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Chemistry · Edexcel 1CH0 · Paper 2 · Foundation · June 2019

Edexcel GCSE Chemistry Paper 2 Foundation June 2019 question paper 1CH0/2F

1h 45m 100 marks

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Edexcel 1CH0 · Paper 2F

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Question 1

(a)

Plants release oxygen into the atmosphere.

What is the name of the process that releases oxygen into the atmosphere?

Question 1, shown as an image

(1)

(b)

The atmosphere contains 21% of oxygen.

(b)(i)

Figure 1 shows an incomplete bar chart of the main gases in the atmosphere.

Figure for question 1

Complete the bar chart by showing the percentage of oxygen in the atmosphere.

(1)

(b)(ii)

Calculate the volume of oxygen present in 300 cm3 of air.

(volumes are measured under the same conditions of temperature and pressure)

(2)

(c)

An atom of an element has an atomic number and a mass number.

Draw one straight line from each of these to the numbers of subatomic particles it shows to be present in an atom.

number of subatomic particles in an atom

Figure for question 1 Figure for question 1

(2)

(d)

Which test shows a gas is oxygen?

Question 1, shown as an image

(1)

Question 2

(a)

Complete the following sentences.

(a)(i)

The name given to group 7 in the periodic table is........ .

(1)

(a)(ii)

The name given to group 0 in the periodic table is........ .

(1)

(b)

Which of the following rows gives the colours of the group 7 elements chlorine and bromine at room temperature?

Figure for question 2

(1)

(c)

Figure 2 shows the melting and boiling points of bromine and iodine.

elementmelting point in Cboiling point in C
bromine–759
iodine114184
Question 2, shown as an image

Using the information in Figure 2, which row shows the physical states of these elements at 50maths symbolC?

Figure for question 2

(1)

(d)

The densities of some elements in group 0 are shown in Figure 3.

Figure for question 2

Use the information in Figure 3 to suggest the density of krypton.

Question 2, shown as an image

(1)

(e)

For many years, argon was used to fill filament light bulbs.

A filament light bulb is shown in Figure 4.

Figure for question 2

When the bulb is in use the metal filament becomes extremely hot.

Explain why argon, rather than air, was used to fill filament light bulbs.

(2)

Question 3

Polymer molecules can be made by joining together large numbers of small molecules called monomers.

(a)

Figure 5 shows the names and structures of some polymers and the monomers used to make them.

Complete the table using the information given.

Figure for question 3

(3)

(b)

Plastics are polymers.

State two problems caused by the disposal of polymers.

(2)

(c)

A molecule of propene has the structure shown in Figure 6.

Figure for question 3

Which of the following shows the structure of part of a poly(propene) molecule?

Question 3, shown as an image
Question 3, shown as an image
Question 3, shown as an image
Question 3, shown as an image
Question 3, shown as an image

H H H H H H

Question 3, shown as an image
Question 3, shown as an image
Question 3, shown as an image
Question 3, shown as an image
Question 3, shown as an image

(1)

(d)
Question 3, shown as an image

Calculate the relative formula mass of the poly(propene) molecule made from joining together 24 600 molecules of propene, C3H6. (relative formula mass: C3H6 = 42.0)

Give your answer to three significant figures.

(2)

Question 4

A student poured 50 cm3 water into a beaker and measured the water’s temperature.

Figure for question 4

The student added 1.00 g calcium chloride to the water, stirred the mixture and then recorded the temperature.

(a)

Give the name of the apparatus that could be used to measure 1.00 g of calcium chloride.

(1)

(b)

The student’s results were

temperature of water at start = 21maths symbolC temperature of mixture after stirring = 32maths symbolC

Explain, using these results, the type of heat energy change that occurs when calcium chloride dissolves in water.

(2)

(c)

Calcium chloride is hazardous to health.

(c)(i)

Which hazard symbol would be expected to be seen on a container of calcium chloride?

Figure for question 4

(1)

(c)(ii)

Give a safety precaution that the student should take during the experiment.

(1)

(d)

State one way in which the apparatus could be changed to reduce the amount of heat energy lost during the experiment.

(1)

(e)

The concentration of a calcium chloride solution is 12 g dm–3.

