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Combined Science B (21st Century) · OCR J260 · Paper 6 · June 2022

OCR GCSE Combined Science B (21st Century) Paper 6 June 2022 question paper

OCR J260 · Paper 6

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Question 1

The table gives information about some of the compounds present in crude oil.

Number of carbon atomsMolecular formulaEmpirical formulaMelting point (°C)Boiling point (°C)State at room temperature
4C4H10C2H5–1380Gas
5...................C5H12–13036
6C6H14C3H7–9569Liquid
7C7H16C7H16–90Liquid
8C8H18...................–57126Liquid
(a)(i)

Complete the table to show the missing molecular formula and empirical formula.

[2]

Answer
Mark scheme for question 1(a)(i)
(a)(ii)

Predict the boiling point for the compound with 7 carbon atoms.

[1]

Answer
Mark scheme for question 1(a)(ii)
(a)(iii)

Predict the state of the 5 carbon compound at room temperature (20 °C).

Explain your answer.

[2]

Answer
Mark scheme for question 1(a)(iii)
(b)

All the compounds in the table are in the same homologous series.

All members of a homologous series have the same general formula.

(b)(i)

Give two other characteristics of a homologous series that are shown in the table.

[2]

Answer
Mark scheme for question 1(b)(i)
(b)(ii)
Figure for question 1

[3]

Answer
Mark scheme for question 1(b)(ii)

Question 2

Solid calcium carbonate reacts with dilute hydrochloric acid to form calcium chloride, carbon dioxide and water.

Question 2, shown as an image
(a)

Jane investigates the rate of this reaction. She measures the change in mass during the reaction over five minutes.

She uses 10 g of calcium carbonate lumps and 50 cm3 of dilute hydrochloric acid.

The graph shows Jane’s results.

Figure for question 2
(a)(i)

What was the time taken for the reaction to finish?

[1]

Answer
Mark scheme for question 2(a)(i)
(a)(ii)

What was the total mass lost during the reaction?

[2]

Answer
Mark scheme for question 2(a)(ii)
(a)(iii)

Calculate the average rate of the reaction.

Rate of reaction =........ g / s

[2]

Answer
Mark scheme for question 2(a)(iii)
(b)

Jane repeats the experiment with 10 g of calcium carbonate powder instead of 10 g of lumps. She keeps everything else the same.

Sketch a line on the graph to show the results she should expect.

[2]

Answer
Mark scheme for question 2(b)
(c)

Complete the sentences to explain why the rate of reaction changes when powdered calcium carbonate is used instead of lumps.

Question 2, shown as an image

The surface area of 10 g of powdered calcium carbonate is larger than / smaller than / the same as 10 g of lumps.

The total volume of 10 g of powdered calcium carbonate is larger than / smaller than / the same as 10 g of lumps.

[2]

Answer
Mark scheme for question 2(c)

Question 3

Calcium is a metal in Group 2 of the Periodic Table. Chlorine is a non-metal in Group 17(7) of the Periodic Table.

Table 3.1 shows some properties of calcium and chlorine.

Figure for question 3
(a)

Describe one other property, not shown in Table 3.1, which is different for metals and non-metals.

[1]

Answer
Mark scheme for question 3(a)
(b)

The difference in properties of metals and non-metals is caused by their electronic structures.

(b)(i)

Give the electronic structures of calcium and chlorine.

Calcium........

Chlorine........

[2]

Answer
Mark scheme for question 3(b)(i)
(b)(ii)

Explain why calcium and chlorine form different types of ions.

[3]

Answer
Mark scheme for question 3(b)(ii)
(c)(i)

The boiling points of calcium and chlorine are different because of the forces of attraction between particles.

Draw lines to connect each element to the forces of attraction between its particles.

Figure for question 3

[2]

Answer
Mark scheme for question 3(c)(i)
(c)(ii)

Explain why the boiling points of calcium and chlorine are different.

Use your answer to (i) to support your answer.

