Reactions of acids

Sodium carbonate has the formula Na₂CO₃.

Sodium carbonate contains Na⁺ ions and CO₃^2– ions.

The atomic number of sodium is 11.

What is the electronic configuration of the Na⁺ ion?

Explain why solid sodium carbonate cannot conduct electricity but a solution of sodium carbonate can conduct electricity.

Calculate the percentage by mass of sodium in sodium carbonate, Na₂CO₃.

(relative atomic masses: C = 12, O = 16, Na = 23)

percentage by mass of sodium =_........

*(c) A student has three solids, A, B and C.

The solids are sodium carbonate, powdered zinc and copper oxide, but the student does not know which solid is which.

The student reacted each solid with dilute sulfuric acid.

Figure 15 shows the student’s observations and the results of tests on any gases produced.

Use the observations and results in Figure 15 to identify which solid is which.

Your answer should include

• how each test result helps you to identify the solid

• word equations to support your answer.

Barium hydroxide reacts with dilute hydrochloric acid to form barium chloride solution and water.

Complete the balanced equation for the reaction by adding a number in front of HC l (aq).

State what you would see during the reaction.

A student investigated how the pH of the mixture changed as barium hydroxide was added to dilute hydrochloric acid.

The student used this method.

step 1 measure out 50 cm3³ of dilute hydrochloric acid into a beaker using a measuring cylinder

step 2 use a glass rod to place a drop of the acid onto a piece of universal indicator paper and record the pH

step 3 add one spatula measure of barium hydroxide to the acid in the beaker and stir

step 4 use the glass rod to place a drop of the mixture onto a new piece of universal indicator paper and record the pH again

step 5 repeat steps 3 and 4 until there is no further change in the pH.

Name a piece of equipment that could be used to measure the pH of a substance more accurately than universal indicator paper.

Explain why, in step 3, the mixture was stirred after adding the barium hydroxide.

Figure 3 shows the student’s results.

Plot a graph of the pH of the mixture against the number of spatula measures of barium hydroxide.

Use the graph to find the pH of the mixture when 4.5 spatula measures of barium hydroxide are added.

Titration can be used to find the volume of dilute hydrochloric acid needed to neutralise 25.0 cm³ of barium hydroxide solution.

Before the titration is carried out, the pipette and conical flask are rinsed out with pure water.

Explain the effect, if any, that traces of water in the pipette and conical flask after rinsing could have on the titration result.

pipette

conical flask

In the titration, a few drops of phenolphthalein indicator are added to the barium hydroxide solution.

State the change in colour of phenolphthalein at the end point, when the barium hydroxide solution has just been neutralised.

Write the ionic equation for the neutralisation reaction that occurs when hydrochloric acid is added to barium hydroxide solution.

When barium hydroxide solution is neutralised by dilute sulfuric acid, a white precipitate of barium sulfate is formed in the conical flask.

Describe an experiment to obtain a sample of pure, dry barium sulfate from the contents of the conical flask.

In an experiment, powdered calcium hydroxide was added to dilute hydrochloric acid and the pH was measured.

The method used was

step 1 measure 200 cm3³ dilute hydrochloric acid into a beaker

step 2 aadd 0.1 g of powdered calcium hydroxide to the beaker

step 3 find the pH of the mixture

step 4 repeat steps 2 and 3 until the pH stops changing.

State what should be done after step 2 to make sure that any reaction is complete.

Complete the word equation for the reaction.

calcium hydroxide + hydrochloric acid _........

Which row of the table shows the state symbols for powdered calcium hydroxide and dilute hydrochloric acid in the balanced chemical equation?

The results of the experiment are shown in Figure 12.

mass of calcium hydroxide added in grams

Figure 12

Using Figure 12, give the pH of the acid at the start of the experiment.

Using Figure 12, give the mass of calcium hydroxide required to make a neutral mixture.

Explain why the pH starts at a low value and ends at a higher value.

State what should be used to measure the pH of the mixture in this experiment.

The calcium hydroxide used is corrosive to the eyes and an irritant to skin.

Using this information, state one safety precaution that should be taken during the experiment when using any corrosive substance.

A student wanted to find the volume of dilute hydrochloric acid that would react with 25.0 cm³ of lithium hydroxide solution.

They used the equipment in Figure 7 to carry out a rough titration and then a further two accurate titrations.

Suggest why the student carried out a rough titration before the two accurate titrations.

Figure 8 shows the results of the rough titration.

What was the volume of acid added in the rough titration?

Describe how the rough titration should be carried out once the dilute hydrochloric acid, lithium hydroxide solution and indicator are placed in the apparatus in Figure 7.

Which is the name of an indicator that is suitable to use in this titration?

During the titration the dilute hydrochloric acid, HC l, is reacting with the lithium hydroxide solution, LiOH.

Explain what type of reaction is taking place in the titration.

Magnesium carbonate has the formula MgCO₃.

Magnesium carbonate contains Mg²⁺ and CO₃²⁻ ions.

The atomic number of magnesium is 12.

What is the electronic configuration of the Mg²⁺ ion?

