 3

This question is about the efficiency of LED light-bulbs in 2015 compared to 2011.

Figure for question 3

The table shows part of a life-cycle assessment for the two light-bulbs. The numbers in the table compare the energy used to give the same amount of light in a certain time.

Stage in life cycle2011 light (MJ)2015 light (MJ)
Manufacture343132
Transport32
Use of the light-bulb35401630
Total energy used
(a)(i)

Which stage uses the most energy?

[1]

Answer
Mark scheme for question 3(a)(i)
(a)(ii)

In total, the 2011 light-bulb uses more energy than the 2015 light-bulb.

Calculate the difference in the total energy used.

[2]

Answer
Mark scheme for question 3(a)(ii)
(b)

The last stage in the life-cycle assessment is missing.

Name the last stage.

[1]

Answer
Mark scheme for question 3(b)
(c)

The percentage decrease in energy use at ‘manufacture’ stage from 2011 to 2015 is given by:

Question 3, shown as an image

Calculate the percentage decrease in energy use at ‘use of the light-bulb’ stage from 2011 to 2015.

Give your answer to 2 significant figures.

[2]

Answer
Mark scheme for question 3(c)

Question 4

Some cars use hydrogen fuel cells.

This is the reaction that happens in the fuel cell:

Question 4, shown as an image
(a)

Name the product of this reaction.

[1]

Answer
Mark scheme for question 4(a)
(b)

Most cars still use petrol as a fuel.

Give two advantages of using hydrogen as a fuel for cars.

[2]

Answer
Mark scheme for question 4(b)
(c)

The reaction profile below shows the energy changes when hydrogen and oxygen react together.

Figure for question 4

You may use each letter once, more than once, or not at all.

(c)(i)

Which arrow, A, B, or C, shows the activation energy for the reaction?........

[1]

Answer
Mark scheme for question 4(c)(i)
(c)(ii)

Which arrow, A, B, or C, shows that the reaction is exothermic?........

[1]

Answer
Mark scheme for question 4(c)(ii)
(d)(i)

Calculate the relative formula mass of H2O.

Relative formula mass of H2O =........

[1]

Answer
Mark scheme for question 4(d)(i)
(d)(ii)

4 g of hydrogen burns giving out 240 kJ of energy.

How much energy is given out when 20 g of hydrogen burns?

[2]

Answer
Mark scheme for question 4(d)(ii)

Question 5

A chemist makes a teaspoon out of gallium metal.

Gallium looks like aluminium. Gallium melts at 30 °C and aluminium melts at 660 °C.

Figure for question 5
(a)

Tea is made with boiling water.

What would happen if a gallium spoon is used to stir hot tea?

Explain your answer.

[2]

Answer
Mark scheme for question 5(a)
(b)

When Mendeleev made his Periodic Table, he left a gap below aluminium.

Later gallium was discovered and put into this gap.

Give one reason why gallium fitted into this gap.

Tick (✓) one box.

Question 5, shown as an image

[1]

Answer
Mark scheme for question 5(b)
(c)

When gallium reacts it loses three electrons.

Which ion is formed?

Question 5, shown as an image

Ga Ga+ Ga2+ Ga3+ Ga− Ga2− Ga3−

[1]

Answer
Mark scheme for question 5(c)
(d)

Ionic compounds have high melting points.

Which two statements explain this?

Tick (✓) two boxes.

Question 5, shown as an image

[2]

Answer
Mark scheme for question 5(d)
(e)

Mendeleev put potassium and sodium in the same group because they both react with water.

Ali’s teacher puts a piece of sodium into water. The teacher then puts a piece of potassium into water.

Give two ways Ali could tell potassium is more reactive than sodium.

[2]

Answer
Mark scheme for question 5(e)

Question 6

Mia has three metals, A, B and C, that she reacts with water.

This is what she sees:

Metal A Fizzes and reacts quickly.

Metal B A few bubbles appear after some time.

Metal C Slow fizzing.

(a)(i)

Put the metals in order of reactivity, with the most reactive first.

[1]

Answer
Mark scheme for question 6(a)(i)
(a)(ii)

Which metal forms positive ions most easily?

