Question 1
The diagram represents an atom of an element.
Label the three subatomic particles on the diagram.
(3)
Use information from the diagram to complete the table for this element.
(4)
Give the name of this element.
(1)
The diagram represents an atom of an element.
Label the three subatomic particles on the diagram.
(3)
Use information from the diagram to complete the table for this element.
(4)
Give the name of this element.
(1)
A small piece of lithium is added to a trough of water.
State two observations made when lithium reacts with water.
(2)
What are the products of the reaction?
(1)
After the reaction is complete, a few drops of universal indicator are added to the solution in the trough.
Explain the colour and pH of the solution in the trough.
(3)
Give the formula of the ion responsible for this pH.
(1)
Lithium ions can be identified using a flame test.
What flame colour indicates the presence of lithium ions?
(1)
A student uses paper chromatography to investigate the dyes in five different inks, V, W, X, Y and Z.
The chromatogram shows the results of the investigation.
solvent front
V W X Y Z
Explain why the start line on the paper is drawn in pencil rather than in ink.
(2)
Explain which two inks contain the dye that is most soluble in the solvent.
(2)
Explain how the chromatogram shows that
• W contains only one dye
• V may contain more than one dye
(3)
Calculate the Rf value for the dye in W.
Give your answer to two significant figures.
(4)
Calcium phosphate is an ionic compound with the formula Ca3(PO4)2
What is the total number of atoms in the formula Ca3(PO4)2?
(1)
What are the correct charges on the ions in calcium phosphate?
(1)
Calculate the relative formula mass (Mr) of Ca3(PO4)2
Mr of Ca3(PO4)2 =........
(2)
Calculate the percentage by mass of calcium in calcium phosphate.
(2)
Calcium hydroxide can react with phosphoric acid to form calcium phosphate.
Complete the equation for this reaction.
(1)
Butane (C4H10) is an alkane.
Explain why butane is a saturated hydrocarbon.
(3)
When butane burns completely in oxygen, carbon dioxide and water are produced.
Give a chemical equation for this combustion reaction.
(2)
Incomplete combustion can occur when the oxygen supply is limited.
One product of the incomplete combustion of butane is carbon monoxide.
Give the name of another product of this incomplete combustion.
(1)
State why carbon monoxide is poisonous to humans.
(1)
C4H10 exists as two isomers.
State what is meant by the term isomers.
(2)
Draw the displayed formula of each isomer.
(2)
Explain why hexane (C6H14) has a higher boiling point than butane (C4H10).
(3)
When iron rusts, iron(III) oxide forms.
State two conditions needed for iron to rust.
(2)
What is the name of the process used to coat iron with zinc?
(1)
What is the correct order of reactivity of these four metals?
(1)
Describe a test to show that a solution contains Fe3+ ions.
test
(2)
result
A sample of iron(III) oxide reacts with excess carbon monoxide.
This is the equation for the reaction.
Explain why this is a redox reaction.
(2)
Calculate the minimum mass of iron(III) oxide needed to produce a theoretical yield of 28 g of iron.
[for Fe2O3 Mr = 160]
(3)
The actual yield of iron from this sample is 21 g.
Calculate the percentage yield of iron.
(2)
A student does an experiment to determine the maximum temperature change when sulfuric acid reacts with sodium hydroxide.
Complete the chemical equation for this neutralisation reaction.
Include the state symbols.
(2)
This is the student’s method.
Step 1 add 50 cm3 of sodium hydroxide solution to a glass beaker
Step 2 record the initial temperature of the sodium hydroxide solution
Step 3 add 5 cm3 of dilute sulfuric acid to the beaker
Step 4 stir the mixture and record the highest temperature reached
The student repeats steps 3 and 4 until a total of 40 cm3 of acid has been added.
Explain one way the student could improve the accuracy of the experiment.
(2)
The table shows the student’s results.
| Total volume of acid in cm3 | 0 | 5 | 10 | 15 | 20 | 25 | 30 | 35 | 40 |
| Temperature of mixture in | 21.0 | 22.3 | 23.8 | 24.4 | 26.5 | 28.0 | 28.5 | 28.2 | 27.9 |
Draw a circle around the anomalous result.
(1)
Draw a straight line of best fit through the first six points, ignoring the anomalous result.
Draw another straight line of best fit through the last three points.
Make sure that the two lines cross.
Volume of sulfuric acid in cm3
(2)
The point where the lines cross shows the volume of acid needed to exactly neutralise the alkali and the maximum temperature reached.
Use your graph to determine these values.
(2)
Explain what might have caused the anomalous result.
(2)
Diamond and graphite are two naturally‑occurring forms of carbon.
They both have giant covalent structures.
Explain, with reference to its bonding, why diamond has a high melting point.
(3)
Explain why graphite is soft and is a conductor of electricity.
Refer to structure and bonding in your answer.
(6)
This question is about organic compounds.
Chloroethene (C2H3Cl) is a covalent molecule that is used to make poly(chloroethene).
This is the displayed formula of chloroethene.
Draw a dot‑and‑cross diagram of chloroethene.
Show only the outer shell electrons.
(2)
Describe, in terms of electrostatic attraction, what is meant by a covalent bond.
(2)
Chloroethene is a monomer.
Draw the displayed formula of the repeat unit of poly(chloroethene).
(1)
Poly(chloroethene) is non‑biodegradable.
There are two main methods used to dispose of poly(chloroethene).
Describe one problem caused by each method.
(4)
An organic compound contains this percentage composition by mass.
C = 22.0% H = 4.6% Br = 73.4%
Calculate the empirical formula of this compound.
(3)
Ethane and ethene undergo different types of reaction with bromine.
Describe the differences between these two reactions.
(5)
A student uses this apparatus to investigate the energy content of different fuels.
This is the student’s method.
• pour some water into the copper can
• record the mass of the spirit burner and fuel
• measure the initial temperature of the water
• place the spirit burner under the copper can and light the burner
• stop heating the water when the temperature reaches 30C
• record the new mass of the spirit burner and fuel
The student repeats the experiment with different fuels.
Explain two variables the student should control to make this a valid test.
(4)
In one of the experiments, the student uses ethanol as the fuel.
These are the student’s results for ethanol.
Calculate the value of heat energy change (Q) in joules.
[for water, c = 4.2 J/g/C 1.0 cm3 of water has mass = 1.0 g]
(2)
Calculate the enthalpy change (Δ H) in kJ/mol.
[for ethanol, Mr = 46]
Include a sign in your answer.
ΔH =........ kJ/mol
(5)
The paper as printed
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