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Combined Science B (21st Century) · OCR J260 · Paper 6 · June 2018

OCR GCSE Combined Science B (21st Century) Paper 6 June 2018 question paper

OCR J260 · Paper 6

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Question 1

The elements in Group 7 (Group 17) of the Periodic Table are called the halogens.

(a)

Each element has a different state and colour at room temperature.

Draw lines to connect each element with its correct state and colour at room temperature.

State Element Colour

Figure for question 1

[3]

Answer
Mark scheme for question 1(a)
(b)

Table 1.1 shows what happens when some halogens react with hydrogen.

Figure for question 1
(b)(i)

Describe the trend in reactivity of the Group 7 elements with hydrogen.

[1]

Answer
Mark scheme for question 1(b)(i)
(b)(ii)

A mixture of chlorine and hydrogen explodes when a small spark is added.

Does this fit the trend of the reactivity of the other Group 7 elements with hydrogen?

Explain your reasoning.

[2]

Answer
Mark scheme for question 1(b)(ii)
(c)

The halogens also react with reactive metals.

(c)(i)

Potassium reacts with bromine to form potassium bromide.

Balance the symbol equation for this reaction.

Question 1, shown as an image

[1]

Answer
Mark scheme for question 1(c)(i)
(c)(ii)

Other metals also react with bromine to form metal bromides.

The formula of the metal bromide depends on the number of electrons in the outer shell of an atom of the metal.

Complete Table 1.2 which shows the products formed when different metals react with

Figure for question 1

[3]

Answer
Mark scheme for question 1(c)(ii)

Question 2

Most cars are fitted with catalytic converters.

Harmful gases from the car engine react together in the converter to form less harmful gases.

(a)

The catalyst in the converter increases the rate of the reactions between the gases.

Use ideas about energy to explain how catalysts increase the rate of a reaction.

[2]

Answer
Mark scheme for question 2(a)
(b)
Figure for question 2

[2]

Answer
Mark scheme for question 2(b)
(c)(i)
Figure for question 2

[1]

Answer
Mark scheme for question 2(c)(i)
(c)(ii)

Catalysts are now made from nanoparticles. A nanoparticle in a catalyst is shown in the

Figure for question 2

Calculate the surface area to volume ratio of the nanoparticle. Assume that it is a cube with sides of 10 nm.

[4]

Answer
Mark scheme for question 2(c)(ii)

Question 3

Many compounds found on Earth and other planets contain hydrogen.

(a)

Water is a compound of hydrogen with oxygen. It is found in very large amounts in the Earth’s seas.

Water is added to the sea when ice caps melt.

In sunlight, plants use water for photosynthesis to make glucose.

(a)(i)

Which statements are true only for melting, which are true only for photosynthesis and which are true for both ?

Put a tick (✓) in one box in each row.

Figure for question 3

[2]

Answer
Mark scheme for question 3(a)(i)
(a)(ii)

Use the particle model to explain why the ice caps are a fixed shape but water in the sea can flow and change shape.

[3]

Answer
Mark scheme for question 3(a)(ii)
(b)

Water, methane and ammonia are compounds of hydrogen with other elements.

Some scientists think that life on other planets could be based on methane or ammonia instead of water.

The table shows some properties of water, methane and ammonia.

CompoundFormulaMelting point (°C)Boiling point (°C)
WaterH2O0100
MethaneCH4–182–164
AmmoniaNH3–78–33
(b)(i)

Which statements about water, methane and ammonia are true and which are false

Put a tick (✓) in one box in each row

Figure for question 3

[2]

Answer
Mark scheme for question 3(b)(i)
(b)(ii)

The average surface temperature of Earth is 14 °C. The average surface temperature of Mars is –55 °C.

Use the data in the table to predict the state of ammonia on each planet.

Explain your answer.

[3]

Answer
Mark scheme for question 3(b)(ii)

Question 4

Indigestion may be caused by excess acid in the stomach. Kai and Jane investigate indigestion tablets.

