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Chemistry B (21st Century) · OCR J258 · Paper 1 · November 2021

OCR GCSE Chemistry B (21st Century) Paper 1 November 2021 question paper

OCR J258 · Paper 1

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Question 1

In the early nineteenth century, a chemist called Dobereiner found sets of three elements with similar properties.

Table 1.1 shows an example:

Figure for question 1
(a)

State the Group number of lithium, sodium and potassium in the modern Periodic Table.

[1]

Answer
Mark scheme for question 1(a)
(b)

Which statements about lithium, sodium and potassium are true and which are false ?

Tick (✓) one box in each row.

Figure for question 1

[2]

Answer
Mark scheme for question 1(b)
(c)(i)

The elements nitrogen, phosphorus and arsenic have similar properties.

Complete Table 1.2 by adding the symbols for these three elements.

Figure for question 1

[1]

Answer
Mark scheme for question 1(c)(i)
(c)(ii)

Dobereiner called his sets of three elements ‘triads’. He had this idea:

‘The relative atomic mass of element 2 is approximately equal to the mean of the other two elements.’

Do the elements in Table 1.2 fit Dobereiner’s idea?

Question 1, shown as an image

Use a calculation to help explain your answer.

[2]

Answer
Mark scheme for question 1(c)(ii)
(d)

Mendeleev arranged the elements in order of their relative atomic masses.

Mendeleev’s work was peer reviewed.

Describe the peer review process.

[2]

Answer
Mark scheme for question 1(d)

Question 2

Water evaporates from lakes and oceans. It forms clouds of gaseous water.

In the right conditions the water falls as rain, as shown by the equation:

Question 2, shown as an image
(a)

Which two processes does this equation show?

Tick (✓) two boxes.

Question 2, shown as an image

[2]

Answer
Mark scheme for question 2(a)
(b)

Fig. 2.1 represents the three states of matter: solid, liquid and gas.

(b)(i)

Write the word for the correct state under each model.

Figure for question 2

Fig. 2.1

[1]

Answer
Mark scheme for question 2(b)(i)
(b)(ii)

Fig. 2.2 shows a molecule of oxygen, O2.

Question 2, shown as an image

Fig. 2.2

Draw a similar diagram to show a molecule of water, H2O.

[1]

Answer
Mark scheme for question 2(b)(ii)
(c)

The table shows the percentage of nitrogen and carbon dioxide in air:

GasPercentage (%)
Nitrogen78
Carbon dioxide0.04
(c)(i)

Calculate how many times more nitrogen there is than carbon dioxide in air.

........ times more nitrogen than carbon dioxide

[2]

Answer
Mark scheme for question 2(c)(i)
(c)(ii)

Oxygen is 21% of air.

Plot the data for oxygen on the bar chart.

Figure for question 2

[1]

Answer
Mark scheme for question 2(c)(ii)
(c)(iii)

Draw lines to connect each gas with its correct property.

Figure for question 2

Relights a glowing splint.

Figure for question 2

[3]

Answer
Mark scheme for question 2(c)(iii)

Question 3

Plastic bags are made of poly(ethene).

Poly(ethene) is made by polymerisation of ethene.

(a)

Complete the diagram to show the polymerisation of ethene, C2H4.

Figure for question 3

[2]

Answer
Mark scheme for question 3(a)
(b)

Ethene, C2H4, is made by cracking molecules such as decane, C10H22.

Complete the symbol equation for this reaction.

Question 3, shown as an image

[1]

Answer
Mark scheme for question 3(b)
(c)

The table shows the energy required to make 1000 poly(ethene) bags and transport them to shops:

Energy per 1000 bags (kJ)
Energy required to make the raw materials279 000
Energy required to process the raw materials to make the bags220 000
Energy required to transport the bags11 000
(c)(i)

Calculate the total energy required per bag.

Use data from the table.

[2]

Answer
Mark scheme for question 3(c)(i)
(c)(ii)

Calculate the percentage of the energy in the table required to make the raw materials for 1000 bags.

