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Chemistry B (21st Century) · OCR J258 · Paper 3 · November 2021

OCR GCSE Chemistry B (21st Century) Paper 3 November 2021 question paper

OCR J258 · Paper 3

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Question 1

Chlorine is used to make water safe to drink.

(a)

How does chlorine make water safe to drink?

[1]

Answer
Mark scheme for question 1(a)
(b)

James has a solution of chlorine in water.

He tests the solution with blue litmus paper.

State two colour changes that James will see.

[2]

Answer
Mark scheme for question 1(b)
(c)

Mia adds a solution of chlorine to a solution of sodium bromide.

This is the equation for the reaction that happens:

Question 1, shown as an image

The solution changes colour.

(c)(i)

State the colour of the solution at the end of the experiment.

[1]

Answer
Mark scheme for question 1(c)(i)
(c)(ii)

What causes the colour change?

[1]

Answer
Mark scheme for question 1(c)(ii)
(d)

Potassium reacts with chlorine. Sodium also reacts with chlorine.

Is the reaction of sodium with chlorine faster or slower than the reaction of potassium with chlorine?

Question 1, shown as an image

Explain why the rate of reaction is different.

[1]

Answer
Mark scheme for question 1(d)
(e)

Calcium also reacts with chlorine. Calcium forms Ca2+ ions and chlorine forms Cl– ions.

What is the correct formula of calcium chloride?

Question 1, shown as an image

CaCl Ca2Cl2 CaCl2 ClCa2 ClCa

[1]

Answer
Mark scheme for question 1(e)
(f)

The element astatine, At, is below iodine in Group 7 of the Periodic Table.

Which two properties of astatine are correct?

Tick (✓) two boxes.

Question 1, shown as an image

[2]

Answer
Mark scheme for question 1(f)

Question 2

Figure for question 2
(a)

Alex measures the volume of gas made at the start and then again after every minute for 7 minutes.

Fig. 2.2 shows a graph of his results:

Figure for question 2
(a)(i)

What is the gradient of the curve at 5 minutes?

Gradient =........ cm3 / minute

[1]

Answer
Mark scheme for question 2(a)(i)
(a)(ii)

What happens to the reaction after 5 minutes?

[1]

Answer
Mark scheme for question 2(a)(ii)
(b)

Which value is a correct estimate for the rate at which the reaction starts?

Use Fig. 2.2.

Tick (✓) one box.

Question 2, shown as an image

[1]

Answer
Mark scheme for question 2(b)
(c)

2.0 g of zinc makes a total of 800 cm3 of gas. (c)

Calculate the mass of zinc Alex used in his experiment.

Use the total volume of gas produced in Fig. 2.2.

[2]

Answer
Mark scheme for question 2(c)
(d)

Alex repeats the experiment with different metals and excess acid. He wants to compare the rate of reaction for the different metals.

State two factors that he should control in these experiments to get valid results.

[2]

Answer
Mark scheme for question 2(d)
(e)

Fig. 2.3 shows Alex’s results for zinc, magnesium and iron:

Figure for question 2

Which metal makes each curve in Fig. 2.3 ?

Curve A........

Curve B........

Curve C........

[2]

Answer
Mark scheme for question 2(e)

Question 3

In very cold conditions, hand warmers can be used inside gloves. One type of hand warmer uses a chemical reaction to give off heat.

Iron powder inside the hand warmer reacts with oxygen to make iron oxide. An exothermic reaction starts when the iron powder comes into contact with the air.

(a)
Figure for question 3

[1]

Answer
Mark scheme for question 3(a)
(b)

Draw and label the reaction profile for this reaction.

Label the activation energy ‘AE’.

Figure for question 3

[3]

Answer
Mark scheme for question 3(b)
(c)

Carbon is used as a catalyst in the hand warmer.

(c)(i)

Suggest why a catalyst is added to the hand warmer.

[1]

Answer
Mark scheme for question 3(c)(i)
(c)(ii)

Why does the catalyst have the effect identified in (c)(i) ?

Use ideas about energy in your answer.

[1]

Answer
Mark scheme for question 3(c)(ii)
(d)

The iron is in powdered form.

Explain why this makes the reaction go quickly.

Use ideas about particles in your answer.

[2]

Answer
Mark scheme for question 3(d)

Question 4

In the early nineteenth century, a chemist called Dobereiner found some sets of three elements with similar properties.

The table shows an example:

ElementRelative atomic mass
Lithium6.9
Sodium23.0
Potassium39.1
(a)

Lithium, sodium and potassium react in a similar way with water.

(a)(i)

Balance the symbol equation for the reaction of lithium with water.

Question 4, shown as an image

[1]

Answer
Mark scheme for question 4(a)(i)
(a)(ii)

Potassium is more reactive with water than sodium and lithium.