[1]

Answer
Mark scheme for question 6(a)(ii)
(b)

Metal A is placed in copper sulfate solution. A brown metal is made.

Name the brown metal........

[1]

Answer
Mark scheme for question 6(b)
(c)

The diagram below shows the bonding in metals.

Label the diagram by writing on the dotted lines.

Use words from the list below.

Figure for question 6

[2]

Answer
Mark scheme for question 6(c)
(d)

Metals conduct electricity and are malleable (shapeable).

Draw lines to connect each property with its correct explanation.

Figure for question 6

[2]

Answer
Mark scheme for question 6(d)

Question 7

Dalton was one of the first scientists to model the atom.

Rutherford later developed an improved model of the atom from experiments.

Figure for question 7

Rutherford’s model describes:

• a small positive nucleus

• the nucleus surrounded by empty space

• negatively charged particles orbiting in this empty space.

(a)

Describe how Dalton’s model of the atom was different to Rutherford’s.

[1]

Answer
Mark scheme for question 7(a)
(b)

Name the ‘negatively charged particles’ in Rutherford’s model.

[1]

Answer
Mark scheme for question 7(b)
(c)

We currently know that the nucleus of an atom contains protons and neutrons.

Complete the table by filling in the blank spaces.

Figure for question 7

[2]

Answer
Mark scheme for question 7(c)
(d)

The table shows the number of protons and neutrons in a sodium atom.

Complete the table by filling in the blank spaces.

Atomic numberProtonsMass numberNeutrons
Sodium11112312
Fluorine919

[2]

Answer
Mark scheme for question 7(d)
(e)

Kai finds some information on the internet.

Figure for question 7

Kai writes some notes: 1 Atoms are smaller than molecules. 2 Atoms are smaller than protons.

Is Kai correct?

Use the information in Table 7.1 to explain your answer.

[2]

Answer
Mark scheme for question 7(e)

Question 8

Figure for question 8
(a)

Layla puts some Tumsoothe in a beaker and places it on a balance.

Figure for question 8

She adds hydrochloric acid to the contents of the beaker and this reaction happens:

Question 8, shown as an image

Layla writes down the mass every 10 seconds, as shown in Table 8.1.

Figure for question 8
(a)(i)

Plot a graph of mass against time on the axes below, using Table 8.1.

Add a curve of best fit to the graph.

Figure for question 8

[2]

Answer
Mark scheme for question 8(a)(i)
(a)(ii)

Estimate the mass of the beaker at 100 seconds. Use the graph to help you.

[1]

Answer
Mark scheme for question 8(a)(ii)
(a)(iii)

Draw an F on your graph where the rate of reaction is the fastest.

[1]

Answer
Mark scheme for question 8(a)(iii)
(b)(i)

Describe the rate of change of mass during the reaction.

[1]

Answer
Mark scheme for question 8(b)(i)
(b)(ii)

Explain how you worked this out from the graph.

[1]

Answer
Mark scheme for question 8(b)(ii)
(b)(iii)

The law of conservation of mass says:

‘The mass at the start and end of a reaction must be the same.’

Explain why the law is true for the reaction between NaHCO3 and HCl, even though the reading on the balance changes.

[1]

Answer
Mark scheme for question 8(b)(iii)
(c)
Figure for question 8

[2]

Answer
Mark scheme for question 8(c)
(d)
Figure for question 8
(d)(i)

Layla says, ‘This is good quality data.’

Do you agree?

Explain your answer.

[1]

Answer
Mark scheme for question 8(d)(i)
(d)(ii)

Calculate the mean value for the volume of acid added in the titration.

[1]

Answer
Mark scheme for question 8(d)(ii)

Question 9

Sundip reacts zinc with dilute sulfuric acid.

Figure for question 9
(a)

Complete the symbol equation for the reaction.

Question 9, shown as an image

[1]

Answer
Mark scheme for question 9(a)
(b)

Sundip drops a piece of zinc into some dilute sulfuric acid.

The zinc fizzes.

What is the name of the gas given off?

[1]

Answer
Mark scheme for question 9(b)
(c)

Sundip then drops some zinc powder into some dilute sulfuric acid.

