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Edexcel IGCSE Chemistry

Topic questions Atomic structure and the periodic table Isotopes & relative atomic mass

Isotopes & relative atomic mass

20 questions · 159 marks · about 3 hours

Isotopes and relative atomic mass questions

Edexcel 4CH1 Isotopes and relative atomic mass 20 questions

Chemistry Paper 1 June 2025, Question 1 8 marks

The diagram represents an atom of an element.

Figure for question 1
(a)

Label the three subatomic particles on the diagram.

[3]
Reveal mark scheme Mark scheme for question 1(a)
(b)

Use information from the diagram to complete the table for this element.

Figure for question 1
[4]
Reveal mark scheme Mark scheme for question 1(b)
(c)

Give the name of this element.

[1]
Reveal mark scheme Mark scheme for question 1(c)

Chemistry Paper 2 November 2024, Question 1 7 marks

The table shows the composition of five species that are either atoms or ions.

SpeciesNumber of protonsNumber of neutronsNumber of electrons
A101
B333
C343
D91010
E131413
(a)

Use the table to answer these questions.

You may use each letter once, more than once, or not at all.

(a)(i)

Give the letter of the species that is a negative ion.

[1]
Reveal mark scheme Mark scheme for question 1(a)(i)
(a)(ii)

Give the letter of the species that has a full outer shell of electrons.

[1]
Reveal mark scheme Mark scheme for question 1(a)(ii)
(a)(iii)

Give the letter of the species that has an atomic number equal to its mass number.

[1]
Reveal mark scheme Mark scheme for question 1(a)(iii)
(b)

Explain why species B and C are atoms of the same element with identical chemical properties.

[2]
Reveal mark scheme Mark scheme for question 1(b)
(c)

A proton has a mass of 1.6726maths symbol10–24g.

A neutron has a mass of 1.6740maths symbol10–24g.

Calculate the mass, in grams, of the nucleus of an atom of species C.

[2]
Reveal mark scheme Mark scheme for question 1(c)

Chemistry Paper 1 June 2024 (R), Question 1 5 marks

This question is about atomic structure.

(a)

The table shows the number of protons, neutrons and electrons in five species, V, W, X, Y and Z.

The letters represent the species but are not symbols from the Periodic Table.

SpeciesNumber of protonsNumber of neutronsNumber of electrons
V293827
W121212
X91010
Y668
Z7710

Choose letters from the table to answer these questions.

Each letter may be used once, more than once or not at all.

(a)(i)

Which species is an atom?

[1]
Reveal mark scheme Mark scheme for question 1(a)(i)
(a)(ii)

Which species is an ion with a positive charge?

[1]
Reveal mark scheme Mark scheme for question 1(a)(ii)
(a)(iii)

Which species is an ion with a 3− charge?

[1]
Reveal mark scheme Mark scheme for question 1(a)(iii)
(b)
(b)(i)

State what is meant by the term atomic number.

[1]
Reveal mark scheme Mark scheme for question 1(b)(i)
(b)(ii)

State what is meant by the term mass number.

[1]
Reveal mark scheme Mark scheme for question 1(b)(ii)

Chemistry Paper 2 June 2024 (R), Question 2 6 marks

(a)

The diagram represents an atom of an element.

Figure for question 2
(a)(i)

What is the name of the particle labelled W?

Question 2, shown as an image
[1]
Reveal mark scheme Mark scheme for question 2(a)(i)
(a)(ii)

What is the mass number of this atom?

Question 2, shown as an image
[1]
Reveal mark scheme Mark scheme for question 2(a)(ii)
(b)

These are the symbols for the two isotopes of lithium.

Question 2, shown as an image
(b)(i)

In terms of sub-atomic particles, give one similarity and one difference between the two isotopes.

similarity

[2]
Reveal mark scheme Mark scheme for question 2(b)(i)
(b)(ii)

difference

A sample of lithium contains 7.5% of63Li and 92.5% of73Li

Calculate the relative atomic mass (Ar) of this sample of lithium.