The active compound in each tablet is calcium carbonate which reacts with excess acid.

(a)

Kai and Jane react solid calcium carbonate with dilute hydrochloric acid.

The products of the reaction are calcium chloride, carbon dioxide and water.

This is the equation for the reaction.

Question 4, shown as an image

Kai says that after the reaction, the mass of products must equal the mass of the reactants.

Jane predicts that the mass will decrease during the reaction.

Explain why they are both correct.

Kai........

Jane........

[2]

Answer
Mark scheme for question 4(a)
(b)

Jane does an experiment to find out the total mass of carbon dioxide made when one indigestion tablet reacts with dilute hydrochloric acid.

Describe how Jane could do her experiment.

Include a list of the apparatus she could use and the measurements she should record. You may include a diagram in your answer.

[4]

Answer
Mark scheme for question 4(b)
(c)

Jane repeats her experiment four times.

Here are her results.

Experiment1234
Mass of carbon dioxide made (g)0.220.180.240.17
(c)(i)

What is the range of Jane’s results?

[1]

Answer
Mark scheme for question 4(c)(i)
(c)(ii)

Calculate the mean value for the mass of carbon dioxide made.

Give your answer to 2 decimal places.

[3]

Answer
Mark scheme for question 4(c)(ii)
(d)

The label on the tablets says that each tablet contains 500 mg of calcium carbonate.

(d)(i)

Jane works out that there are 0.005 moles of calcium carbonate in 500 mg.

Show by calculation that she is right.

[2]

Answer
Mark scheme for question 4(d)(i)
(d)(ii)

Jane reacts 0.005 moles of calcium carbonate with dilute hydrochloric acid.

Question 4, shown as an image

Calculate the mass of carbon dioxide made in the reaction.

[2]

Answer
Mark scheme for question 4(d)(ii)

Question 5

5* The table shows the type of bonding and the melting points of the chlorides and oxides of the elements in Period 3 of the Periodic Table.

Figure for question 5

Describe the pattern shown by the melting points of the chlorides and oxides. Use ideas about bonding and structure to explain why the melting points are different.

[6]

Answer
Mark scheme for question 5

Question 6

Mia is investigating vitamin tablets. She reads the label on a bottle of vitamin tablets and it says that the tablets contain other ingredients.

(a)

The tablets are a formulation.

What is the difference between a formulation and a pure substance?

[2]

Answer
Mark scheme for question 6(a)
(b)

The other ingredients in the tablet include coloured dyes.

Mia uses chromatography to separate the dyes. She starts by crushing a tablet and mixing it with water.

She finds that some of the ingredients in the tablet dissolve in the water but the dyes do not.

(b)(i)

How can she tell that the dyes have not dissolved in the water?

[1]

Answer
Mark scheme for question 6(b)(i)
(b)(ii)

What should she do to make a solution of the dyes?

[1]

Answer
Mark scheme for question 6(b)(ii)
(c)

Mia takes a solution of the dyes and does a chromatography experiment.

Here are her results.

Figure for question 6
(c)(i)

Use the scale given on the diagram to complete the table of results.

Figure for question 6

[2]

Answer
Mark scheme for question 6(c)(i)
(c)(ii)
Figure for question 6

[2]

Answer
Mark scheme for question 6(c)(ii)
(c)(iii)

Mia does a chromatography experiment for a green dye. This dye has an Rf value of 0.52.

After the experiment the solvent front has travelled 8 cm from the start line.

How far from the start line does the green dye travel?

[2]

Answer
Mark scheme for question 6(c)(iii)
(d)

Explain why it was not necessary to use a locating agent in this experiment.

[1]

Answer
Mark scheme for question 6(d)

Question 7

Aluminium is extracted from aluminium oxide by electrolysis.

Aluminium oxide, Al2O3, is an ionic compound.

Figure for question 7
(a)

The aluminium oxide must be molten in this process so that it conducts electricity.