Calculate the volume of this solution, in cm3, that contains 9.0 g of calcium chloride.

You must show your working.

(3)

Question 5

(a)

Propene can be produced by the cracking of some hydrocarbons obtained from crude oil.

The equation shows the cracking of one molecule of decane to produce one molecule of butene and one molecule of another product.

Question 5, shown as an image

decane butene

(a)(i)

Calculate the values of x and y in CxHy.

(2)

(a)(ii)

State the total mass of products formed if 25 g of decane is cracked in this way.

(1)

(b)

The structure of a molecule of ethene is shown in Figure 8.

Figure for question 5
(b)(i)

Figure 9 shows the incomplete dot and cross diagram for a molecule of ethene.

Figure for question 5

Complete Figure 9 to show the electrons of the C fraction C double bond.

(1)

(b)(ii)

The incomplete combustion of ethene in air produces water as one of the products.

Give the name of another product of the incomplete combustion of ethene.

(1)

(c)

Substance X is an unsaturated hydrocarbon. The structure of a molecule of substance X is shown in Figure 10.

Question 5, shown as an image
Question 5, shown as an image
Figure for question 5

Explain how the structure of substance X shows that it is an unsaturated hydrocarbon.

(2)

(d)

Two liquid hydrocarbons, A and B, were tested with bromine water. One hydrocarbon was known to be an alkane. The other hydrocarbon was known to be an alkene.

Each hydrocarbon was shaken with a few drops of bromine water.

The results of the tests were hydrocarbon A + bromine water: the mixture turned from orange to colourless. hydrocarbon B + bromine water: the orange colour remained.

Explain these results.

(2)

Question 6

The word equation for the reaction between magnesium and dilute hydrochloric acid is

magnesium + hydrochloric acid maths symbol magnesium chloride + hydrogen

The reaction was carried out using the apparatus shown in Figure 11.

Figure for question 6
Question 6, shown as an image

A strip of magnesium ribbon was placed in the conical flask. 100 cm3 of dilute hydrochloric acid was added to the conical flask.

The mass of the flask and contents was measured at regular intervals. The loss in mass was calculated. Figure 12 shows a graph of the results.

Figure for question 6
(a)

Name the apparatus that could be used to measure out 100 cm3 of dilute hydrochloric acid.

(1)

(b)

Explain why there is a loss in mass of the flask and contents.

(2)

(c)

The graph shows that the rate of reaction slows as the reaction takes place.

Explain, in terms of particles, why the rate of reaction between magnesium ribbon and dilute hydrochloric acid slows as the reaction takes place.

(3)

(d)

The experiment was repeated using the acid at a higher temperature. All other conditions were kept the same.

State the effect of the higher temperature on the mass loss after two minutes.

(1)

(e)

The original experiment was repeated using the same mass of magnesium powder instead of the magnesium ribbon. All other conditions were kept the same.

Sketch, on the graph in Figure 12, the line you would expect for this experiment.

(2)

(f)

Some reactions are affected by the presence of a catalyst.

(f)(i)

State the effect of a catalyst on a reaction.

(1)

(f)(ii)

Devise a simple experiment to find out what happens to the mass of a solid catalyst during a reaction.

(3)

Question 7

(a)

Qualitative tests are carried out on ionic substances to identify the ions present in the substances.

The test for a given ion must be unique to that ion.

(a)(i)

Explain why the test for a given ion must be unique to that ion.

(2)

(a)(ii)

In the test for the carbonate ion, CO32–, dilute hydrochloric acid is added to the solid being tested.

State the name of the gas produced in the test if carbonate ions are present.

(1)

(a)(iii)

Tests for three ions are described.

Draw one straight line from the test for each ion to the observation that shows that ion to be present. Each observation may be correct for one test, more than one test, or for none of the tests.

description of test
observation

Figure for question 7
Question 7, shown as an image
Figure for question 7

(3)

(b)

*(b) A white solid is known to be a chloride in which the metal ion is sodium, potassium, calcium or aluminium.

A chemist was told to carry out a test for each metal ion that could be present in this white solid.

Describe tests to show the presence of each of these metal ions.