Give your answer to 2 significant figures.

[3]

Answer
Mark scheme for question 3(c)(ii)
(d)

Some plastic materials are described as ‘biodegradable’.

What does ‘biodegradable’ mean?

[1]

Answer
Mark scheme for question 3(d)

Question 4

Amaya is given some coloured sweets.

She uses chromatography to find out the number of dyes in each sweet.

(a)(i)

Amaya starts by drawing a line on a piece of filter paper using ink.

Describe one way in which Amaya can improve this part of her method.

[1]

Answer
Mark scheme for question 4(a)(i)
(a)(ii)

Give one reason for your answer to (a)(i).

[1]

Answer
Mark scheme for question 4(a)(ii)
(b)

Sundip repeats the experiment, improving on Amaya’s method.

Her results are shown in the chromatogram:

Figure for question 4
(b)(i)

Each sweet contains a mixture of dyes.

How many different dyes are there in all of the sweets that Sundip has used?

Use the chromatogram.

[1]

Answer
Mark scheme for question 4(b)(i)
(b)(ii)

Which dye is the least soluble in the solvent?

[1]

Answer
Mark scheme for question 4(b)(ii)
(b)(iii)

Give one reason for your answer to (b)(ii).

[1]

Answer
Mark scheme for question 4(b)(iii)
(b)(iv)

Rf values can be calculated using this equation:

Question 4, shown as an image

Which dye has the largest Rf value?

[1]

Answer
Mark scheme for question 4(b)(iv)
(c)

Ali has a mixture of carbon and copper sulfate crystals. Carbon is insoluble in water.

Complete the list to show the correct order of methods he needs to obtain pure copper sulfate crystals from the mixture.

Use the words.

You can use each word once, more than once, or not at all.

Crystallization Dissolving Distillation Heating

1........

2 Filtration

3........

4........

[3]

Answer
Mark scheme for question 4(c)

Question 5

Chemists use models to describe things that are too small to be seen.

Fig. 5.1 shows an atomic model proposed by a scientist over 100 years ago:

Figure for question 5
(a)

Which scientist suggested the atomic model in Fig. 5.1 ?

Question 5, shown as an image

Dalton Thomson Rutherford Bohr

[1]

Answer
Mark scheme for question 5(a)
(b)

The modern model of the atom is different from the model in Fig. 5.1.

Complete the sentences about the modern model of the atom.

Use the words.

You can use each word once, more than once, or not at all.

electrons ions neutrons nucleus protons

The centre of the atom is called the........

This is made up of positively charged........ and

neutral........

The........ are negatively charged.

In a neutral atom, there are equal numbers of........

and........

[3]

Answer
Mark scheme for question 5(b)
(c)

Fig. 5.2 shows a model of an ethanol molecule and a methane molecule:

Figure for question 5
(c)(i)

The formula of methane is CH4.

What is the formula of ethanol?

Use Fig. 5.2 to help you.

[1]

Answer
Mark scheme for question 5(c)(i)
(c)(ii)

Which two statements do the models in Fig. 5.2 accurately show?

Tick (✓) two boxes.

Question 5, shown as an image

[2]

Answer
Mark scheme for question 5(c)(ii)
(d)

Fig. 5.3 shows models of four types of giant structure.

Figure for question 5
(d)(i)

Which two structures are compounds?

Question 5, shown as an image

A B C D

[2]

Answer
Mark scheme for question 5(d)(i)
(d)(ii)

Which structure conducts electricity when it is solid?

Question 5, shown as an image

A B C D

[1]

Answer
Mark scheme for question 5(d)(ii)
(d)(iii)

Which two structures contain ions?

Question 5, shown as an image

A B C D

[2]

Answer
Mark scheme for question 5(d)(iii)

Question 6

Blue copper sulfate crystals turn white when heated:

Question 6, shown as an image

• Kai weighs out five different samples of ‘blue copper sulfate’.