Explain why solid magnesium carbonate cannot conduct electricity but solid magnesium can.

Calculate the percentage by mass of magnesium in magnesium carbonate, MgCO₃.

(relative atomic masses: C = 12.0, O = 16.0, Mg = 24.0)

*(c) A student has two separate test tubes containing sulfuric acid.

The student adds a spatula measure of magnesium carbonate, MgCO₃, to the first test tube and a piece of magnesium to the second test tube.

Explain what the student would see in each test tube and the tests that they should carry out to identify the gases produced.

Your answer should include word equations for the reactions that would take place.

Magnesium carbonate has the formula MgCO₃.

Magnesium carbonate contains Mg²⁺ and CO₃²⁻ ions.

The atomic number of magnesium is 12.

What is the electronic configuration of the Mg²⁺ ion?

Explain why solid magnesium carbonate cannot conduct electricity but solid magnesium can.

Calculate the percentage by mass of magnesium in magnesium carbonate, MgCO₃.

(relative atomic masses: C = 12.0, O = 16.0, Mg = 24.0)

percentage by mass of magnesium =_........

Magnesium carbonate reacts with dilute hydrochloric acid. Water and carbon dioxide are two of the products of the reaction.

Complete the balanced equation for this reaction.

The scientist John Dalton lived over 200 years ago.

John Dalton suggested an early model of atoms.

When Dalton first described atoms he said that

• all elements are made of atoms

• atoms are not formed of any smaller particles

• all atoms of the same element are identical.

Give two differences between Dalton’s model of atoms and today’s model of atoms.

Dalton also investigated different gases.

One of the gases that Dalton investigated was ethene.

The structure of one molecule of ethene is shown in Figure 8.

Give the molecular formula and the empirical formula of ethene.

Another gas that Dalton investigated was chlorine.

Chlorine gas reacts with water. The two products are a solution of hydrogen chloride and the substance HC l O.

Complete the balanced equation for this reaction, including the three missing state symbols.

Hydrogen chloride solution is acidic.

The formulae of four ions are shown in Figure 9.

Give the formula of the ion in Figure 9 that causes the hydrogen chloride solution to be acidic.

An acid reacts with an alkali.

Give the name of this type of reaction.

Describe what you would see when some copper carbonate powder is added to a beaker of dilute sulfuric acid.

The scientist John Dalton lived over 200 years ago.

John Dalton suggested an early model of atoms.

When Dalton first described atoms he said that

• all elements are made of atoms

• atoms are not formed of any smaller particles

• all atoms of the same element are identical.

Give two differences between Dalton’s model of atoms and today’s model of atoms.

Dalton also investigated different gases.

One of the gases that Dalton investigated was ethene.

The structure of one molecule of ethene is shown in Figure 2.

Give the molecular formula and the empirical formula of ethene.

Another gas that Dalton investigated was chlorine.

Chlorine gas reacts with water. The two products are a solution of hydrogen chloride and the substance HC l O.

Complete the balanced equation for this reaction, including the three missing state symbols.

Hydrogen chloride solution is acidic.

The formulae of four ions are shown in Figure 3.

Give the formula of the ion in Figure 3 that causes the hydrogen chloride solution to be acidic.

An acid reacts with an alkali.

Give the name of this type of reaction.

Copper carbonate reacts with dilute nitric acid.

During the reaction the copper carbonate powder completely disappears.

State what can be deduced about the amount of acid used.

During the reaction, the pH of the mixture changed from 2 to 6.

By what factor has the concentration of the hydrogen ions in the mixture changed?

Using different reactants, a solution of copper sulfate was prepared.

Describe what should be done to obtain copper sulfate crystals from this copper sulfate solution.

When chloride ions are added to a pale blue solution containing copper ions, the mixture turns yellow.

This is a reversible reaction.

pale blue solution + chloride ions yellow solution + water

What effect does the removal of chloride ions have on the colour of the yellow mixture?

Hydrated copper sulfate has the formula CuSO₄.5H₂O. The formula tells us that each mole of copper sulfate contains 5 moles of water.

A sample of CuSO₄.5H₂O was heated gently until all the water was removed to form anhydrous copper sulfate, CuSO₄.

The mass of water formed was 4.5 g.

Calculate the mass of hydrated copper sulfate that was heated.

(relative atomic masses: H = 1.0, O = 16.0; relative formula mass: CuSO₄.5H₂O = 249.5)

mass of CuSO₄.5H₂O =_........

When solid sodium chloride is mixed with water, sodium chloride solution forms.

What name is given to the process of mixing a solid with water to form a solution?

Sodium reacts with hydrochloric acid to form sodium chloride and hydrogen.

Write the word equation for this reaction.

The hazard symbol shown in Figure 1 is used on containers of sodium.

What is the meaning of this hazard symbol?

Hydrogen has one electron in its electron shell. Figure 2 shows the incomplete dot and cross diagram of a hydrogen molecule.

Complete Figure 2 to show the electrons in the covalent bond between the two atoms of hydrogen.

The pH of a sodium chloride solution was measured.

State what could be used to measure the pH of a solution.

Sodium chloride solution is neutral.