(6)

Question 8

Most of the fuels used today are obtained from crude oil.

(a)

Which statement about crude oil is correct?

Question 8, shown as an image

(1)

(b)

Crude oil is separated into several fractions by fractional distillation. Two of these fractions are kerosene and diesel oil.

(b)(i)

State a use for each of these fractions.

(2)

(b)(ii)

Figure 13 shows where the fractions kerosene and diesel oil are produced in the fractionating column.

Figure for question 8

Kerosene is obtained higher up the column than diesel oil. Kerosene and diesel oil fractions have slightly different properties.

Choose a property. State how this property for kerosene compares with the property for diesel oil.

(1)

(c)

Figure 14 shows the formulae of a molecule of butane and of a molecule of pentane. Butane and pentane are neighbouring members of the same homologous series.

H H H H
H H H H H

Question 8, shown as an image

H H H H
H H H H H

butane pentane

Figure 14

(c)(i)

Explain, using these formulae, why butane and pentane are neighbouring members of the same homologous series.

(2)

(c)(ii)

Butane has the formula C4H10.

Calculate the mass of carbon in 100 g of butane.

Give your answer to three significant figures.

(relative atomic masses: H = 1.00, C = 12.0; relative formula mass: C4H10 = 58.0)

You must show your working.

(3)

(c)(iii)

Butane burns completely in air to form carbon dioxide and water.

Write the word equation for this reaction.

(2)

Question 9

(a)

An aluminium atom has the atomic number 13 and the mass number 27.

Which row shows the numbers of subatomic particles present in an

Question 9, shown as an image
Figure for question 9

(1)

(b)

Magnesium burns in excess oxygen to form magnesium oxide. The balanced equation for this reaction is

Starting with 1.35 g of magnesium, calculate the maximum mass of magnesium oxide that could be formed in this reaction. (relative atomic masses: O = 16.0, Mg = 24.0)

You must show your working.

(3)

(c)

Chlorine reacts with hydrogen to form hydrogen chloride.

Write the balanced equation for this reaction.

(3)

(d)

*(d) Sodium chloride is an ionic compound, containing sodium ions, Na+, and chloride ions, Cl–.

Figure 15 shows the electronic configuration of sodium and chlorine.

Figure for question 9

Explain how sodium and chlorine atoms form the ions in sodium chloride and how the ions are arranged in the solid sodium chloride.

You may wish to use diagrams in your answer.

(6)

Question 10

(a)

Ethanol is made by fermentation of a carbohydrate dissolved in water, in the presence of yeast.

The reaction is carried out at 30maths symbolC.

Explain why the reaction is carried out at a temperature of 30maths symbolC rather than at a

Question 10, shown as an image

(2)

(b)

Ethanol, C2H5OH, can be converted into ethanoic acid, CH3COOH.

(b)(i)

In this reaction ethanol is

Question 10, shown as an image

(1)

(b)(ii)

Draw the structure of a molecule of ethanoic acid, CH3COOH, showing all covalent bonds.

(2)

(c)
(c)(i)

The apparatus in Figure 16 can be used to investigate the temperature rise produced in a known mass of water when a sample of ethanol is burned.

Figure for question 10

The first steps of the method are

NK =$put=NMMcm3 of water into a beaker 2. maths symbol determine the mass of the burner containing ethanol 3. maths symbol measure the initial temperature of the water 4. maths symbol place the burner under the beaker of water

Question 10, shown as an image

Describe the remaining steps of the method that are needed to determine the mass of ethanol required to raise the temperature of the water by 30maths symbolC.

(3)

(c)(ii)

In a different experiment, separate samples of the alcohols methanol, ethanol, propanol, butanol and pentanol were burned to determine the mass of each alcohol that needs to be burned to raise the temperature of 100 cm3 water by 10maths symbolC.

alcoholnumber of carbon atoms in one molecule of alcoholmass of alcohol burned in g
methanol10.37
ethanol20.28
propanol30.25
butanol40.23
pentanol50.22

Draw a graph of the mass of each alcohol required to raise the temperature of 100cm3 of water by 10maths symbolC against the number of carbon atoms in one molecule of that alcohol.

Figure for question 10

(3)

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