• He puts each sample in a test tube.

• He heats each test tube.

• He weighs each test tube and its contents after heating.

• He then calculates the mass of ‘white copper sulfate’.

(a)

Fig. 6.1 shows a graph of his results:

Figure for question 6

Mass of ‘blue copper sulfate’ at start (g)

Fig. 6.1

One result does not fit the pattern.

(a)(i)
Question 6, shown as an image

[1]

Answer
Mark scheme for question 6(a)(i)
(a)(ii)

Kai thinks he made a mistake when he was heating the ‘blue copper sulfate’ for this result.

Suggest the mistake Kai made.

[1]

Answer
Mark scheme for question 6(a)(ii)
(b)

Calculate the mass of ‘white copper sulfate’ that is made when 2.0 g of ‘blue copper sulfate’ is heated.

Use the equation: mass of ‘white copper sulfate’ × 1.5625 = mass of ‘blue copper sulfate’

[3]

Answer
Mark scheme for question 6(b)
(c)

Jane and Kai discuss the results:

Figure for question 6

Explain why Jane and Kai are both correct.

Jane........

Kai........

[2]

Answer
Mark scheme for question 6(c)
(d)

100 g of ‘blue copper sulfate’ gives 64 g of ‘white copper sulfate’.

Question 6, shown as an image

Calculate the mass of water that is formed.

[1]

Answer
Mark scheme for question 6(d)
(e)

Jane tests whether this reaction is reversible:

Question 6, shown as an image

She adds water to ‘white copper sulfate’ in a test tube. The solid turns blue and the test tube gets hot.

(e)(i)

Does her observation show that the reaction is reversible?

Question 6, shown as an image

Explain your answer.

[1]

Answer
Mark scheme for question 6(e)(i)
(e)(ii)

What name is given to a reaction that gives out heat?

[1]

Answer
Mark scheme for question 6(e)(ii)
(e)(iii)

Draw one line to show the energy level of ‘blue copper sulfate’ on the reaction profile in Fig. 6.2.

Label your line ‘blue copper sulfate’.

Figure for question 6

[1]

Answer
Mark scheme for question 6(e)(iii)

Question 7

Crude oil contains many compounds that are used as fuels.

The table shows some of these compounds:

NameFormulaRelative formula massBoiling point (°C)
MethaneCH4–162
ButaneC4H1058–1
BenzeneC6H67880
OctaneC8H18114126
HexadecaneC16H34226287
(a)

Which word describes crude oil?

Question 7, shown as an image

Chemical Compound Element Mixture

[1]

Answer
Mark scheme for question 7(a)
(b)(i)

Name the two compounds in the table that are gases at 25 °C.

[1]

Answer
Mark scheme for question 7(b)(i)
(b)(ii)

Explain your answer to (b)(i).

[1]

Answer
Mark scheme for question 7(b)(ii)
(c)

Calculate the relative formula mass of methane.

Use the Data Sheet.

[1]

Answer
Mark scheme for question 7(c)
(d)

Describe the relationship between relative formula mass and boiling point for the compounds in the table.

[1]

Answer
Mark scheme for question 7(d)
(e)

Benzene has six carbon atoms but is not an alkane.

Alkanes have the general formula CnH2n+2.

Give the formula of the alkane with six carbon atoms.

[1]

Answer
Mark scheme for question 7(e)
(f)

The graph shows the boiling point and the number of carbon atoms for some alkanes.

Figure for question 7
(f)(i)

Hexadecane has 16 carbon atoms. The boiling point of hexadecane is 287 °C.

Plot the point for hexadecane on the graph.

[1]

Answer
Mark scheme for question 7(f)(i)
(f)(ii)

Draw a line of best fit.

[1]

Answer
Mark scheme for question 7(f)(ii)
(f)(iii)

Estimate the boiling point of the alkane with the formula C12H26.

Show your working on the graph.