[2]
Reveal mark scheme Mark scheme for question 2(b)(ii)

Chemistry Paper 1 November 2023, Question 2 10 marks

(a)

Table 1 shows some relative masses and charges of subatomic particles.

Complete table 1 by giving the missing information.

Figure for question 2
[2]
Reveal mark scheme Mark scheme for question 2(a)
(b)

Table 2 gives the number of protons, neutrons and electrons in atoms and ions of some elements.

The letters are not the symbols of the elements.

Figure for question 2
(b)(i)

What is the atomic number of P in table 2?

Question 2, shown as an image
[1]
Reveal mark scheme Mark scheme for question 2(b)(i)
(b)(ii)

What is the mass number of U in table 2?

Question 2, shown as an image
[1]
Reveal mark scheme Mark scheme for question 2(b)(ii)
(b)(iii)

Give the letter in table 2 that represents an element in Group 5 of the Periodic Table.

[1]
Reveal mark scheme Mark scheme for question 2(b)(iii)
(c)

Q and R represent isotopes of the same element.

(c)(i)

Explain, in terms of subatomic particles, why Q and R are isotopes.

[2]
Reveal mark scheme Mark scheme for question 2(c)(i)
(c)(ii)

A sample containing the isotopes Q and R has this percentage composition by mass.

Q = 20.6 %
R = 79.4 %

Calculate the relative atomic mass (Ar) of this sample of the element.

Give your answer to one decimal place.

[3]
Reveal mark scheme Mark scheme for question 2(c)(ii)

Chemistry Paper 1 June 2023 (R), Question 3 8 marks

(a)

The diagram represents an atom of an element.

Figure for question 3
(a)(i)

What is the particle labelled W?

Question 3, shown as an image
[1]
Reveal mark scheme Mark scheme for question 3(a)(i)
(a)(ii)

An atom of this element contains 13 neutrons.

What is the mass number of this element?

Question 3, shown as an image
[1]
Reveal mark scheme Mark scheme for question 3(a)(ii)
(a)(iii)

State why atoms have no overall charge.

[1]
Reveal mark scheme Mark scheme for question 3(a)(iii)
(a)(iv)

What is the charge on the ion usually formed from this element?

Question 3, shown as an image
[1]
Reveal mark scheme Mark scheme for question 3(a)(iv)
(b)

There are two isotopes of the element lithium.

Question 3, shown as an image
(b)(i)

State why both isotopes react in the same way.

[1]
Reveal mark scheme Mark scheme for question 3(b)(i)
(b)(ii)

A sample of lithium contains 7.60%36Li and 92.4%73Li

Calculate the relative atomic mass, Ar, of this sample of lithium.

Give your answer to two decimal places.

[3]
Reveal mark scheme Mark scheme for question 3(b)(ii)

Chemistry Paper 1 June 2023, Question 7 14 marks

This question is about the three halogens, bromine, chlorine and iodine.

(a)

Give the number of protons and the number of neutrons in an atom of iodine–127

number of protons

number of neutrons

[2]
Reveal mark scheme Mark scheme for question 7(a)
(b)

A sample of bromine contains two isotopes.

• Br–79 with relative abundance 52.8 %

• Br–81 with relative abundance 47.2 %

Calculate the relative atomic mass (Ar) of this sample of bromine.

Give your answer to three significant figures.

[3]
Reveal mark scheme Mark scheme for question 7(b)
(c)

Aluminium reacts with chlorine to form aluminium chloride.

This is the equation for the reaction.

Question 7, shown as an image

Calculate the minimum mass of chlorine needed to form 26.7 g of aluminium chloride.

[for Cl2, Mr = 71 for AlCl3, Mr = 133.5]

[3]
Reveal mark scheme Mark scheme for question 7(c)
(d)

A student mixes the following pairs of solutions.

Pair 1 bromine solution and potassium chloride solution

Pair 2 bromine solution and potassium iodide solution

Explain how the student can use the results of these experiments to show the order of reactivity of the three halogens, bromine, chlorine and iodine.

Include observations in your answer.

