Oxidation & reduction in terms of electrons

Figure 11 shows part of the reactivity series of metals.

The method used to extract a metal from its ore is related to the metal’s position in the reactivity series.

Which metal is found in the Earth’s crust as an uncombined element?

Name one metal in Figure 11 that is normally extracted by electrolysis.

25 000 kg of an ore of iron was found to contain 10 050 kg of iron.

Calculate the percentage of iron in this ore of iron.

percentage of iron in ore =_........

When copper oxide is heated with carbon, the products are copper and carbon dioxide.

Write the word equation for this reaction.

In this reaction, copper oxide loses oxygen.

State the type of reaction when copper oxide loses oxygen.

In one reaction, 159.0 g of copper oxide was heated with excess carbon to produce 127.0 g of copper.

Use this information to calculate the mass of copper formed, in g, when 238.5 g of copper oxide is reacted with excess carbon.

mass of copper =_........ g

State why this reaction with copper oxide uses excess carbon.

A solution of zinc sulfate was made by dissolving 23.8 g of the compound in water and was made up to a total volume of 250 cm³ with water.

Calculate the concentration of this solution in g dm^–3.

Give your answer to 2 significant figures.

concentration =_........ g dm^–3

This question is about the extraction of metals.

Give two advantages of obtaining metals by recycling rather than by extracting them from their metal ores.

Small amounts of some metals are extracted using displacement reactions.

In one process, zinc dust is used to precipitate cadmium metal from a solution containing cadmium ions.

cadmium ions cadmium

Explain why this displacement reaction can be described as a redox reaction.

The formula of the cadmium ion is Cd²⁺. The formula of the phosphate ion is PO₄^3–.

Which is the formula of cadmium phosphate?

One of the alternative biological methods of extracting metals from very low‑grade ores is bioleaching using bacteria.

Give one disadvantage of this method of extracting metals from low‑grade ores.

Lead is low in the reactivity series.

Describe how to obtain a sample of lead from some lead oxide in the laboratory.

The elements in group 7 of the periodic table are the halogens.

Which row shows the colour and physical state of iodine at room temperature?

Iron wool is heated with bromine vapour as shown in Figure 12.

At the end of the reaction, a solid forms at the top of the test tube.

Identify the solid.

Aluminium reacts with bromine.

Write the balanced equation for the reaction between aluminium and bromine.

*(d) (i) The order of reactivity of the halogens can be found by displacement reactions.

A student was provided with

• solutions of bromine, chlorine and iodine

• solutions of sodium bromide, sodium chloride and sodium iodide.

Describe experiments the student could carry out using these solutions to find the order of reactivity of bromine, chlorine and iodine, explaining how the results would show the order of reactivity.

You should use equations to support your answer.

Explain why the displacement reactions of halogens are redox reactions.

Crystals of copper sulfate are prepared by reacting copper oxide, a base, with dilute sulfuric acid.

Name the other product of this reaction.

During the experiment, a spatula measure of copper oxide, a black powder, is added to warm, dilute sulfuric acid in a beaker.

When the mixture is stirred, the black powder disappears and the mixture turns pale blue.

The student then adds more copper oxide until the maximum amount of copper sulfate is formed without wasting copper oxide.

Explain how the student knows when to stop adding copper oxide.

The reaction produces an aqueous solution of copper sulfate.

What is the best way to obtain crystals of copper sulfate from an aqueous solution?

When some water is removed from the aqueous solution of copper sulfate, crystals of copper sulfate are made.

Describe how the arrangement and movement of the particles change as crystals are formed from a solution.

In this reaction, copper oxide, CuO, forms copper sulfate, CuSO₄.

Explain, in terms of electrons, whether the copper in copper oxide has been oxidised, has been reduced, or has not been oxidised or reduced.

In another experiment, a copper sulfate solution with a concentration of 39.875 g dm^–3 is used.

Calculate the mass of copper sulfate dissolved in 0.300 dm³ of this solution.

The method used to extract a metal from its ore depends on the position of the metal in the reactivity series.

Aluminium is extracted from its ore by electrolysis.

Explain why this method is used to extract aluminium from its ore.

One step in the extraction of titanium metal involves the displacement reaction between titanium chloride, TiCl₄, and magnesium.

This equation can be simplified as

Explain why this displacement reaction can be described as a redox reaction.

The formula of the sulfate ion is SO²⁻₄.

Which of the following is the formula of titanium sulfate containing the Ti⁴⁺ ion?