[1]

Answer
Mark scheme for question 7(f)(iii)
(g)

Fractional distillation is used to separate the compounds in crude oil.

Which property is used to separate compounds in fractional distillation?

Tick (✓) one box.

Question 7, shown as an image

[1]

Answer
Mark scheme for question 7(g)
(h)(i)

The formula for butane is C4H10.

Draw the displayed formula for butane.

[1]

Answer
Mark scheme for question 7(h)(i)
(h)(ii)

What is the simplest ratio of carbon atoms to hydrogen atoms in butane?

Ratio of carbon atoms: hydrogen atoms =........:........

[1]

Answer
Mark scheme for question 7(h)(ii)
(h)(iii)

State the empirical formula of butane.

[1]

Answer
Mark scheme for question 7(h)(iii)

Question 8

Chlorine is used to make water safe to drink.

(a)

How does chlorine make water safe to drink?

[1]

Answer
Mark scheme for question 8(a)
(b)

James has a solution of chlorine in water.

He tests the solution with blue litmus paper.

State two colour changes that James will see.

[2]

Answer
Mark scheme for question 8(b)
(c)

Mia adds a solution of chlorine to a solution of sodium bromide.

This is the equation for the reaction that happens:

Question 8, shown as an image

The solution changes colour.

(c)(i)

State the colour of the solution at the end of the experiment.

[1]

Answer
Mark scheme for question 8(c)(i)
(c)(ii)

What causes the colour change?

[1]

Answer
Mark scheme for question 8(c)(ii)
(d)

Potassium reacts with chlorine. Sodium also reacts with chlorine.

Is the reaction of sodium with chlorine faster or slower than the reaction of potassium with chlorine?

Question 8, shown as an image

Explain why the rate of reaction is different.

[1]

Answer
Mark scheme for question 8(d)
(e)

Calcium also reacts with chlorine. Calcium forms Ca2+ ions and chlorine forms Cl– ions.

What is the correct formula of calcium chloride?

Question 8, shown as an image

CaCl Ca2Cl2 CaCl2 ClCa2 ClCa

[1]

Answer
Mark scheme for question 8(e)
(f)

The element astatine, At, is below iodine in Group 7 of the Periodic Table.

Which two properties of astatine are correct?

Tick (✓) two boxes.

Question 8, shown as an image

[2]

Answer
Mark scheme for question 8(f)

Question 9

Alex reacts zinc with excess hydrochloric acid.

Fig. 9.1 shows the apparatus Alex uses:

Figure for question 9
Question 9, shown as an image
Figure for question 9
(a)

Alex measures the volume of gas made at the start and then again after every minute for 7 minutes.

Fig. 9.2 shows a graph of his results:

Figure for question 9
(a)(i)

What is the gradient of the curve at 5 minutes?

Gradient =........ cm3 / minute

[1]

Answer
Mark scheme for question 9(a)(i)
(a)(ii)

What happens to the reaction after 5 minutes?

[1]

Answer
Mark scheme for question 9(a)(ii)
(b)

Which value is a correct estimate for the rate at which the reaction starts?

Use Fig. 9.2.

Tick (✓) one box.

Question 9, shown as an image

[1]

Answer
Mark scheme for question 9(b)
(c)

2.0 g of zinc makes a total of 800 cm3 of gas. (c)

Calculate the mass of zinc Alex used in his experiment.

Use the total volume of gas produced in Fig. 9.2.

[2]

Answer
Mark scheme for question 9(c)
(d)

Alex repeats the experiment with different metals and excess acid. He wants to compare the rate of reaction for the different metals.

State two factors that he should control in these experiments to get valid results.

[2]

Answer
Mark scheme for question 9(d)
(e)

Fig. 9.3 shows Alex’s results for zinc, magnesium and iron:

Figure for question 9

Which metal makes each curve in Fig. 9.3 ?

Curve A........

Curve B........

Curve C........

[2]

Answer
Mark scheme for question 9(e)

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