[6]
Reveal mark scheme Mark scheme for question 7(d)

Chemistry Paper 1 January 2023 (R), Question 6 11 marks

This question is about elements in Group 7 of the Periodic Table.

(a)(i)

Which element is a liquid at room temperature?

Question 6, shown as an image
[1]
Reveal mark scheme Mark scheme for question 6(a)(i)
(a)(ii)

What colour is solid iodine?

Question 6, shown as an image
[1]
Reveal mark scheme Mark scheme for question 6(a)(ii)
(a)(iii)

Describe a test for chlorine gas.

[2]
Reveal mark scheme Mark scheme for question 6(a)(iii)
(b)

A sample of chlorine, containing two isotopes, has this percentage composition by mass.

chlorine‑35 71.2% chlorine‑37 28.8%

Calculate the relative atomic mass of this sample of chlorine.

Give your answer to one decimal place.

[3]
Reveal mark scheme Mark scheme for question 6(b)
(c)

A student is given an aqueous solution of chlorine and an aqueous solution of sodium iodide.

Explain how the student can use these solutions to compare the reactivity of chlorine with the reactivity of iodine.

[4]
Reveal mark scheme Mark scheme for question 6(c)

Chemistry Paper 2 January 2023, Question 1 7 marks

(a)

The diagram shows the electronic configuration of an atom of an element.

Figure for question 1

Complete the table by giving the missing information.

Figure for question 1
[3]
Reveal mark scheme Mark scheme for question 1(a)
(b)

The table gives information about four different species, W, X, Y and Z.

SpeciesNumber of protonsNumber of neutronsNumber of electrons
W222
X131410
Y171817
Z172017
(b)(i)

Give the mass number of W.

[1]
Reveal mark scheme Mark scheme for question 1(b)(i)
(b)(ii)

Give a reason why X has a 3+ charge.

[1]
Reveal mark scheme Mark scheme for question 1(b)(ii)
(b)(iii)

Explain why Y and Z are isotopes of the same element.

[2]
Reveal mark scheme Mark scheme for question 1(b)(iii)

Chemistry Paper 1 June 2022 (R), Question 1 6 marks

(a)

The diagram represents an atom of an element.

Figure for question 1

Use numbers from the box to complete the table.

You may use each number once, more than once or not at all.

Figure for question 1
[4]
Reveal mark scheme Mark scheme for question 1(a)
(b)

In terms of sub‑atomic particles, state a similarity and a difference for isotopes of the same element.

similarity

difference

[2]
Reveal mark scheme Mark scheme for question 1(b)

Chemistry Paper 1 June 2022, Question 7 13 marks

This question is about copper and copper compounds.

(a)

A sample of copper contains two isotopes.

• Cu-63 with relative abundance 69.5%

• Cu-65 with relative abundance 30.5%

(a)(i)

State what is meant by the term isotopes.

[2]
Reveal mark scheme Mark scheme for question 7(a)(i)
(a)(ii)

Calculate the relative atomic mass (Ar) of this sample of copper.

Give your answer to three significant figures.

[3]
Reveal mark scheme Mark scheme for question 7(a)(ii)
(b)

When copper(II) carbonate is heated, copper(II) oxide and carbon dioxide are formed.

(b)(i)

What is the name of this type of reaction?

Question 7, shown as an image
[1]
Reveal mark scheme Mark scheme for question 7(b)(i)
(b)(ii)

Which colour change occurs during this reaction?

Question 7, shown as an image
[1]
Reveal mark scheme Mark scheme for question 7(b)(ii)
(c)

A student uses this apparatus to find the value of x in the formula CuSO4.xH2O

Figure for question 7

This is the student’s method.

• find the mass of an empty boiling tube

• add hydrated copper(II) sulfate to the tube and record the new mass

• heat the hydrated copper(II) sulfate until it changes colour

• allow the tube to cool and record the mass again

The table shows the student’s results.

Figure for question 7
(c)(i)

Calculate the mass of CuSO4 formed.

Question 7, shown as an image
[1]
Reveal mark scheme Mark scheme for question 7(c)(i)
(c)(ii)

Calculate the mass of water formed.