Phytoextraction is an alternative biological method that can be used to extract metals from very low-grade ores.

Give one disadvantage of phytoextraction as a method of extraction of metals.

Copper is low down in the reactivity series and can be obtained from copper oxide.

Devise a simple method to obtain a sample of copper from copper oxide in the laboratory.

The elements in group 7 of the periodic table are known as the halogens.

Name the halogen that is in period 4 of the periodic table.

Explain why chlorine is more reactive than iodine.

A piece of burning sodium is placed into a gas jar containing chlorine gas, as shown in Figure 9.

At the end of the reaction, the inside of the gas jar is coated with white crystals.

Identify the white crystals.

Sodium also reacts with bromine.

Write the balanced equation for the reaction between sodium and bromine.

In another experiment, a student adds colourless sodium bromide solution to chlorine water.

State what you would see in this reaction.

The ionic equation for the reaction between sodium bromide and chlorine is:

Explain which species has been oxidised in this reaction.

When chromium reacts with oxygen, chromium oxide is formed.

Write the word equation for this reaction.

What type of reaction occurs when chromium reacts with oxygen?

Calculate the relative formula mass of chromium oxide, Cr₂O₃.

(relative atomic masses: O = 16, Cr = 52)

relative formula mass =_........

Three different metals are added to separate test tubes of acid.

The observations are shown in Figure 4.

Place the metals in order of reactivity from most to least reactive.

Hydrogen is given off when magnesium reacts with acid. The hydrogen is tested by collecting the gas in a test tube and igniting it.

What is the safest way to ignite the gas?

State the observation made in this test that shows that the gas is hydrogen.

Iron is extracted by heating iron oxide with carbon. Electrolysis of molten iron oxide is not used to extract iron.

State why iron can be extracted by heating iron oxide with carbon.

State why electrolysis is not used to extract iron.

Some metals are found in the Earth’s crust as uncombined elements. Reactive metals are found in ores.

In ores, metals are combined with other elements.

Which of these metals is found as the uncombined element in the Earth’s crust?

Give two advantages of recycling metals rather than extracting metals from their ores.

An ore of iron is mostly iron oxide, Fe₂O₃. Iron can be extracted from this iron oxide by heating it with carbon.

Balance this equation for the reaction that takes place.

Most copper ores are described as low grade. This means that the percentage of copper in the ore is very small.

5000 kg of one copper ore was found to contain 42.5 kg of copper.

Calculate the percentage of copper in this ore.

percentage of copper in ore =_........

In one stage of the extraction of lead from its ore, lead oxide is heated strongly with carbon.

The equation for the reaction is

Explain, using this equation, which substance has been oxidised in this reaction.

A titanium ore was analysed and found to contain 12 g of titanium atoms combined with 8.0 g of oxygen atoms.

Calculate the empirical formula of this titanium compound. (relative atomic masses: Ti = 48, O = 16)

You must show your working.

empirical formula =_........

Titanium and iron are examples of transition metals.

Figure 6 shows the percentage abundance of each isotope in a sample of titanium.

Calculate the relative atomic mass of titanium in this sample.

Iron, when heated in air, reacts with oxygen to form iron oxide.

This reaction is an example of

The equipment shown in Figure 7 can be used to find the mass of oxygen that combines with iron.

Describe how the equipment shown in Figure 7 could be used to find the mass of oxygen that combines with 0.500 g of iron wool in a crucible and lid of known mass.

2.24 g of iron combines with 0.96 g of oxygen to form an oxide of iron.

Determine the formula of this oxide of iron and use it to complete the balanced equation.

(relative atomic masses: Fe = 56.0, O = 16.0)

You must show your working.

balanced equation for the reaction is

Sodium thiosulfate solution, Na₂S₂O₃, reacts with dilute hydrochloric acid.

When dilute hydrochloric acid is mixed with sodium thiosulfate solution, the mixture turns cloudy.

Explain why the mixture turns cloudy.

In an investigation, different concentrations of hydrochloric acid are reacted with sodium thiosulfate solution. The mixture goes cloudy at different rates.

Describe how the rate at which the mixture goes cloudy can be measured.

You are provided with some dilute hydrochloric acid which has a concentration of 50 g dm^–3.

For this experiment, dilute hydrochloric acid with a concentration of 20 g dm^–3 is required.

How much water must be added to 100 cm³ of 50 g dm^–3 hydrochloric acid to make dilute hydrochloric acid with a concentration of 20 g dm^–3?

Sodium iodide solution is colourless.