State two observations that would prove this.

[2]

Answer
Mark scheme for question 4(a)(ii)
(b)

Which property is used to arrange the elements in the modern Periodic Table?

Tick (✓) one box.

Question 4, shown as an image

[1]

Answer
Mark scheme for question 4(b)
(c)

Dobereiner called his sets of three elements, ‘triads’. He had this idea:

‘The relative atomic mass of the middle element is approximately equal to the mean of the other two elements.’

The elements nitrogen, phosphorus and arsenic:

• have similar properties

• are found in Group 5 of the modern Periodic Table.

Are nitrogen, phosphorus and arsenic a Dobereiner ‘triad’?

Use the Data Sheet and a calculation to help explain your answer.

[2]

Answer
Mark scheme for question 4(c)

Question 5

Crude oil contains many compounds that are used as fuels. The table shows information about some of these compounds:

NameFormulaRelative formula massMelting point (°C)Boiling point (°C)
MethaneCH416–182–162
PentaneC5H1070–13036
NonaneC9H20128–54151
DodecaneC12H26170–10
HexadecaneC16H3422618287
IcosaneC20H4228237343
BenzeneC6H678680
(a)

All the compounds in the table are alkanes, except benzene.

Explain how the formula of benzene shows it is not an alkane.

[2]

Answer
Mark scheme for question 5(a)
(b)(i)

Name one compound from the table which is a solid at 25 °C.

[1]

Answer
Mark scheme for question 5(b)(i)
(b)(ii)

Give one reason for your answer to (b)(i).

[1]

Answer
Mark scheme for question 5(b)(ii)
(c)

Describe the relationship between melting point and boiling point for the alkanes in the table.

[1]

Answer
Mark scheme for question 5(c)
(d)

The graph shows the boiling point and relative formula mass for some alkanes.

Figure for question 5
(d)(i)

Hexadecane, C16H34, boils at 287 °C. Plot the point for hexadecane on the graph.

Use data from the table.

[1]

Answer
Mark scheme for question 5(d)(i)
(d)(ii)

Draw a line of best fit.

[1]

Answer
Mark scheme for question 5(d)(ii)
(d)(iii)

Estimate the boiling point of dodecane, C12H26.

Show your working on the graph.

[1]

Answer
Mark scheme for question 5(d)(iii)
(e)

Fractional distillation is used to separate the compounds in crude oil.

Which property of the compounds is used to separate them?

[1]

Answer
Mark scheme for question 5(e)
(f)
(f)(i)

Describe how carbon monoxide forms when alkanes burn in vehicle engines.

[1]

Answer
Mark scheme for question 5(f)(i)
(f)(ii)

Why is it important to decrease the amount of carbon monoxide entering the air?

[1]

Answer
Mark scheme for question 5(f)(ii)
(f)(iii)

The formula of carbon monoxide is CO. One mole of carbon monoxide contains 6.02 × 1023 molecules.

Calculate the mass of one carbon monoxide molecule.

Question 5, shown as an image

Give your answer to 3 significant figures.

[3]

Answer
Mark scheme for question 5(f)(iii)
(g)

Nitrogen oxides are also formed in vehicle engines.

Describe how nitrogen oxides form in vehicle engines.

[2]

Answer
Mark scheme for question 5(g)

Question 6

Scientists use models to describe things that are too small to be seen.

Fig. 6.1 shows a model of an atom:

Figure for question 6
(a)

Name the particles represented by black circles in the model.

[1]

Answer
Mark scheme for question 6(a)
(b)(i)

Identify the element in Fig. 6.1.

Use the Data Sheet.

[1]

Answer
Mark scheme for question 6(b)(i)
(b)(ii)

How was the element in Fig. 6.1 identified in (b)(i) ?

[1]

Answer
Mark scheme for question 6(b)(ii)
(c)
Figure for question 6
(c)(i)

Which two features are shown by the model in Fig. 6.2 ?

Tick (✓) two boxes.

Question 6, shown as an image

[2]

Answer
Mark scheme for question 6(c)(i)
(c)(ii)

State the empirical formula of butane.

[1]

Answer
Mark scheme for question 6(c)(ii)
(d)

Fig. 6.3 shows models of four types of giant structure.

Figure for question 6
(d)(i)

Which two structures contain covalent bonds?

Question 6, shown as an image

A B C D

[2]

Answer
Mark scheme for question 6(d)(i)
(d)(ii)

Which structure only conducts electricity when it is molten?

Question 6, shown as an image

A B C D

[1]

Answer
Mark scheme for question 6(d)(ii)

Question 7

Amaya is given some coloured sweets. She removes the food colour from each sweet. Each food colour contains a mixture of dyes.