[1]
(c)(iii)

Show that the value of x is approximately 4

[Mr of CuSO4 = 159.5 Mr of H2O = 18]

[3]
Reveal mark scheme Mark scheme for question 7(c)(iii)
(c)(iv)

The actual value of x is 5

Give a reason why the calculated value of x is lower than the actual value.

[1]
Reveal mark scheme Mark scheme for question 7(c)(iv)

Chemistry Paper 2 June 2022 (R), Question 1 5 marks

The diagram shows the sub‑atomic particles in an atom of an element.

Figure for question 1
(a)(i)

Give the name of each of the sub‑atomic particles labelled P, Q and R.

[3]
Reveal mark scheme Mark scheme for question 1(a)(i)
(a)(ii)

Give the name of the part of the atom labelled S.

[1]
Reveal mark scheme Mark scheme for question 1(a)(ii)
(b)

Give the name of this element.

[1]
Reveal mark scheme Mark scheme for question 1(b)

Chemistry Paper 1 January 2022, Question 5 11 marks

Also involves Amounts of substance in equations · Limiting reactants

(a)

Complete the table to show the relative mass and relative charge of a proton and a neutron.

Figure for question 5
[2]
(b)

Magnesium has three isotopes.

(b)(i)

State the meaning of the term isotopes.

[2]
Reveal mark scheme Mark scheme for question 5(b)(i)
(b)(ii)

The symbol for an atom of one isotope of magnesium is

Question 5, shown as an image

Give the number of protons, neutrons and electrons in one atom of this isotope.

number of protons

number of neutrons

number of electrons

[2]
Reveal mark scheme Mark scheme for question 5(b)(ii)
(b)(iii)

A sample of magnesium contains these percentages of the three isotopes.

Mg‑24 = 79.00 % Mg‑25 = 10.00 % Mg‑26 = 11.00 %

Use this information to show that the relative atomic mass of magnesium is 24.32

[2]
Reveal mark scheme Mark scheme for question 5(b)(iii)
(b)(iv)

One mole of magnesium has a mass of 24.32 g. There are 6.022 × 1023 atoms in one mole.

Calculate the mass, in grams, of one atom of magnesium.

Give your answer to 4 significant figures.

[2]
Reveal mark scheme Mark scheme for question 5(b)(iv)
(c)

The equation for the reaction between magnesium and oxygen is

Question 5, shown as an image

Determine the maximum amount, in moles, of magnesium oxide that can be produced from 0.50 mol of magnesium and 0.20 mol of oxygen.

[1]
Reveal mark scheme Mark scheme for question 5(c)

Chemistry Paper 2 January 2021, Question 1 5 marks

The diagram shows an atom of an element.

Figure for question 1
(a)(i)

What is the name of the particle labelled Y?

Question 1, shown as an image
[1]
Reveal mark scheme Mark scheme for question 1(a)(i)
(a)(ii)

Give the mass number of this atom.

[1]
Reveal mark scheme Mark scheme for question 1(a)(ii)
(a)(iii)

Name this element.

Use the Periodic Table on page 2 to help you.

[1]
Reveal mark scheme Mark scheme for question 1(a)(iii)
(b)

There are two isotopes of this element.

Give one way, in terms of sub-atomic particles, that these isotopes are the same and one way that they are different.

[2]

Chemistry Paper 2 November 2020 (R), Question 2 7 marks

Thallium, Tl, is an element in Group 3 and Period 6 of the Periodic Table.

The atomic number of thallium is 81

(a)

How many electrons are there in the outer shell of an atom of thallium?

Question 2, shown as an image
[1]
Reveal mark scheme Mark scheme for question 2(a)
(b)

A thallium ion has a charge of 3+

How many electrons are there in this thallium ion?

Question 2, shown as an image
[1]
Reveal mark scheme Mark scheme for question 2(b)
(c)

A sample of thallium contains two isotopes.

The table shows the mass number and percentage abundance of each isotope in the sample.