Explain why aluminium oxide conducts electricity when it is liquid but not when it is solid.

[3]

Answer
Mark scheme for question 7(a)
(b)(i)

Complete the table to show the product and half equation at the positive electrode.

ElectrodeName of productHalf equation
NegativealuminiumAl3+ + 3e- → Al
Positive

[3]

Answer
Mark scheme for question 7(b)(i)
(b)(ii)
Question 7, shown as an image

The reaction at the negative electrode is oxidation / reduction because

electrons are gained / lost.

[1]

Answer
Mark scheme for question 7(b)(ii)
(c)

Alex does an experiment to find out if he can make aluminium at room temperature. He starts by making a solution of aluminium sulfate.

He reacts solid aluminium oxide with dilute sulfuric acid to make a solution of aluminium sulfate in water.

Complete and balance the chemical equation for this reaction. Include the state symbols.

aluminium oxide + sulfuric acid → aluminium sulfate + water

Question 7, shown as an image

[2]

Answer
Mark scheme for question 7(c)
(d)

Alex passes electricity through the dilute solution of aluminium sulfate he has made. He expects aluminium to form at the negative electrode.

He finds that a gas forms at the negative electrode instead of aluminium. He tests the gas with a lighted splint and it gives a squeaky pop.

(d)(i)

Explain why aluminium is not formed at the negative electrode.

[1]

Answer
Mark scheme for question 7(d)(i)
(d)(ii)

Name the gas that forms at the negative electrode and explain why this gas is produced during the electrolysis.

[3]

Answer
Mark scheme for question 7(d)(ii)

Question 8

The Haber Process manufactures ammonia by reacting nitrogen with hydrogen.

Question 8, shown as an image
(a)

Explain why this reaction cannot produce a yield of 100%.

[3]

Answer
Mark scheme for question 8(a)
(b)

The table shows the yield of ammonia at different conditions of temperature and pressure.

Percentage yield of ammonia at equilibrium
Temperature (°C)
Pressure (atm)100200300400500
10–511541
2592642793
50957440156
1009782532511
2009889673918
4009995805532
(b)(i)

Describe the effect of changing the temperature and the pressure on the percentage yield of ammonia produced.

Temperature........

Pressure........

[2]

Answer
Mark scheme for question 8(b)(i)
(b)(ii)

Which temperature and pressure would together give the highest yield?

[1]

Answer
Mark scheme for question 8(b)(ii)
(b)(iii)

The conditions chosen for the manufacture of ammonia are 400–450 °C and 200 atmospheres pressure.

For each condition, give a reason why it is chosen rather than the one that gives the highest yield.

Temperature........

Pressure........

[2]

Answer
Mark scheme for question 8(b)(iii)

Question 9

Diamond and graphite are allotropes of carbon.

Figure for question 9
(a)

Describe two similarities and two differences between the structures of diamond and graphite.

Similarities:

Differences:

[4]

Answer
Mark scheme for question 9(a)
(b)

Use ideas about structure and bonding to explain why the hardness and electrical conductivity of diamond and graphite are different.

Hardness........

Electrical conductivity........

[4]

Answer
Mark scheme for question 9(b)

Question 10

pH values can be used to compare the acidity of different acids. The pH of an acid can be measured by reading the display on a pH meter.

(a)

Describe a different way that the pH of an acid can be measured.

[2]

Answer
Mark scheme for question 10(a)
(b)

Ling tests the pH of solutions of a strong acid and a weak acid. Both acids have the same concentration. She finds that the strong acid has a much lower pH.

Explain why the strong acid has a lower pH than the weak acid.

[2]

Answer
Mark scheme for question 10(b)
(c)

The table shows information about three different acid solutions.

Complete the table for the three solutions.

Acid solutionConcentration of solution (mol / dm3)pHConcentration of hydrogen ions (mol / dm3)Type of acid
10.111 × 10–1strong
20.0121 × 10–2....................
30.15............................weak

[2]

Answer
Mark scheme for question 10(c)

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