Edexcel GCSE Combined Science Paper 4: Chemistry 2 Higher June 2023 question paper 1SC0/2CH

A student used the apparatus shown in Figure 1 to investigate the reaction between

The student recorded the volume of gas every minute as shown in Figure 2.

On the grid, plot the results shown in Figure 2.

Draw a curve of best fit.

Rate of reaction can be calculated using

Figure 3 shows the rates of reaction calculated from the results of this experiment.

The rate of reaction for the time interval 2 to 3 minutes is missing.

Calculate the rate of reaction for the time interval 2 to 3 minutes.

rate of reaction =_........ cm³min

State and explain what happens to the rate of reaction as the acid reacts with the marble chips in this experiment.

The student repeated the experiment using the same volume of acid and the same mass of marble chips but used smaller marble chips.

All other conditions remained the same.

The student found that the reaction with the smaller marble chips was faster to start with but produced the same volume of gas.

Using this information, draw a line on the grid to show the results for the reaction with the smaller marble chips.

Label this line ‘C’.

Figure 4 shows some information about the group 1 metals.

Explain, in terms of their electronic configurations, why these metals are placed in group 1 of the periodic table.

Which row shows two correct properties of group 1 metals?

The word equation for the reaction of potassium with bromine is

potassium + bromine potassium bromide

Add the missing state symbol and balance the equation for this reaction.

A sample of potassium contains three isotopes, potassium-39, potassium-40 and potassium-41.

Explain the meaning of the term isotopes.

This sample of potassium contains

93.25% potassium-39

0.02% potassium-40

6.73% potassium-41

Calculate the relative atomic mass of this sample of potassium.

Figure 5 shows the percentage of three gases, X, Y and Z, in the Earth’s early atmosphere.

What is the name of gas Z ?

It is thought that small quantities of hydrogen sulfide, H₂S, were also in the Earth’s early atmosphere.

Draw the dot and cross diagram for a molecule of hydrogen sulfide.

Show outer electrons only.

Acid rain is caused by some pollutant gases present in the atmosphere.

Explain how impurities in fossil fuels can result in acid rain.

A student investigates the effect of acid rain on cress plants.

The student uses this method.

step 1 grow 20 cress plants in each of two dishes, A and B

step 2 water the cress plants in dish A with 10 cm³ of dilute hydrochloric acid with a pH of 2

step 3water the cress plants in dish B with 10 cm³ of pure water with a pH of 7

step 4 repeat steps 2 and 3 every day for one week

step 5 count how many plants are still alive after one week.

State what piece of equipment the student could use to measure the pH of each liquid.

Explain one improvement that the student could make to the method to make the results more valid.

Chlorine gas can be prepared by reacting concentrated hydrochloric acid with solid potassium manganate(VII).

Figure 6 shows the apparatus used.

Figure 7 shows the hazard symbols for concentrated hydrochloric acid, potassium manganate(VII) and chlorine gas.

Use the information in Figure 7 to help you answer (a)(i) and (a)(ii).

What are the hazards associated with potassium manganate(VII)?

Explain one precaution that should be taken when preparing the sample of chlorine gas.

precaution

reason

State the purpose of the delivery tube.

Suggest why damp blue litmus is placed at the top of the gas jar.

In the reaction, potassium manganate(VII), KMnO₄, reacts with hydrochloric acid to form manganese chloride, MnCl₂, potassium chloride, chlorine and water.

Write the balanced equation for the reaction.

Ammonia can be produced from the reaction of hydrogen with nitrogen.

What is the percentage by mass of nitrogen in ammonia, NH₃?

(relative atomic masses: H = 1.0, N = 14)

The reaction between hydrogen and nitrogen is exothermic.

Figure 8 shows the reaction profile of this exothermic reaction.

Which arrow represents the activation energy for the reaction?

Describe what the reaction profile shows about the energy involved in bond breaking and bond making in this reaction.

Ammonia, NH₃, and silicon dioxide, SiO₂, are both compounds that are made of two non-metallic elements.

Ammonia has a boiling point of –33 °C. Silicon dioxide has a boiling point of 2230 °C.

Explain why the boiling points of ammonia and silicon dioxide are so different.

Crude oil is a mixture of hydrocarbons.

Crude oil can be separated into useful fractions by the process of fractional distillation in a fractionating column.

Figure 10 shows a fractionating column, the fractions obtained and the trend in viscosity of the fractions.

Which row shows the correct uses for bitumen, diesel oil and fuel oil?

Explain the trend in the viscosity of the fractions.

Hydrocarbon X was cracked to form one molecule of hexane, C₆H₁₄, and one molecule of alkene Y.

The relative formula mass of Y is 56. The empirical formula of Y is CH₂.

Deduce the molecular formula of hydrocarbon X.

Show your working.

(relative atomic masses: H = 1.0, C = 12)

*(c) Large quantities of methane are used as a fuel.

Figure 11 shows a Bunsen burner.

Methane can be used as fuel for the Bunsen burner.

The air-hole on the chimney of the Bunsen burner can be opened and closed.

Explain the effect of opening and closing the air-hole of the Bunsen burner on the products of combustion of methane and the harm that using large quantities of methane as a fuel can cause.