IsotopeMass numberPercentage abundance (%)
thallium-20320330.80
thallium-20520569.20
(c)(i)

Give the number of protons and the number of neutrons in one atom of the thallium-205 isotope.

number of protons........

number of neutrons........

[2]
Reveal mark scheme Mark scheme for question 2(c)(i)
(c)(ii)

Calculate the relative atomic mass of this sample of thallium.

Give your answer to one decimal place.

[3]
Reveal mark scheme Mark scheme for question 2(c)(ii)

Chemistry Paper 1 January 2020 (R), Question 1 6 marks

The diagram shows the particles in the atom of an element.

Figure for question 1
(a)

Particle Y is a proton.

What is particle Z?

Question 1, shown as an image
[1]
Reveal mark scheme Mark scheme for question 1(a)
(b)

Which of these has the smallest mass?

Question 1, shown as an image
[1]
Reveal mark scheme Mark scheme for question 1(b)
(c)

What is the mass number of this atom?

Question 1, shown as an image
[1]
Reveal mark scheme Mark scheme for question 1(c)
(d)

What is the atomic number of this atom?

Question 1, shown as an image
[1]
Reveal mark scheme Mark scheme for question 1(d)
(e)(i)

Identify the element that contains this atom.

[1]
(e)(ii)

State what is formed when this atom loses its outer shell electrons.

[1]
Reveal mark scheme Mark scheme for question 1(e)(ii)

Chemistry Paper 1 January 2020, Question 2 8 marks

The diagram shows the electronic configuration of an atom of an element.

Figure for question 2
(a)

Complete the table by giving the missing information about this atom.

Figure for question 2
[5]
Reveal mark scheme Mark scheme for question 2(a)
(b)

This element has three isotopes.

The table shows the mass number and percentage abundance of each isotope in a sample of this element.

Mass numberPercentage abundance (%)
2479.2
2510.0
2610.8

Calculate the relative atomic mass (Ar) of this element.

Give your answer to one decimal place.

[3]
Reveal mark scheme Mark scheme for question 2(b)

Chemistry Paper 2 June 2019, Question 1 6 marks

The diagram shows the particles in an atom of an element.

Figure for question 1
(a)

The box gives the names of some particles.

Figure for question 1

Use words from the box to label the diagram.

[3]
Reveal mark scheme Mark scheme for question 1(a)
(b)

Give the mass number of this atom.

[1]
Reveal mark scheme Mark scheme for question 1(b)
(c)

Complete the sentence about isotopes.

Isotopes are atoms that have the same number of........

but have a different number of........ .

[2]
Reveal mark scheme Mark scheme for question 1(c)

Chemistry Paper 2 June 2019, Question 2 9 marks

The table gives some information about the halogens, chlorine, bromine and iodine.

HalogenPhysical state at room temperatureColour
chlorinegaspale green
brominered-brown
iodinesolid
(a)

Complete the table.

[2]
Reveal mark scheme Mark scheme for question 2(a)
(b)

Chlorine has two isotopes of mass numbers 35 and 37

The relative percentage of each isotope in a sample of chlorine is

chlorine-35 77.78% chlorine-37 22.22%

Calculate the relative atomic mass of this sample of chlorine.

Give your answer to one decimal place.

[3]
Reveal mark scheme Mark scheme for question 2(b)
(c)

A student is given an aqueous solution of chlorine and an aqueous solution of potassium bromide.

Explain how he can use these two solutions to compare the reactivity of chlorine with the reactivity of bromine.

[4]

Chemistry Paper 2 June 2019 (R), Question 2 7 marks

The diagram represents an atom of boron.

Figure for question 2
(a)

Use information from the diagram to complete the table.

The first row has been done for you.

Figure for question 2
[5]
Reveal mark scheme Mark scheme for question 2(a)
(b)

Boron has two isotopes, boron‑10 and boron‑11.

A sample of boron contains 18.7% of boron‑10 and 81.3% of boron‑11.

Calculate the relative atomic mass of this sample of boron.

[2]
Reveal mark scheme Mark scheme for question 2(b)

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