Explain why the fizzing is faster with zinc powder.

[1]

Answer
Mark scheme for question 9(c)
(d)

Sundip adds some blue copper sulfate solution and zinc to the acid.

Sundip thinks that the copper sulfate is a catalyst in the reaction.

If Sundip is right, which statements are correct?

Tick (✓) two boxes.

Question 9, shown as an image

[2]

Answer
Mark scheme for question 9(d)

Question 10

An industrial firm makes nitrogen oxide, NO, by the following reaction:

Question 10, shown as an image
(a)
Question 10, shown as an image

Which two statements are correct at equilibrium?

Tick (✓) two boxes.

Question 10, shown as an image
Question 10, shown as an image
Question 10, shown as an image
Question 10, shown as an image

[2]

Answer
Mark scheme for question 10(a)
(b)

The NO then reacts with air and water to form nitric acid. Nitric acid is an ingredient used to make fertilisers.

Why is nitric acid not used as a fertiliser on its own?

Tick (✓) one box.

Question 10, shown as an image

[1]

Answer
Mark scheme for question 10(b)
(c)

In theory, 28 g of nitrogen makes a maximum of 60 g of NO.

However, in a reaction, 28 g of nitrogen makes 9.0 g of NO.

Calculate the percentage yield of the reaction.

[2]

Answer
Mark scheme for question 10(c)

Question 11

Diamond and graphite are two forms of carbon.

(a)(i)

Fig. 11.1 shows the structure of diamond:

Figure for question 11

Explain why diamond has a high melting point.

[1]

Answer
Mark scheme for question 11(a)(i)
(a)(ii)

Fig. 11.2 shows the structure of graphite.

Graphite also has a high melting point.

Figure for question 11

Describe and explain two other properties of graphite.

Use the structure shown in Fig. 11.2 to help explain your answers.

[2]

Answer
Mark scheme for question 11(a)(ii)
(b)

Diamond has a high density.

1.0 g of diamond has a volume of 0.29 cm3.

Calculate the mass of 1.0 cm3 of diamond.

Give your answer to 2 significant figures.

[2]

Answer
Mark scheme for question 11(b)
(c)

12 g of diamond produces 44 g of CO2 when it is burned completely.

(c)(i)
Figure for question 11 Figure for question 11

[2]

Answer
Mark scheme for question 11(c)(i)
(c)(ii)

Jane makes some statements about graphite and diamond:

1 ‘Complete combustion of 12 g of graphite produces less than 44 g of CO2.’

2 ‘This is because atoms in graphite are further apart than in diamond.’

Do you agree with Jane’s statements?

Explain your answer.

[2]

Answer
Mark scheme for question 11(c)(ii)

Question 12

Ben uses chromatography to investigate a solid black food dye.

(a)

Ben tests the solubility of the dye in three solvents.

Here are his results:

SolventResult
waterinsoluble
ethanolinsoluble
propanonesoluble
(a)(i)

Which of the three solvents are non-aqueous?

[1]

Answer
Mark scheme for question 12(a)(i)
(a)(ii)

Ben uses paper chromatography to investigate the dye.

Which of the three solvents should Ben use in his investigation?

[1]

Answer
Mark scheme for question 12(a)(ii)
(b)

Here is some information about the experiment:

chromatogram at the start
chromatogram at the end

Figure for question 12
(b)(i)

Name the stationary phase.

[1]

Answer
Mark scheme for question 12(b)(i)
(b)(ii)

What is wrong with the way Ben set up his experiment?

Explain your answer.

[2]

Answer
Mark scheme for question 12(b)(ii)
(b)(iii)

Which spot has the greatest Rf value in the chromatogram at the end?

Explain your answer.

[2]

Answer
Mark scheme for question 12(b)(iii)
(c)

Ben thinks the dye is a pure substance. Kareem, another student, disagrees.

Who do you agree with?

Explain your answer.

[1]

Answer
Mark scheme for question 12(c)
(d)

Ben measures the melting point of the dye.

Describe what Ben would see if the dye is pure.

[1]

Answer
Mark scheme for question 12(d)

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