[2]

Answer
Mark scheme for question 3(c)(ii)
(d)

Metals and non-metals react together to form ionic compounds.

Table 3.2 shows some information about three ionic compounds.

Figure for question 3

Complete the table to show the ions in potassium oxide and the formula of aluminium oxide.

[2]

Answer
Mark scheme for question 3(d)
(e)

Metals and ionic compounds can form lattices.

The diagram shows four different lattice structures.

Figure for question 3
(e)(i)

Which two structures are the lattice of a metal?

[1]

Answer
Mark scheme for question 3(e)(i)
(e)(ii)

Which structure is the lattice of potassium oxide (K2O)?

Explain your answer.

[2]

Answer
Mark scheme for question 3(e)(ii)

Question 4

Figure for question 4
(a)(i)

Complete the balanced symbol equation for the reaction of aluminium with sodium hydroxide.

Question 4, shown as an image

[1]

Answer
Mark scheme for question 4(a)(i)
(a)(ii)

How does the equation show that contact with aluminium surfaces is a hazard?

[2]

Answer
Mark scheme for question 4(a)(ii)
(b)

Tests can be used to identify gases produced in a reaction.

Complete the table to show the method and the result for the tests for the three gases.

GasMethodResult
hydrogen..........................................................................................................
carbon dioxide..........................................................................................................
oxygen..........................................................................................................

[3]

Answer
Mark scheme for question 4(b)
(c)

Sam does a titration to find the amount of sodium hydroxide in the oven cleaner.

This is the method:

• Measure out 3.00 g of the cleaner into a conical flask

• Add a few drops of indicator

• Add 0.25 mol / dm3 hydrochloric acid until all of the sodium hydroxide has reacted.

The equation shows the reaction of sodium hydroxide with hydrochloric acid.

Question 4, shown as an image
(c)(i)

Calculate the range of the mass of sodium hydroxide expected in 3 g of oven cleaner.

Use information from the label.

Mass of sodium hydroxide is from........ g to <........ g

[3]

Answer
Mark scheme for question 4(c)(i)
(c)(ii)

How does Sam know when all the sodium hydroxide has reacted?

[1]

Answer
Mark scheme for question 4(c)(ii)
(c)(iii)

Sam wants to measure the exact volume of acid needed for all of the sodium hydroxide to react.

Describe one thing Sam should do so that the titration result is accurate.

[1]

Answer
Mark scheme for question 4(c)(iii)
(d)

Sam finds that 24.8 cm3 of 0.25 mol / dm3 hydrochloric acid is needed to react with the (d) sodium hydroxide in 3.00 g of oven cleaner.

(d)(i)

Calculate the number of moles of hydrochloric acid in 24.8 cm3 of 0.25 mol / dm3. (i)

Question 4, shown as an image

[3]

Answer
Mark scheme for question 4(d)(i)
(d)(ii)

Find out how many moles of sodium hydroxide react with this amount of acid.

Question 4, shown as an image

[1]

Answer
Mark scheme for question 4(d)(ii)
(d)(iii)

Calculate the mass of sodium hydroxide (NaOH) reacting with the acid.

Use the formula and the relative atomic masses given.

Question 4, shown as an image

Relative atomic masses: Na = 23.0, O = 16.0, H = 1.0

Mass of sodium hydroxide =........ (g)

[3]

Answer
Mark scheme for question 4(d)(iii)

Question 5

(a)

Table 5.1 shows information about some pollutants in the air over 100 days in 2020.

Figure for question 5

Calculate the orders of magnitude for the change in each pollutant in 2020.

Question 5, shown as an image

[3]

Answer
Mark scheme for question 5(a)
(b)

Table 5.2 shows information about the same pollutants in the air over a 100-day period in 5 years from 2015–2019.

Figure for question 5

Sundip looks at the data in Table 5.1 and Table 5.2 and says: ‘The changes in these pollutants during 2020 are not significant. They go up and down each year.’

Explain why she is only partially correct.