When a solution of bromine is added to sodium iodide solution, a reaction occurs.

The mixture turns brown.

Give the name of the substance causing the brown colour.

Explain which substance has been reduced in this reaction.

Pieces of zinc react with copper sulfate solution. Zinc sulfate solution is colourless.

Describe what you would see when an excess of zinc is added to copper sulfate solution and the mixture left until the reaction is complete.

This reaction is described as a redox reaction.

Explain, in terms of electrons, which particles have been oxidised and which particles have been reduced in this reaction.

The copper sulfate solution used has a concentration of 15.95 g dm⁻³.

Calculate the number of moles of copper sulfate, CuSO₄, in 50.00 cm³ of this solution. (relative atomic masses: O = 16, S = 32, Cu = 63.5)

In another experiment, 0.043 mol of copper sulfate, CuSO₄, is used.

Calculate, to one decimal place, the minimum mass of zinc that must be added to react with all the copper sulfate. (relative atomic mass: Zn = 65)

7 *(a) Pure metals are often converted into more useful alloys. For example, aluminium is converted into an alloy used in aircraft, iron is converted into an alloy used in cutlery and gold alloys are used in jewellery. These processes of alloying change the structures of the metals.

Some properties of pure aluminium, iron and gold are shown in Figure 12.

Explain how alloying changes these pure metals to make the alloys more suitable for the given uses.

Iron objects can corrode when exposed to the atmosphere.

Corrosion involves the oxidation of iron.

State what is meant by oxidation.

Painting iron objects prevents corrosion.

Explain why painting iron objects prevents corrosion.

Corrosion of iron objects can be prevented by painting them or by electroplating them.

State one other way of preventing the corrosion of iron objects.

The apparatus shown in Figure 13 was used to electroplate a spoon with nickel.

State to what the anode and cathode have to be connected in order to carry out the electroplating.

Predict the name of a substance that could be dissolved in water to form the electrolyte for this electroplating.

Most metals are extracted from ores found in the Earth’s crust.

The method used to extract a metal from its ore is linked to the reactivity of the metal.

Part of the reactivity series is shown in Figure 14.

Iron ore contains iron oxide.

Iron is extracted from iron oxide by heating the oxide with carbon.

iron carbon

In this reaction

The formula of the iron oxide is Fe₂O₃.

Calculate the maximum mass of iron that can be obtained from 240 tonnes of iron oxide, Fe₂O₃.

(relative atomic masses: O = 16, Fe = 56)

mass of iron =_........ tonnes

Aluminium cannot be extracted by heating its oxide with carbon. Aluminium has to be extracted from its oxide by electrolysis.

Explain why.

Predict the method that will have to be used to extract calcium from its ore.

*(d) Aluminium is extracted from its ore by electrolysis. Iron is extracted from its ore by heating with carbon. Both metals can also be obtained by recycling.

Explain the advantages of recycling aluminium and iron rather than extracting them from their ores.

Most metals are extracted from ores found in the Earth’s crust.

The method used to extract a metal from its ore is linked to the reactivity of the metal.

Part of the reactivity series is shown in Figure 2.

Iron ore contains iron oxide.

Iron is extracted from iron oxide by heating the oxide with carbon.

iron carbon

In this reaction

The formula of the iron oxide is Fe₂O₃.

Calculate the maximum mass of iron that can be obtained from 240 tonnes of iron oxide, Fe₂O₃.

(relative atomic masses: O = 16, Fe = 56)

mass of iron =_........ tonnes

Aluminium cannot be extracted by heating its oxide with carbon. Aluminium has to be extracted from its oxide by electrolysis.

Explain why.

Predict the method that will have to be used to extract calcium from its ore.

In recent years, researchers have been investigating alternative methods of extracting metals from soils.

Researchers have found that growing certain plants in appropriate areas can result in the phytoextraction of copper.

Describe how growing plants can result in the phytoextraction of copper.

Describe what is seen when chlorine water is added to potassium bromide solution and the mixture shaken.

Chlorine reacts with potassium bromide to form potassium chloride and bromine. In this reaction chlorine forms chloride ions

In this reaction, chlorine has been reduced.

Explain, using the equation, how you know that chlorine has been reduced.

Write the half equation for the formation of bromine from bromide ions.

Aluminium reacts with chlorine to form aluminium chloride.

Write the balanced equation for this reaction.

A solid ionic compound is dissolved in water to form a solution.

Describe a simple experiment to show that charged particles are present in this solution.