Give the pH of this solution.

In the 19th century, Mendeleev arranged the elements known at the time to form his periodic table. Mendeleev’s periodic table is different from the modern periodic table.

State one difference between Mendeleev’s periodic table and the modern periodic table.

Aluminium oxide reacts with hydrochloric acid to form a salt and water.

State the name of the salt formed.

In this reaction aluminium oxide is a base.

State the type of reaction that takes place when an acid reacts with a base.

Gallium, Ga, is in the same group of the modern periodic table as aluminium.

The formula of aluminium oxide is Al₂O₃.

Predict the formula of gallium oxide.

Gallium oxide has a very high melting point. Gallium oxide does not conduct electricity when solid but does conduct electricity when molten.

What type of substance is gallium oxide?

Figure 5 shows the changes of state for gallium and the arrangement of particles in liquid gallium.

Complete the boxes for solid gallium and gaseous gallium by drawing the arrangement of the particles in each of these physical states.

Give the name of the change of state labelled Y in Figure 5.

Gallium metal is a conductor of electricity.

Explain how metals conduct electricity.

The word equation for the reaction between copper carbonate and dilute sulfuric acid is

copper sulfuric copper carbon

Complete the balanced equation for this reaction.

Calculate the relative formula mass of copper carbonate, CuCO₃. (relative atomic masses: C = 12.0, O = 16.0, Cu = 63.5)

relative formula mass of CuCO₃ =_........

What is the chemical test to show that a gas is carbon dioxide?

Figure 4 shows a conical flask containing dilute sulfuric acid. Copper carbonate is added to the acid in the flask. The copper carbonate is added one spatula measure at a time until the reaction has finished.

State two observations that would show the reaction has finished.

The electronic configuration of carbon is 2.4 The electronic configuration of oxygen is 2.6

Draw a dot and cross diagram for a molecule of carbon dioxide.

Show outer electrons only.

Dilute hydrochloric acid is a strong acid.

Explain why dilute hydrochloric acid is described as a strong acid.

1 cm³ of hydrochloric acid of pH 2 is made up to a volume of 10 cm³ with distilled water.

State the pH of the new solution.

Magnesium oxide reacts with dilute hydrochloric acid to produce magnesium chloride solution and water.

Write the ionic equation for this reaction.

In an experiment magnesium hydroxide powder is added in 0.1 g portions to 25 cm³ of dilute hydrochloric acid until the magnesium hydroxide is just in excess.

Universal indicator paper can be used to test the pH of the solution after each addition of magnesium hydroxide.

Give the name of an alternative piece of equipment that can be used to measure pH.

State and explain how the pH changes as the magnesium hydroxide is added to the dilute hydrochloric acid.

(a) X and Y are solutions of two different acids. The concentration of acid in each solution, in mol dm⁻³, is the same. Solution X has a pH of 3.40 and solution Y has a pH of 4.40.

State what could be used to measure these pH values of 3.40 and 4.40.

What is the concentration of hydrogen ions in solution X compared with that in solution Y ?

An experiment is planned to record the change in pH as a powdered base is added to 50 cm³ dilute hydrochloric acid.

The method suggested is

step 1 add dilute hydrochloric acid up to the 50 cm³ mark on a beaker

step 2 add one spatula of the base and stir

step 3 measure the pH of the mixture

step 4 repeat steps 2 and 3 until the pH stops changing.

State how you could change the method so that the amounts of dilute hydrochloric acid and of the base can be measured more accurately.

dilute hydrochloric acid_........

During the experiment the pH changes from 2 to 10. If phenolphthalein indicator is added at the beginning of the experiment, a colour change occurs as the base is added.

State the colour change that occurs.

Explain, in terms of the particles present, why the pH increases during the experiment.

*(c) Some properties of four solids, A, B, C and D, are shown in Figure 6.

The solids, in no particular order, are copper carbonate, copper oxide, magnesium metal and sodium hydroxide.

Identify the solids A, B, C and D, explaining how the information in Figure 6 supports the identification of each solid.

(a) Nitric acid can be titrated with a solution of ammonia.

State the type of reaction occurring when nitric acid reacts with ammonia.

What salt is formed in this reaction?

In one stage of the production of nitric acid, nitrogen oxide, NO, is reacted with oxygen to make nitrogen dioxide, NO₂.

Calculate the minimum volume of air, measured at room temperature and pressure, required to react with 1000 g nitrogen oxide to form nitrogen dioxide.

Assume that the air contains 20% oxygen by volume. (relative atomic masses: N = 14, O = 16 1 mol of gas occupies 24 dm³ at room temperature and pressure)

*(c) In another stage in the production of nitric acid, ammonia is reacted with oxygen to form nitrogen oxide and water.

Heat energy is given out when ammonia reacts with oxygen.

The conditions chosen for the reaction are

• excess air, rather than just the right amount

• a pressure of 10 atm, rather than atmospheric pressure

• a temperature of 900 °C, rather than room temperature.

Explain the effect of the conditions chosen on the equilibrium yield of nitrogen oxide and on the rate of attainment of equilibrium.