(a)

She uses chromatography to find out the number of dyes in each sweet:

• She draws a pencil line on a piece of filter paper 1 cm from the bottom.

• She puts spots of food colour from each sweet on the pencil line.

• She places the filter paper in 2 cm of water in a beaker.

• She waits for the water to rise to near the top of the filter paper.

There is a mistake in Amaya’s method.

(a)(i)

Identify the mistake in Amaya’s method.

[1]

Answer
Mark scheme for question 7(a)(i)
(a)(ii)

Why will this mistake stop Amaya from getting useful results?

[1]

Answer
Mark scheme for question 7(a)(ii)
(b)
Figure for question 7
(b)(i)

Amaya says, ‘The chromatogram shows that there were a total of four different pure dyes used in the three sweets.’

Explain why this is incorrect.

[2]

Answer
Mark scheme for question 7(b)(i)
(b)(ii)

Which dye is the most soluble in water?

[1]

Answer
Mark scheme for question 7(b)(ii)
(b)(iii)

Give one reason for your answer to (b)(ii).

[1]

Answer
Mark scheme for question 7(b)(iii)
(b)(iv)

Calculate the Rf value for the yellow dye.

Use the chromatogram and the equation:

Question 7, shown as an image

[2]

Answer
Mark scheme for question 7(b)(iv)
(c)

Ali has a mixture of carbon in copper sulfate solution. Carbon is insoluble in water.

Describe a method Ali can use to obtain pure copper sulfate crystals from the mixture.

[3]

Answer
Mark scheme for question 7(c)

Question 8

Plastic bags are made of poly(ethene).

(a)(i)

Poly(ethene) is made by polymerising ethene, C2H4.

Draw the structure of the repeating unit of poly(ethene).

[2]

Answer
Mark scheme for question 8(a)(i)
(a)(ii)

What type of polymer is poly(ethene)?

[1]

Answer
Mark scheme for question 8(a)(ii)
(b)(i)

Ethene, C2H4, is made by cracking molecules such as decane, C10H22. One other product is made in the reaction.

Write a balanced symbol equation for the cracking of decane.

[2]

Answer
Mark scheme for question 8(b)(i)
(b)(ii)

Ethene is an alkene.

Describe a laboratory test for an alkene and the expected result for ethene.

Test........

Result........

[2]

Answer
Mark scheme for question 8(b)(ii)
(c)

Table 8.1 shows the energy required to make 1000 poly(ethene) bags and transport them to shops:

Figure for question 8
(c)(i)

Calculate the percentage of the energy in the table required to transport the bags.

Give your answer to 1 decimal place.

[3]

Answer
Mark scheme for question 8(c)(i)
(c)(ii)

Sarah estimates the cost of recycling waste bags into new bags.

Table 8.2 shows her estimates:

Figure for question 8

Suggest why Sarah’s estimates may be inaccurate.

Use data from Table 8.1 and Table 8.2 to support your answer.

[2]

Answer
Mark scheme for question 8(c)(ii)
(d)

Poly(ethene) is described as ‘non-biodegradable’.

Define ‘ non-biodegradable ’.

[1]

Answer
Mark scheme for question 8(d)

Question 9

Blue copper sulfate crystals turn white when heated:

Question 9, shown as an image

• Sarah weighs out five different samples of ‘blue copper sulfate’.

• She puts each sample in a test tube.

• She heats each test tube.

• She weighs each test tube and its contents after heating.

• She then calculates the mass of ‘white copper sulfate’.

(a)

The graph shows the results:

Figure for question 9

Mass of ‘blue copper sulfate’ at start (g)

Fig. 9.1

(a)(i)

Result A does not fit the pattern.

Sarah says the test tube was not heated for long enough.

Is Sarah correct? Explain your answer.

[1]

Answer
Mark scheme for question 9(a)(i)
(a)(ii)

The equation for the line in Fig. 9.1 is given by y = m x + c.

Calculate values for m and c, using Fig. 9.1.

[3]

Answer
Mark scheme for question 9(a)(ii)
(b)(i)

25 g of ‘blue copper sulfate’ gives 16 g of ‘white copper sulfate’ when heated.

Calculate the number of moles of water that are made.

Question 9, shown as an image

[3]

Answer
Mark scheme for question 9(b)(i)
(b)(ii)

‘Blue copper sulfate’ has the formula CuSO4•nH2O, where n is a whole number.

In one experiment, Sarah makes 2.0 mol of water and 0.4 mol of ‘white copper sulfate’.

‘White copper sulfate’ has the formula CuSO4.

Calculate the value of n in ‘blue copper sulfate’, CuSO4•nH2O.

[2]

Answer
Mark scheme for question 9(b)(ii)

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