Use data from Table 5.1 and Table 5.2 to support your answer.

[2]

Answer
Mark scheme for question 5(b)
(c)

These pollutants are all emitted from car exhausts. Particulates are tiny carbon particles and NO and NO2 are oxides of nitrogen.

(c)(i)

Describe how particulates and oxides of nitrogen are produced by car engines.

Oxides of nitrogen........

[4]

Answer
Mark scheme for question 5(c)(i)
(c)(ii)

Carbon monoxide, carbon dioxide and sulfur dioxide are also emitted from car exhausts.

Draw lines to connect each gas with the main problem caused by increased amounts of the gas in the atmosphere.

Figure for question 5

[2]

Answer
Mark scheme for question 5(c)(ii)

Question 6

Ammonia is manufactured from nitrogen and hydrogen. When nitrogen and hydrogen gases are mixed, they come to a dynamic equilibrium.

Question 6, shown as an image
(a)(i)
(a) Question 6, shown as an image

[1]

Answer
Mark scheme for question 6(a)(i)
(a)(ii)

What is happening to the rates of the forward and reverse reactions when it is at dynamic equilibrium ?

[1]

Answer
Mark scheme for question 6(a)(ii)
(a)(iii)

Why is the yield of the reaction not 100%?

[2]

Answer
Mark scheme for question 6(a)(iii)
(b)

* The yield of ammonia is affected by changing the conditions of the reaction vessel.

Table 6.1 shows the percentage yield at different temperatures and pressures.

Figure for question 6

Chemical companies choose the most effective conditions for the manufacture of ammonia.

Table 6.2 shows the conditions chosen by one company.

Figure for question 6

Describe the effect of changing the conditions of the reaction vessel on the yield of ammonia shown in Table 6.1 and explain why the chemical company chose the conditions shown in Table 6.2.

Use ideas about yield, rate, energy use and safety in your answer.

[6]

Answer
Mark scheme for question 6(b)

Question 7

Neutralisation is when an acid reacts with an alkali to form a salt and water. Neutralisation can also be described in terms of ions.

(a)

Complete the word and balanced symbol equations for the reaction between nitric acid and sodium hydroxide.

Question 7, shown as an image
Question 7, shown as an image

[3]

Answer
Mark scheme for question 7(a)
(b)

Identify the two ions involved in a neutralisation reaction and state where they come from.

[2]

Answer
Mark scheme for question 7(b)
(c)
Figure for question 7
(c)(i)
Figure for question 7

[2]

Answer
Mark scheme for question 7(c)(i)
(c)(ii)
Figure for question 7

[1]

Answer
Mark scheme for question 7(c)(ii)
(d)
Figure for question 7

[2]

Answer
Mark scheme for question 7(d)

Question 8

Diamond, graphite and graphene are all allotropes of carbon.

The table shows the structure and some properties for these allotropes.

Figure for question 8
(a)

The properties of these allotropes depend on their structure.

(a)(i)

Explain why graphite and graphene are good conductors of electricity but diamond is not.

[3]

Answer
Mark scheme for question 8(a)(i)
(a)(ii)

Explain why diamond and graphene are hard but graphite is soft.

Diamond and graphene........

[4]

Answer
Mark scheme for question 8(a)(ii)
(a)(iii)

Graphene sheets are one atom deep.

What is the depth of a graphene sheet?

Question 8, shown as an image
Question 8, shown as an image

[1]

Answer
Mark scheme for question 8(a)(iii)
(b)

Carbon nanotubes are graphene sheets rolled into a tube.

Figure for question 8

Graphene and nanotubes are examples of nanoparticles. Nanoparticles have important uses which depend on their structure and properties.

(b)(i)
Figure for question 8

[2]

Answer
Mark scheme for question 8(b)(i)
(b)(ii)

Give one risk and one benefit of using nanoparticles to carry drugs into the body.

Risk........

Benefit........

[2]

Answer
Mark scheme for question 8(b)(ii)

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